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Phase characterization

Of great interest to physical chemists and chemical physicists are the broadening mechanisms of Raman lines in the condensed phase. Characterization of tliese mechanisms provides infomiation about the microscopic dynamical behaviour of material. The line broadening is due to the interaction between the Raman active chromophore and its environment. [Pg.1211]

Fig. 23. Total internal redection occurs at boundary between denser, transparent phase (characterized by and rarer, absorbing phase (characterized by n )... Fig. 23. Total internal redection occurs at boundary between denser, transparent phase (characterized by and rarer, absorbing phase (characterized by n )...
The system of primary interest, then, is that of a condensable vapor moving between a Hquid phase, usually pure, and a vapor phase in which other components are present. Some of the gas-phase components may be noncondensable. A simple example would be water vapor moving through air to condense on a cold surface. Here the condensed phase, characterized by T and P, exists pure. The vapor-phase description requiresjy, the mole fraction, as weU as T and P. The nomenclature used in the description of vapor-inert gas systems is given in Table 1. [Pg.96]

D development on the same monolayer stationary phase with mobile phases characterized by different total solvent strength (5t) and selectivity values (5y) ... [Pg.170]

One can see that ordering reaction proceeds abruptly around time t = 40,000 45,000 leading to the formation of LIq ordered phase characterized by a layered arrangement of A and B atoms alternatively along the [100] direction as is shown in the uppermost right-hand figure. It was amply discussed in the previous papers that, in the fiat portion of... [Pg.87]

For high temperatures, the spin-glass system behaves essentially the way conventional Ising-spin systems behave namely, a variety of different configurations are accessible, each with some finite probability. It is only at low enough tempera tures that a unique spin-glass phase - characterized chiefly by the appearance of a continuum of equilibrium states - first appears. [Pg.338]

The novel element in these models is the introduction of a third phase in the Hashin-Rosen model, which lies between the two main phases (inclusions and matrix) and contributes to the progressive unfolding of the properties of the inclusions to those of the matrix, without discontinuities. Then, these models incoporate all transition properties of a thin boundary-layer of the matrix near the inclusions. Thus, this pseudo-phase characterizes the effectiveness of the bonding between phases and defines a adhesion factor of the composite. [Pg.175]

Initially, the compression does not result in surface pressure variations. Molecnles at the air/water interface are rather far from each other and do not interact. This state is referred to as a two-dimensional gas. Farther compression results in an increase in snrface pressure. Molecules begin to interact. This state of the monolayer is referred as two-dimensional liquid. For some compounds it is also possible to distingnish liqnid-expanded and liquid-condensed phases. Continnation of the compression resnlts in the appearance of a two-dimensional solid-state phase, characterized by a sharp increase in snrface pressure, even with small decreases in area per molecule. Dense packing of molecnles in the mono-layer is reached. Further compression results in the collapse of the monolayer. Two-dimensional structure does not exist anymore, and the mnltilayers form themselves in a non-con trollable way. [Pg.141]

Theoretical objections to the use of retention index differences for stationary phase characterization are based on the... [Pg.100]

The last tvo approaches represent promising beginnings for new methods to characterize stationary phase selectivity. The methods are evolutionary and not fully developed at present. Their future prospects are quite good and should eventually evolve into a standardized protocol for phase characterization. This is urgently required to make both the selection of stationary phases from those currently available and the rationale synthesis of new phases a logical process. [Pg.102]

The goal of our investigations was to characterise the morphology of the sample, and to determine the size and location of the PTFE and silicone oil phases by different methods [46,47], For phase characterization using Raman microscopy, no special sample preparation was necessary. For FTIR imaging, microtomed sections (5 pm in thickness) had to be prepared by cutting the sample with a diamond knife at — 80°C ("cryo-microtomy") to prevent smearing and to obtain flat surfaces. [Pg.540]

Table 3 Data relative to selected crystalline polymers for which only chiral crystalline phases, characterized by chiral helical conformations, are known... [Pg.116]

Once the headache pain wanes, a resolution phase characterized by exhaustion, malaise, and irritability ensues. [Pg.613]

The literature abounds with countless examples that illustrate how powder diffraction has been used to distinguish between the members of a polymorphic system. It is absolutely safe to state that one could not publish the results of a phase characterization study without the inclusion of XRPD data. For example, Fig. 7.11 shows the clearly distinguishable XRPD powder patterns of two anhydrous forms of a new chemical entity. These are easily distinguishable on the overall basis of their powder patterns, and one could place the identification on a more quantitative basis through the development of criteria similar to those developed for the mandelic acid system. [Pg.209]

The following list identifies the most important analytical techniques that are regularly used in the support of industrial crystallization process development and API solid phase characterization. [Pg.48]

Among these phases, characterized by high coordination numbers, typical representatives are Cr3Si-type phases, a phases and p phases, Laves phases. As for phases formed with semi-metals or non-metals we may point out the NiAs, NaCl, M0S2, MoSi2 types. [Pg.421]

The most common approach to chromatographic stationary-phase characterization is in terms of bulk-phase properties, such as percent carbon loading onto the silica substrate. This property together with the surface area of the substrate and the molecular characteristics of the bonded silane can be used to calculate the bonding density (A) of the chromatographic sorbent [60] ... [Pg.260]

One of the initial spectroscopic methods applied to stationary-phase characterization was Fourier transform infrared spectroscopy (FTIR). This originated from several important studies of phase conformational order in crystalline n-alkanes conducted in the late 1960s and early 1980s by Snyder, Maroncelli, and coworkers [111-114], In this work, assignments of C—H bond wagging modes were associated with chain... [Pg.261]

Differential scanning calorimetry (DSC) is a common technique for the classification of individual phase transitions in liquid-crystalline materials and has been applied for the phase characterization of alkyl-modified chromatographic surfaces. Hansen and Callis [187] applied DSC to investigate phase changes in Cig and C22... [Pg.277]


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Bicontinuous phases characterization

Bonded stationary phases characterization, HPLC

Catalyst Characterization for Gas Phase Processes

Characterization goals phase identification

Characterization minor phases

Characterization of Phase Behavior in Polymer Blends by Light Scattering

Characterization of Reversed Phase Silicas

Characterization of Two-Phase Dispersions by IS

Characterization of the solid phase

Characterization, substrate phase

Characterizations Stability and Phase Behavior

Chemically bonded stationary phases characterization

Energetic and structural quantities for phase characterization by canonical statistical analysis

Fluorescence spectroscopy phase characterization using

Linear empirical, phase characterization

Liquid Phase Process Characterization

Liquid crystal phases, characterization

Material characterization methods quantitative phase analysis

Molecular simulations phase characterization using

Normal-phase stationary phases characterization

Phase Doppler Based Size Characterization Equipment

Phase characterization Monte Carlo simulations

Phase characterization ellipsometry

Phase characterization molecular simulations

Phase characterization using FTIR

Phase characterization using Raman spectroscopy

Phase characterization using SANS

Phase separation characterizations

Phase stability characterization

Phase transition characterization

Reversed-phase selectivity characterization

Reversed-phase stationary phases characterization

Shape selectivity phase characterization

Solid-phase extractions characterization

Sponge phases characterization

Stationary Phase Characterization with Empirical LFER Parameters

Stationary phases characterization

Three-phase fluidized beds characterization

Two Simple Tests for the Characterization of RP Phases

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