Multiple emission

The photomultiplier, as shown in Fig. 6, is almost universally used as a photon counter, that is, the internal electron multiplication produces an output electrical pulse whose voltage is large compared with the output electric circuit noise. Each pulse in turn is the result of an individual photoexcited electron. The numbered electrodes, 1-8, called dynodes, are each successively biased about 100 V positive with respect to the preceding electrode, and an accelerated electron typically produces about 5 secondary electrons as it impacts the dynode. The final current pulse collected at the output electrode, the anode, would in this case contain 5 400,000 electrons. The secondary emission multiplication process is random, the value of the dynode multiplication factor is close to Poisson distributed from electron to electron. The output pulse amplitude thus fluctuates. For a secondary emission ratio of = 5, the rms fractional pulse height fluctuation is 1 /V<5 — 1 = 0.5. Since the mean pulse height can be well above the output circuit noise, the threshold for a pulse count may be... 

As described at the end of section Al.6.1. in nonlinear spectroscopy a polarization is created in the material which depends in a nonlinear way on the strength of the electric field. As we shall now see, the microscopic description of this nonlinear polarization involves multiple interactions of the material with the electric field. The multiple interactions in principle contain infomiation on both the ground electronic state and excited electronic state dynamics, and for a molecule in the presence of solvent, infomiation on the molecule-solvent interactions. Excellent general introductions to nonlinear spectroscopy may be found in [35, 36 and 37]. Raman spectroscopy, described at the end of the previous section, is also a nonlinear spectroscopy, in the sense that it involves more than one interaction of light with the material, but it is a pathological example since the second interaction is tlirough spontaneous emission and therefore not proportional to a driving field... 

Flame Sources Atomization and excitation in flame atomic emission is accomplished using the same nebulization and spray chamber assembly used in atomic absorption (see Figure 10.38). The burner head consists of single or multiple slots or a Meker-style burner. Older atomic emission instruments often used a total consumption burner in which the sample is drawn through a capillary tube and injected directly into the flame. 

Multiple-Bubble Sonoluminescence. The sonoluminescence of aqueous solutions has been often examined over the past thirty years. The spectmm of MBSL in water consists of a peak at 310 nm and a broad continuum throughout the visible region. An intensive study of aqueous MBSL was conducted by VerraH and Sehgal (35). The emission at 310 nm is from excited-state OH, but the continuum is difficult to interpret. MBSL from aqueous and alcohol solutions of many metal salts have been reported and are characterized by emission from metal atom excited states (36). 

An important development in the 1980s was the multiple stripe laser, capable of emission of high output powers. A number of stripes are placed on a bar perhaps 1 cm wide the output of the different stripes is coupled so that the device may be regarded as a single laser. Bars having continuous output up to 20 W are available in the aluminum gallium arsenide system. A number of bars may then be stacked to form two-dimensional arrays with high values of output power. 

A notable difference between the newer large machines and the somewhat smaller units is the use of multiple, reverse-flow can combustors configured annulady. Because the individual cans are relatively small, they reportedly lend themselves well to laboratory experimentation with various fuel types, including reduced-heat value synfuels (see Fuels, synthetic). A dry, low NO version of the can combustors has been developed for both gas and hquid fuel firing. NO emissions can reportedly be held below 25 ppm when firing gas fuel. By employing water injection, NO emissions can be held below 60 ppm for oil-fired units. 

Clouds of Nonblack Particles The correction for nonblackness of the particles is complicated by multiple scatter of the radiation reflected by each particle. The emissivity . of a cloud of gray particles of individual surface emissivity 1 can be estimated by the use of Eq. (5-151), with its exponent multiplied by 1, if the optical thickness alv)L does not exceed about 2. Modified Eq. (5-151) would predict an approach of . to 1 as L 0°, an impossibihty in a scattering system the asymptotic value of . can be read from Fig. 5-14 as /, with albedo (0 given by particle-surface refleclance 1 — 1. Particles with a perimeter lying between 0.5 and 5 times the wavelength of interest can be handledwith difficulty by use of the Mie equations (see Hottel and Sarofim, op. cit., chaps. 12 and 13). 

If the bounding surface is gray rather than black, multiplication of Eq. (5-154) by surface emissivity 1 allows properly for reduction of the primary beams, gas-to-surface or surface-to-gas, but secondary reflections are ignored. The correction then lies between 1 and 1, and for most industrially important surfaces with 1 > 0.8 a value of (1 -t- 1)/ 2 is adequate. Rigorous allowance for this and other factors is presented later, e.g., Eq. (5-163). 

Multiple Metals Testing The samphng method commonly used to measure emissions of metals from stationaiy sources is contained in 40 CFR 266, Appendix IX. The procedure is titled Methodology for the Determination of Metals Emissions in Exhaust Gases from Hazardous Waste Incineration and Similar Combustion Processes. It is also currently pubhshed as Draft EPA Method 29 for inclusion in 40 CFR 60. 

For VOCs, control options are multiple. Source reduction or removal includes product substitution or reformulation. Particleboard or pressed w ood has been developed and used extensively in building materials for cabinet bases and subflooring and in furniture manufacturing for frames. If the product is not properly manufactured and cured prior to use as a building material, VOCs can outgas into the interior of the residence or building. Other sources of VOCs may be paints, cleaning solutions, fabrics, binders, and adhesives. Proper use of household products will lower volatile emissions. 

ESPs), and some of the previously discussed novel devices. Series combinations of control devices may be necessary to achieve the required level of particulate matter emission. A commonly used system is a multiple cyclone followed by a fine-particle control system, such as a baghouse, scrubber, or ESP. 

Control of particulate matter emissions from the kilns, dryers, grinders, etc. is by means of standard devices and systems (1) multiple cyclones (80% efficiency), (2) ESPs (95% -I- efficiency), (3) multiple cyclones followed by ESPs (97.5% efficiency), and (4) baghouses (99.8% efficiency). 

Future developments of this instrumentation include field emission electron sources at 200-300 kV that will allow better elemental detectability and better spatial resolution. Multiple X-ray detectors having large collection angles will also improve elemental detectability in X-ray microanalysis. The higher accelerating... 

A booth should be of suffieient size to eontain any naturally oeeuii ing emissions and so minimize eseape via the open faee. An air veloeity of 0.56 m/s is required over the whole open faee a higher veloeity is needed if there is signifieant air movement within the booth or to eope with eonveetion eurrents. Booths should be deep enough to eontain eddies at the rear eorners baffle plates or multiple offtakes may be neeessary with shallow booths. 

SCREEN can not explicitly determine maximum impacts from multiple sources, except for the procedure to handle multiple nearby stacks by merging emissions into a single "representative" stack. The reader is directed to the MPTER (Pierce and Turner, 1980) or ISC (EPA, 1995b) models on EPA s Support Center for Regulatory Air Models (SCRAM) Bulletin Board System (BBS) to model short-term impacts for multiple sources. With the... 

Enclosed flares are composed of multiple gas burner heads placed at ground level in a staeklike enclosure that is usually refractory or ceramic lined. Many flares are equipped with automatic damper controls that regulate the supply of combustion air depending on temperature which is monitored upstream of the mixing, but inside the staek. This class of flare is becoming the standard in the industry due to its ability to more effectively eontrol emissions. Requirements on emissions includes carbon monoxide limits and minimal residence time and temperature. Exhaust gas temperatures may vary from 1,000 to 2,000 F. 

Duplicate submissions not identified. Facilities sometimes send multiple copies of the same Form R report to insure that EPA received a copy. Duplicate submissions must be identified by printing the word DUPLICATE" in red Ink on page one in the box marked "THIS SPACE FOR YOUR OPTIONAL USE". Failure to clearly identity a duplicate report may result in the duplicate appearance of the data in the database and the appearance of increased emissions from the facility. 

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