Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Equivalent Mises

Assume a continuous release of pressurized, hquefied cyclohexane with a vapor emission rate of 130 g moLs, 3.18 mVs at 25°C (86,644 Ib/h). (See Discharge Rates from Punctured Lines and Vessels in this sec tion for release rates of vapor.) The LFL of cyclohexane is 1.3 percent by vol., and so the maximum distance to the LFL for a wind speed of 1 iti/s (2.2 mi/h) is 260 m (853 ft), from Fig. 26-31. Thus, from Eq. (26-48), Vj 529 m 1817 kg. The volume of fuel from the LFL up to 100 percent at the moment of ignition for a continuous emission is not equal to the total quantity of vapor released that Vr volume stays the same even if the emission lasts for an extended period with the same values of meteorological variables, e.g., wind speed. For instance, in this case 9825 kg (21,661 lb) will havebeen emitted during a 15-min period, which is considerablv more than the 1817 kg (4005 lb) of cyclohexane in the vapor cloud above LFL. (A different approach is required for an instantaneous release, i.e., when a vapor cloud is explosively dispersed.) The equivalent weight of TNT may be estimated by... [Pg.2320]

Wiring and Eqitipment Above Class I Locations. All fixed wiring above Class I locations shall be in metal raceways or PVC schedule 80 rigid nonmetallic conduit, or equivalent, or be Type MI, TC, or Type MC cable. Fixed equipment that may produce arcs. [Pg.644]

The application of the overpotential t] can be considered to be equivalent to the displacement of the potential energy curves by the amount 7]F with respect to each other. The high field is now applied across the double layer between the electrode and the ions at the plane of closest approach. It is apparent from Fig. 12 that the energy of activation in the favoured direction will be diminished by etrjF while that in the reverse direction will be increased by (1 — ac)r]F where the simplest interpretation of a is in terms of the slopes of the potential energy curves (a = mi/ mi+m )) at the points of intersection electrode processes indeed are the classical example of linear free energy relations. [Pg.209]

Filter cartridges, Acrodisc nylon, 25-mm (Gelman Sciences, Ann Arbor, MI, USA) or equivalent Filter paper, GF/A, 9-cm... [Pg.1235]

Round, flint glass with polymer-lined lids, 120-mL Square, flint glass with polymer-lined lids, 0.5-oz Filter cartridges, Acrodisc nylon, 25-mm (Gelman Sciences, Ann Arbor, MI, USA) or equivalent Filter, GF/A, 9-cm Florisil, 2.5% deactivated Glass wool... [Pg.1284]

During their passage through the column, sample molecules spend part of the time in the mobile phase and part in the stationary phase. All molecules spend the same amount of time in the mobile phase. This time is called the column dead tine or holdup time (t.) and is equivalent to the tine required for an unretained solute to reach the detector frsolute retention time (t,) is the time between the instant of saiq>le introduction and when the detector senses the maximum of the retained peak. This value is greater than the column holdup time by the amount of time the solute spends in the stationary phase and is called the adjusted retention time (t, ). These values lead to the fundamental relationship, equation (1.1), describing retention in gas and liquid chromatography. [Pg.7]

Example 2-3 Scale-Up of Pipe Flow. We would like to know the total pressure driving force (AP) required to pump oil (/z = 30 cP, p = 0.85 g/cm3) through a horizontal pipeline with a diameter (D) of 48 in. and a length (L) of 700 mi, at a flow rate (Q) of 1 million barrels per day. The pipe is to be of commercial steel, which has an equivalent roughness (e) of 0.0018 in. To get this information, we want to design a laboratory experiment in which the laboratory model (m) and the full-scale field pipeline (f) are operating under dynamically similar conditions so that measurements of AP in the model can be scaled up directly to find AP in the field. The necessary conditions for dynamic similarity for this system are... [Pg.32]

A pipeline to carry crude oil at a rate of 1 million bbl/day is constructed with 50 in. ID pipe and is 700 mi long with the equivalent of 70 gate valves installed but no other fittings ... [Pg.234]

You must specify a pump to be used to transport water at a rate of 5000 gpm through 10 mi of 18 in. sch 40 pipe. The friction loss in valves and fittings is equivalent to 10% of the pipe length, and the pump is 70% efficient. If a 1200 rpm motor is used to drive the pump, determine ... [Pg.257]

The MI is equal to the cosine of the angle (designated as a) between two row vectors (the test and reference spectra) projected onto a two-dimensional plane, and is equivalent to the correlation (r) between the two spectra (row vectors) as equation 74-9. [Pg.499]

This apparent contradiction is best explained by the ensemble behavior of dense mainstream smoke, described by Fuchs (1964). When undiluted mainstream tobacco smoke is passed horizontally into a chamber, the dense smoke column settles as an ensemble, with a gravitational settlement rate equivalent to that for individual particles of 47 /mi diameter. Such behavior can explain the remarkable retention of undiluted smoke (Hinds et al., 1983) as well as the highly nonuniform pattern of deposition for inhaled smoke tars observed by Ermala and Holsti (1955). The heaviest tar deposits occur where the dense smoke column strikes directly on projecting surfaces of the pharynx and the larynx, and at the tracheal and bronchial bifurcations (Er-... [Pg.452]

The main statistical characteristic of the chemical structure of a heteropolymer among those pertaining to the first type is the distribution of molecules f( h, 12) for numbers l and h of their constituent monomeric units Mi and M2. In dealing with a high-molecular weight polymer, these numbers may be taken as continuous variables, uniquely specifying chemical size l=l + h and composition f = li/l of a macromolecule. Under such a consideration, it is more convenient instead of function /(Zi, l2) to use the equivalent function of Size-Composition Distribution (SCD) f(l, < ) This is possible to represent... [Pg.144]

An interesting approach has been employed in paper [74] to find the distribution f(li, l2) of copolymer chains for numbers l and h of monomeric units Mi and M2. This distribution is evidently equivalent to the SCD, because the pair of numbers k and I2 unambiguously characterizes chemical size (l = h + l2) and composition ( 1 = l] //, 2 = h/l) of a macromolecule. The essence of this approach consists of invoking the Superposition Principle [81] that enables the problem of finding the Laplace transform G(pi,p2) of distribution f(li,k) to be reduced to the solution of two subsidiary problems. The first implies the derivation of the expression for the generating function [/(z1",z 2n ZjX,z ) of distribution P(ti, M2 mt, m2), and the second is concerned with finding the Laplace transforms g (pi,p2) and (pi,p2) of distributions (Eq. 91). With these two problems solved, it is possible to obtain the characteristic function G(pi,p2) of distribution f(li,h) using the Superposition Principle formula... [Pg.191]

The common assumed emission rate is 1000 kg/h or 1 tonne/h. To achieve an amount equivalent to the 100 tonnes in the Level I calculation requires an overall residence time of 100 hours. Again, the concentrations and amounts mi and Em, or M can be deduced, as well as the reaction and advection rates. These rates obviously total to give the input rate E. Of particular interest are the relative rates of these loss processes, and the overall persistence or residence time, which is calculated as... [Pg.23]

To relate the hybrid angles of Table 4.3 to idealized molecular shapes, let us now consider a general MI./, species with k monovalent ligands L.13 In general, k equivalent sd hybrids of sd/, 1 composition (i.e., p = k — 1) are needed to form the sigma skeleton... [Pg.381]

Fig. 1. An overview of the DCLD tier/triage flow chart Boxes 1, 2, and 3 are taken from the Office of Device Evaluation decision tree, which is routinely used to determine whether a product can be reviewed as a 510(k) and found substantially equivalent to a predicate (currently marked) device or whether the product must be handled as a fundamentally new product and submitted to a PMA review. Box 4 determines the novelty of the product in terms of analyte, matrix, and/or technology. If new issues of safety and effectiveness are raised, a highly novel product might require review as a PMA. If the issues of safety and effectiveness are not new but require high-level scrutiny, then a tier III review is warranted. Examples of products requiring a tier III review would include 1. Analyte troponin for diagnosis of MI (with creatinine kinase as the predicate) 2. Matrix sweat patches for drugs of abuse (with urine drugs of abuse tests as the predicate) and 3. Technology nucleic acid... Fig. 1. An overview of the DCLD tier/triage flow chart Boxes 1, 2, and 3 are taken from the Office of Device Evaluation decision tree, which is routinely used to determine whether a product can be reviewed as a 510(k) and found substantially equivalent to a predicate (currently marked) device or whether the product must be handled as a fundamentally new product and submitted to a PMA review. Box 4 determines the novelty of the product in terms of analyte, matrix, and/or technology. If new issues of safety and effectiveness are raised, a highly novel product might require review as a PMA. If the issues of safety and effectiveness are not new but require high-level scrutiny, then a tier III review is warranted. Examples of products requiring a tier III review would include 1. Analyte troponin for diagnosis of MI (with creatinine kinase as the predicate) 2. Matrix sweat patches for drugs of abuse (with urine drugs of abuse tests as the predicate) and 3. Technology nucleic acid...
A Schottky diode is always operated under depletion conditions flat-band condition would involve giant currents. A Schottky diode, therefore, models the silicon electrolyte interface only accurately as long as the charge transfer is limited by the electrode. If the charge transfer becomes reaction-limited or diffusion-limited, the electrode may as well be under accumulation or inversion. The solid-state equivalent would now be a metal-insulator-semiconductor (MIS) structure. However, the I-V characteristic of a real silicon-electrolyte interface may exhibit features unlike any solid-state device, as... [Pg.41]


See other pages where Equivalent Mises is mentioned: [Pg.259]    [Pg.261]    [Pg.464]    [Pg.87]    [Pg.426]    [Pg.200]    [Pg.491]    [Pg.261]    [Pg.8]    [Pg.123]    [Pg.464]    [Pg.640]    [Pg.235]    [Pg.267]    [Pg.141]    [Pg.42]    [Pg.201]    [Pg.295]    [Pg.26]    [Pg.40]    [Pg.121]    [Pg.82]    [Pg.25]    [Pg.330]    [Pg.121]    [Pg.728]    [Pg.1681]    [Pg.695]    [Pg.450]    [Pg.24]    [Pg.181]    [Pg.72]    [Pg.232]    [Pg.249]   
See also in sourсe #XX -- [ Pg.91 , Pg.104 ]




SEARCH



© 2024 chempedia.info