Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Cycles minimum number

The minimum number of cycles is given by the nullity or Frerejacque number ( ) according to Eq. (5). It is the difference between the number of nodes a = atoms) and the number of edges h = bonds). The value of 1 stands for the number of compounds considered (here, one compound). This minimum number corresponds to the munber of chords. These are defined as nodes that turn a cyclic graph or structure into an acyclic one. [Pg.55]

Generahzed correlations are available for each of the operations which make up the full filter cycle. This means that simulated operating conditions can be varied to obtain a maximum of information without requiring an excessive number of test runs. The minimum number of test runs required for a given feed will, of course, vary with the expertise of the experimenter and the number of operations performed during the filter cycle. If, for example, the operation invdves only the dewatering of a slurry which forms a cake of relatively low to moderate porosity, frequently sufficient data can be obtained in as little as six runs. For more difficult tests, more runs are usually advisable, and the novice certainly should make a larger number of runs as there is likely to be more data scatter. [Pg.1696]

In practical applications, it can be a factor that the above approach by virtue of the cycle over A values has a higher minimum number of scans per ti value than the standard experiment and its various accordion versions. For dilute samples, this does not matter but for concentrated samples the instrument time can be longer than required considering the inherent sensitivity. [Pg.320]

In the new vision, assay cycle time is dramatically reduced and the criteria used to measure assay acceptability are matched to sample type. Early screening samples may be assayed using simple methods and minimum numbers of standards. Samples from early preclinical PK studies in rats and other species may require additional standards. Finally, for PK studies performed in the lead characterization phase, one might add quality control (QC) samples. One set of rules for non-GLP assays has been codified in a recent publication.16 These rules make it possible to match the assay cycle time with the in-life cycle time in order to minimize the total discovery cycle time. [Pg.207]

Fig. 14.9 Individual components of multidimensional optimization. This approach requires experimental compound profiling against key properties, which should be done on a designed compound subset to maximize information with a minimum number of molecules. These data are used to derive models for key properties, which are applied during the next design cycle. The results then led to augmented models. The process is characterized by a tight integration of in vitro and in silico tools for profiling compound series to guide chemical optimization. Fig. 14.9 Individual components of multidimensional optimization. This approach requires experimental compound profiling against key properties, which should be done on a designed compound subset to maximize information with a minimum number of molecules. These data are used to derive models for key properties, which are applied during the next design cycle. The results then led to augmented models. The process is characterized by a tight integration of in vitro and in silico tools for profiling compound series to guide chemical optimization.
The model includes fundamental hydrocarbon conversion kinetics developed on fresh catalysts (referred to as start-of-cycle kinetics) and also the fundamental relationships that modify the fresh-catalyst kinetics to account for the complex effects of catalyst aging (deactivation kinetics). The successful development of this model was accomplished by reducing the problem complexity. The key was to properly define lumped chemical species and a minimum number of chemical reaction pathways between these lumps. A thorough understanding of the chemistry, thermodynamics, and catalyst... [Pg.193]

Resampling with the Same Resin. Resin cleaning was performed to produce the minimum number of GC-FID responses from the cleaning solvent. One cycle of exposure to a sample of water followed by elution of the columns caused the reappearance of the characteristic contaminants, which have been tentatively identified by GC-MS as methyl benzoate, C2-benzaldehyde, C2-acetophenone, and the unknown listed in Table II and shown in Figures 4 and 5. A similar phenomenon also has been reported by Bean et al. (16) and Care et al. (22). [Pg.287]

For PCR, it is important to use a licensed thermostable enzyme with a proofreading facility and to reduce the cycle number to the minimum number that provides acceptable yield after the post-PCR manipulations. The precautions are necessary, because the error rate for some thermostable polymerases is quite high and the number of errors that accumulate increases with cycle number. [Pg.437]

Reactor core fuel -type - enrichment by 235U, %, maximum -average burn-up, MWday/kg -fuel cycle, eff. days, minimum - number of refuellings Based on UO2 w/multi-layer coatings 20 125 900 3... [Pg.71]

In an industrial hydroformylation reaction with a rhodium catalyst in the presence of excess phosphine and high pressures of CO, what would probably be the minimum number of catalytic cycles and intermediates ... [Pg.101]

All possible interactions between the K and L groups were taken into account and Akk = 0. The definition contains a minimum number of groups and is satisfactory for most of the binary systems studied. However, it cannot take into account the structural differences which exist between position isomers. This is the case of polycyclic aromatic compounds presenting cycle position isomers or substitute position isomers. Structural differences of this type determine the gaps between the values of certain thermophysical properties of isomers, such as, for example, the fusion temperature or sublimation enthalpy. The further the temperature falls, the more these differences are accentuated. The representation of the solid-fluid (low temperature) equilibria is consequently more difficult and the model must take into account the existing structural differences. We came across this problem in the compounds such as anthracene, phenanthrene, pyrene, methylated naphthalenes, hexamethylbenzene and triphenylmethane. As it was out of the question to increase the number of groups because... [Pg.472]

The minimum number of scans is defined by the phase cycle. The total number of scans mnst be an integral multiple of this. [Pg.6171]

For single-unit processes, it is usually desirable to pick design variables that minimize the number of state equations that must be solved simultaneously. For multiple-unit processes, it is desirable to pick design variables to minimize the number of cycles on the flowchart. When doing calculations for cycles on flowcharts, it is desirable to tear as many cycles as possible with the minimum number of tear stream variables. These rules of thumb may not always lead to the most efficient calculations and they may contradict one another, however, so that finding the best combination of design and tear stream variables may require considerable trial-and-error for complex processes. [Pg.533]

The VariCol approach, as introduced by Ludemann-Hombourger et al. (2000b), increases the flexibility of the continuous separation system by asynchronous movement of the injection and withdrawal ports. Within a complete process cycle this leads to mean numbers of columns per section that are non-integer. As the minimum number of columns per section in a SMB-system is one, it is possible in VariCol systems to reduce this to virtually any number less than one. Owing to the... [Pg.197]

The main difficulty is to perfonn work necessary to choose the most promising processes without spreading the efforts too much. A roadmap with milestones needs to be established in order to assign the available resources onto a minimum number of processes. Before concluding the roadmap, work performed so far by CEA on thermochemical cycles and HTE, as well as on a techno-economic analysis, is presented. [Pg.80]

Minimum number of consecutive passes to achieve one full cycle of processing by the... [Pg.92]

In this magnitude COSY experiment it is possible to obtain sine and cosine modulated data with co-addition using a simple two step phase cycle and consequently the minimum number of scans per increment is 2 or for long acquisitions a multiple of 2. The simplicity of this pulse program is in contrast to the phase sensitive COSY experiment and other Bruker two dimension pulse programs which utilize phase increment commands such as ipl to achieve frequency discrimination in fl. [Pg.37]

Phase cycling is an important part of any pulse program enabling signal selection and the suppression of artefacts. To help in setting up an experiment, particularly a 2D experiment, the minimum number of scans required for the correct phase cycling is usually listed in the commentary section of the pulse program. Check it 3.3.1.5 briefly... [Pg.94]

The cycle rank or number of independent circuits, characterizes the network with greater generality, regardless of the nature of its imperfection. is the minimum number of scissions required to reduce the network to a spanning tree. [Pg.80]


See other pages where Cycles minimum number is mentioned: [Pg.55]    [Pg.55]    [Pg.404]    [Pg.522]    [Pg.1153]    [Pg.218]    [Pg.160]    [Pg.143]    [Pg.265]    [Pg.237]    [Pg.319]    [Pg.522]    [Pg.130]    [Pg.202]    [Pg.456]    [Pg.98]    [Pg.404]    [Pg.1355]    [Pg.254]    [Pg.654]    [Pg.270]    [Pg.171]    [Pg.302]    [Pg.404]    [Pg.238]    [Pg.392]   
See also in sourсe #XX -- [ Pg.54 ]




SEARCH



Cycle number

Minimum Number of Cycles

Minimum number

© 2024 chempedia.info