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Ethylene derivs vinyl

Chlorine cannot be stored economically or moved long distances. International movements of bulk chlorine are more or less limited to movements between Canada and the United States. In 1987, chlorine moved in the form of derivatives was 3.3 million metric tons or approximately 10% of total consumption (3). Exports of ethylene dichloride, vinyl chloride monomer, poly(vinyl chloride), propylene oxide, and chlorinated solvents comprise the majority of world chlorine movement. Countries or areas with a chlorine surplus exported in the form of derivatives include Western Europe, Bra2il, USA, Saudi Arabia, and Canada. Countries with a chlorine deficit are Taiwan, Korea, Indonesia, Vene2uela, South Africa, Thailand and Japan (3). [Pg.478]

The term liquefied petroleum gas (LPG) is often used to describe those liquefied flammable gases that are derived from petroleum. The term LFG is preferred when the discussion applies to all liquefied flammable gases. It includes materials such as ethylene oxide, vinyl chloride, and methylamines, which behave similarly so far as their flashing and flammable properties are concerned. [Pg.165]

The rate of eh reaction with ethylene is low, 106 M-1s-1. An electron-donating group adjacent to NH2 or OH makes the rate very low. Similarly, an electron-accepting group enhances the rate as in the case of pyrrole, vinyl alcohol, or ethylene derivatives, where some reactions proceed at diffusion-controlled rates. [Pg.185]

In most of the cases these are ethylene derivatives which have electropositive substituents. The order of reactivity of vinyl monomers is as under ... [Pg.236]

For the addition of ethylene, EtOAc as solvent was particularly advantageous and gave 418 in 60% yield (Scheme 6.86). The monosubstituted ethylenes 1-hexene, vinylcyclohexane, allyltrimethylsilane, allyl alcohol, ethyl vinyl ether, vinyl acetate and N-vinyl-2-pyrrolidone furnished [2 + 2]-cycloadducts of the type 419 in yields of 54—100%. Mixtures of [2 + 2]-cycloadducts of the types 419 and 420 were formed with vinylcyclopropane, styrene and derivatives substituted at the phenyl group, acrylonitrile, methyl acrylate and phenyl vinyl thioether (yields of 56-76%), in which the diastereomers 419 predominated up to a ratio of 2.5 1 except in the case of the styrenes, where this ratio was 1 1. The Hammett p value for the addition of the styrenes to 417 turned out to be -0.54, suggesting that there is little charge separation in the transition state [155]. In the case of 6, the p value was determined as +0.79 (see Section 6.3.1) and indicates a slight polarization in the opposite direction. This astounding variety of substrates for 417 is contrasted by only a few monosubstituted ethylenes whose addition products with 417 could not be observed or were formed in only small amounts phenyl vinyl ether, vinyl bromide, (perfluorobutyl)-ethylene, phenyl vinyl sulfoxide and sulfone, methyl vinyl ketone and the vinylpyri-dines. [Pg.317]

The chemical uses for ethylene prior to World War II were limited, for the most part, to ethylene glycol and ethyl alcohol. After the war, the demand for styrene and polyethylene took off, stimulating ethylene production and olefin plant construction. Todays list of chemical applications for ethylene reads like the WTiat s What of petrochemicals polyethylene, ethylbenzene (a precursor to styrene), ethylene dichloride, vinyl chloride, ethylene oxide, ethylene glycol, ethyl alcohol, vinyl acetate, alpha olefins, and linear alcohols are some of the more commercial derivatives of ethylene. The consumer products derived from these chemicals are found everywhere, from soap to construction materials to plastic products to synthetic motor oils. [Pg.82]

Vinyl acetate is a good example of an ethylene chemical with a high percentage of exports, sometimes near 30%. The United States now has a cost advantage in ethylene production and many ethylene derivatives have high export percentages. [Pg.154]

The solubility data in Table I may be used to test the log P correlations in poly(ethylene-co-vinyl acetate) and polyether-urethanes. The correlations in Equations 19 and 20 are derived by combining this data with the reported (20) water solubilities and octanol-water partition coefficients of the steroids (22-24). [Pg.62]

From a, bis(triehloromethyled) telogens, we carried out various telomerizations with methyl undeeylenate [59], ethylene [60], vinyl acetate [61] aUyl acetate [62-63], and with acrylates [61, 64]. We can notice that the aJlyl and acrylic derivatives lead to a mixture made of monoacetate and diadduct [63] ... [Pg.140]

The effect of polarity on vinyl monomer copolymerization has long been recognized and is a major factor in the Q, e scheme and copolymerization theory. Mayo, Lewis, and Walling tabulated a number of vinyl monomers into an average activity series and an electron donor-acceptor series (62). The activity series showed the effect of substituents on the ease with which an ethylene derivative reacted with an average radical and on stabilizing the radical which was formed thereby. The electron donor-acceptor series indicated the ability of the substituents to serve as donors or acceptors in radical-monomer interactions. It is significant that in both series the dominant factor is the radical-monomer interaction. [Pg.112]

Process Economics Program Report SRI International. Menlo Park, CA, Isocyanates IE, Propylene Oxide 2E, Vinyl Chloride 5D, Terephthalic Acid and Dimethyl Terephthalate 9E, Phenol 22C, Xylene Separation 25C, BTX, Aromatics 30A, o-Xylene 34 A, m-Xylene 25 A, p-Xylene 93-3-4, Ethylbenzene/Styrene 33C, Phthalic Anhydride 34B, Glycerine and Intermediates 58, Aniline and Derivatives 76C, Bisphenol A and Phosgene 81, C1 Chlorinated Hydrocarbons 126, Chlorinated Solvent 48, Chlorofluorocarbon Alternatives 201, Reforming for BTX 129, Aromatics Processes 182 A, Propylene Oxide Derivatives 198, Acetaldehyde 24 A2, 91-1-3, Acetic Acid 37 B, Acetylene 16A, Adipic Acid 3 B, Ammonia 44 A, Caprolactam 7 C, Carbon Disulfide 171 A, Cumene 92-3-4, 22 B, 219, MDA 1 D, Ethanol 53 A, 85-2-4, Ethylene Dichloride/Vinyl Chloride 5 C, Formaldehyde 23 A, Hexamethylenediamine (HMDA) 31 B, Hydrogen Cyanide 76-3-4, Maleic Anhydride 46 C, Methane (Natural Gas) 191, Synthesis Gas 146, 148, 191 A, Methanol 148, 43 B, 93-2-2, Methyl Methacrylate 11 D, Nylon 6-41 B, Nylon 6,6-54 B, Ethylene/Propylene 29 A, Urea 56 A, Vinyl Acetate 15 A. [Pg.403]

IR, Raman and 13C NMR spectroscopic studies have been performed on various [Ir(acac)(L)2] complexes (L = ethylene, propene, vinyl chloride, vinyl acetate, methyl acrylate, styrene) for the elucidation of the bonding between Ir and the alkene ligand.142 Also, the square planar iridium(I) acetylacetonate complexes [Ir(LL)(L )2], where LL is a /J-diketonate and L is CO or ethylene, have been studied by UVPES.143 The enthalpies of reaction of the crystalline [Ir(acac)(L)2] complexes with gaseous CO (reaction 28) have been determined by differential scanning calorimetry. The enthalpies for the gaseous reaction have been derived from these results and Ir—L bond strengths estimated.143... [Pg.1116]

Several procedures exists for calculating the heats of polymerization for various monomers but they are not very important. It is still more useful to consider the experimentally measured values as the best basis both for theoretical studies and for practical calculations. For ethylene derivatives, the value of — AHlc (from liquid monomer to amorphous solid polymer) ranges from 33.5 kJ mol-1 for a-methylstyrene, through ca. 96 kJ mol-1 for vinyl chloride, to 174 kJ mol-1 for tetrafluoroethylene. [Pg.235]

The diazotization of anthranilic acid, a classic route to benzyne, when carried out in the presence of vinyl acetate, vinyl ethers or 1,1-dichloroethylene gives the expected benzocyclobutenes in about 40% yield. Despite the rather moderate yields this method represents a convenient route to multigram quantities of the parent compounds, benzocyclobutenol and benzocyclobutenone. The latter is easily converted to benzocyclobutene-1,2-dione. The diazotization sequence applied to 2-amino-3,6-dimeth-oxybenzoic acid and 1,1-dichloroethylene results in a 80% yield of 3, imethoxycyclobuten-l-one. Trapping of benzynes with other ethylene derivatives, and especially more substituted alkenes, has given generally poorer, variable results. ... [Pg.692]

Braun and Guillet 84) investigated copolymers of ethylene with vinyl acetate and carbon monoxide as well as modified polyethylene waxes. While the crystallinity of such polymers can no longer be derived from their density, it was found that the GC method was equally successful with copolymers or modified K)fymers. Figure 9... [Pg.132]

Butadiene epoxidation to epoxybutene (EpB ) was practiced at a semiworks scale of 1.4 x 10 metric tons year by Tennessee Eastman [9] between 1997 and 2004 [10]. Epoxybutene is a versatile intermediate [11] that can be used to produce a large variety of different products such as epoxybutane, 1,4-butane diols and alcohols, 1,2-butane diols and alcohols, 2,3-dihydrofuran, 2,5-dihydrofuran, tetrahydrofuran, N-methylpyrrolidone, cyclopropyl carboxyaldehyde (CPCA) derivatives, vinyl ethylene carbonate (addition of CCT to EpB), and 3,4-dihydroxy-l-butene (addition of H2O to EpB). [Pg.6]

With the second approach to the preparation of the catalytic system, only methylenebis(dichloroaluminium) was prepared by an electrolytic reaction31. In the flow sheet proposed in the patent, between the electrolytic cell and the polymerization vessel a mixing reactor is interposed, where the various transition metal derivatives are added to the aluminium containing solution. Following this method other monomers, such as butadiene, 1-butene (copolymerized with ethylene), and vinyl chloride were successfully polymerized. [Pg.32]

Photosensitized crosslinking of polymers has been the subject of numerous publications [l - 30], concerned mainly with poly(ethylene), poly(vinyl alcohol), various vinyl copolymers, copolymers of maleic anhydride and/or phtalic anhydride with styrene and some polymers derivated from cinnamic acid. The following compounds were used as sensitizers benzophenone, 4-chloro- and 4,4-dimethylbenzophenone [l, 3-6, 8, 9l, oC -and -derivatives of anthraquinone [3, 23] acetophenone, hydroquinone, triphenylmethane and pyridine li.] chlorobenzene and no less than trichlorinated n-paraffins [6], a complex of zink chloride with o-dia-nizidine fill potassium bichromate [l2j, anthracene fl3, 14] 2,5-methoxy-4-amino-trans-stilbene [l5], benzyl ideneacetophenone fl6-l8] -thiophenylacetophenone,... [Pg.58]

However, it is difficult to say at present to what an extent the picture shown in Scheme 7 and Fig. 2 corresponds to reality. In any case, the free-radical polymerization of symmetric vinyl monomers is not forbidden from the standpoint of symmetry, and ethylene is known to be polymerized by the free-radical mechanism. It should be noted that in the case of quasisymmetric ethylene derivatives (e.g. propylene the quasisymmetric character of which is due to real symmetry of its frontier rc-orbitals), free-radical polymerization is sometimes interrupted as early as in the stage of oligomer formation because chain termination reactions proceed intensively [37]. This has naturally no relationship to any exclusion with respect to symmetry. [Pg.155]

The polymerization of ethylene derivatives has recently become extremely important for the manufacture of plastics. Certain substituents in ethylene — those that increase the polarization — increase both the extent and the rate of polymerization. Such substituents are aromatic groups (as in styrene), oxygen-containing groups (as in acrolein, acrylic esters, and vinyl esters and ethers), and halogens (as in vinyl chloride). Multiplication of these substituents, however, depresses or completely suppresses the tendency to polymerize for instance, stilbene gives only a dimer when illuminated in benzene.14... [Pg.848]

Not every ethylene derivative can be polymerized by each of the three mechanisms. The cationoid mechanism is favored when the doubly bonded atom carries a substituent that shifts the -electron pair of the double bond away from it, as in a vinyl ether ... [Pg.852]


See other pages where Ethylene derivs vinyl is mentioned: [Pg.166]    [Pg.10]    [Pg.104]    [Pg.310]    [Pg.703]    [Pg.429]    [Pg.457]    [Pg.462]    [Pg.455]    [Pg.236]    [Pg.52]    [Pg.334]    [Pg.10]    [Pg.443]    [Pg.692]    [Pg.108]    [Pg.236]    [Pg.371]    [Pg.160]    [Pg.301]    [Pg.26]    [Pg.443]    [Pg.89]   


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