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Crystal precipitation prevention

In general, saliva (as well as plaque fluid) is supersaturated with respect to calcium-phosphate salts, and they prevent tendency to dissolve mineral crystals of teeth. Moreover, precipitation of calcium-phosphate salts that include hydroxyapatite may also occur (remineralization) in early lesions of tooth surfaces injured by acidic bacterial products (i.e., lactic acid). Salivary fluoride facilitates calcium-phosphate precipitation, and such crystals (i.e., fluorapatite) show lower acid solubility properties that lead to an increased caries preventive effect. The increase of pFI (i.e., buffer capacity and pH of saliva, as well as ureolysis in dental plaque) also facilitates crystal precipitation and remineralization (4, 13). [Pg.2059]

Since these examples are for research-laboratory work, economic concerns such as solvent recovery, reuse, or cost are not considered. Solvents such as acetonitrile or tetrahydrofuran have some immiscibility properties that are quite useful in laboratory work. However, economic costs would likely prevent their use in a commercial process. The goal in each example is to end up with a solvent extract that can easily be vacuum-concentrated and used in final purification steps (i.e., crystallization, precipitation, chromatography). [Pg.64]

A gel network which involves folded-chain, lamellar crystals can be obtained by cooling a semi-dilute solution of ultra-high molecular weight polyethylene (UHMW-PE). The usual chain-folded crystallization occurs, but, because of the high molecular weight, complete disentanglement with the resulting crystal precipitation is prevented, and a gel network forms, provided that each lamella is connected... [Pg.284]

The chemistry of the aqueous sol-gel process is quite complex due to metal and the double role of water as ligand and solvent as well as due to the large number of reaction parameters that have to be stricdy controlled (hydrolysis and condensation rate of the metal oxide precursors, pH, temperature, method of mixing, rate of oxidation, the nature and concentration of anions, etc.) in order to provide good reproducibility of the synthesis protocol. Another fundamental problem of aqueous sol-gel chemistry is that the as-synthesized precipitates are generally amorphous. The required postsynthetic annealing step to induce the crystallization process prevents any subtle control over crystal size and shape. For the preparation of bulk metal oxides, like the ceramic pigment case, these limitations play only a minor role however, in the case of nanoparticle synthesis, they constitute a major concern. [Pg.1159]

During the synthesis of TPU crystallization, precipitation and phase separation processes ean prevent the formation of a block copolymer proposed by statistics [1-4], It is also known that the processing can cause transurethanification reactions [4],... [Pg.563]

Hydrogenis prevented from forming a passivating layer on the surface by an oxidant additive which also oxidizes ferrous iron to ferric iron. Ferric phosphate then precipitates as sludge away from the metal surface. Depending on bath parameters, tertiary iron phosphate may also deposit and ferrous iron can be incorporated into the crystal lattice. When other metals are included in the bath, these are also incorporated at distinct levels to generate species that can be written as Zn2Me(P0 2> where Me can represent Ni, Mn, Ca, Mg, or Fe. [Pg.222]

Sca.Ie nd Sta.in Controllers. Polyacrjiates (low molecular weight) and organic phosphonates, eg, (l-hydroxyethyhdene)diphosphonic acid, prevent or control precipitation of CaCO by acting as chelating agents (qv) or dispersants (qv) to prevent excessive formation of hard scale by promoting crystal distortion. [Pg.302]

Anhydrous zinc chloride can be made from the reaction of the metal with chlorine or hydrogen chloride. It is usually made commercially by the reaction of aqueous hydrochloric acid with scrap zinc materials or roasted ore, ie, cmde zinc oxide. The solution is purified in various ways depending upon the impurities present. For example, iron and manganese precipitate after partial neutralization with zinc oxide or other alkah and oxidation with chlorine or sodium hypochlorite. Heavy metals are removed with zinc powder. The solution is concentrated by boiling, and hydrochloric acid is added to prevent the formation of basic chlorides. Zinc chloride is usually sold as a 47.4 wt % (sp gr 1.53) solution, but is also produced in soHd form by further evaporation until, upon cooling, an almost anhydrous salt crystallizes. The soHd is sometimes sold in fused form. [Pg.423]

Ghelants and Precipitation Inhibitors vs Dispersants. Dispersants can inhibit crystal growth, but chelants, such as ethylenediaminetetraacetic acid [60-00-4] (EDTA), and pure precipitation inhibitors such as nitrilotris(methylene)tris-phosphonic acid [6419-19-8], commonly known as amino trismethylene phosphonic acid (ATMP), can be more effective under certain circumstances. Chelants can prevent scale by forming stoichiometric ring stmctures with polyvalent cations (such as calcium) to prevent interaction with anions (such as carbonate). Chelants interact... [Pg.149]

The reaction mixture is not cooled during the addition of the last two or three portions of phenyl isocyanate, so that the final temperature is near 25° this procedure prevents separation of the sodium salt of cyanophenylurea, which crystallizes readily at low temperatures. For the same reason, the filtered solution of the salt is not precooled, but rather is cooled during the precipitation of the free cyanourea. [Pg.10]

The fi-compound is dissolved in 50 c c. pure dry ether, and dry hydiogen chloride is passed in with constant shaking to prevent the delivery tube from becoming blocked. Colourless crystals of the hydrochloride of the /3-o ime separate and aie filtered and washed with dry ether and then placed in a separating funnel and covered with a layer of ether. A. concentrated solution of sodium carbonate is gradually added with constant shaking until no further effervescence is observed. Sodium chloride is precipitated and the /3-oxime dissolves in the ether. The ether extract is sepaiated, dehydrated over sodium sulphate, and the ether remoi ed as rapidly as possible at the ordinary temperature by evaporation in vacuo. The residue crystallises, and when pressed on a porous plate leaves a mass of small silky needles, m. p. 126—130A It may be re-... [Pg.198]

Re-crystallization also leads to a significant reduction in the level of carbon and oxygen impurities however, the reduction of cationic impurities is usually not efficient. To prevent co-precipitation of complex fluorotantalates of polyvalent metals, some suitable complexonates are added to the solution. [Pg.318]

Far less than the stoichiometric amount of sequestrants precipitation of insoluble salts from water hardness can be prevented by slowing down the formation of crystals and crystal growth. This process is called the threshold effect. It has long been used in the preparation of boiler feeding water, e.g., steam vessels of railroad engines. Originally sodium pyrophosphate was used for this task, but alkylphosphonic acids and derivatives thereof are superior in their effect. [Pg.600]


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See also in sourсe #XX -- [ Pg.373 ]




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Crystallization precipitants

Crystals precipitation

Precipitation prevention

Precipitation-crystallization

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