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Critical reaction separations

S.3.4.3 The Si 2 Reaction HO + CH F The gas-phase nucleophilic substitution reaction was discussed in detail in Section 6.1.1. The generic PES for this reaction, shown in Figure 6.1, is characterized by three critical points separating reactants from prodncts two minima corresponding to entrance and exit ion-dipole complexes separated by a TS. [Pg.536]

A schematic diagram of the SCF reaction/separation process is shown in figure 11.12 (Bhise, 1983). An ethylene oxide-rich CO2 phase is obtained when the aqueous solution is mixed with near-critical or supercritical CO2 at temperatures up to 100°C and pressures ranging to 300 bar. The ethylene... [Pg.327]

It is clear from the several examples cited in this chapter that supercritical fluids can be advantageously used as reaction media but many unanswered questions remain. How do near-critical or supercritical conditions affect the rates and paths of chemical reactions How is the phase behavior of the initial reactants affected by product formation Is it possible to exploit the above results to devise efficient reaction/separation schemes These questions pose considerable experimental and theoretical challenges. [Pg.332]

We choose the initial conditions to be /o(x, 0) = 1 for jc <0 and /o(Jt, 0) = 0 for X > 0. This initial condition describes, for example, a territory divided into an invaded zone, x < 0, and a noninvaded zone, x > 0, separated by a frontier at X = 0. If particles disperse according to an isotropic random walk with KPP kinetics, this initial condition turns into a front propagating from left to right, i.e., the invasion starts. Since the particle jumps are isotropic, the reaction is responsible for the motion of the front from left to right. It is the reaction process that starts and maintains a successful invasion. A bias to the left in the random walk will hinder the invasion. Therefore we expect that the critical reaction rate is given by a balance between the factor favoring the invasion, the reaction process, and the factor opposing the invasion, the bias in the transport process. [Pg.175]

Since Luyben identified the snowball effect (Luyben, 1994), the sensitivity of reactor-separator-recycle processes to external disturbances has been the subject of several studies (e.g., Wu and Yn, 1996 Skogestad, 2002). Recent work by Bildea and co-workers (Bildea et al., 2000 and Kiss et aL, 2002) has shown that a critical reaction rate can be defined for each reactor-separator-recycle process using the Damkohler number. Da (dimensionless rate of reaction, proportional to the reaction rate constant and the reactor hold-up). When the Damkohler number is below a critical value, Bildea et al. show that the conventional unit-by-unit approach in Figure 20.15 leads to the loss of control. Furthermore, they show that controllability problems associated with exothermic CSTRs and PFRs are resolved often by controlling the total flow rate of the reactor feed stream. [Pg.696]

In this chapter, we shall explore why several unit operations using critical fluids, separately or coupled, are frequently needed to produce a desired end product. Figure 1 depicts several process sequence possibilities that could use supercritical fluids for isolating or synthesizing the desired end products. SFE can be used to directly produce extracts or products. For example, the SFE of coffee beans results in a product that has been decaffeinated [1] for consumer use, while alternatively SFE can produce an extract from hops [2] that has commercial utility. However, such ideal scenarios are the exception to the rule, and more recently other applications of supercritical fluids have been explored which utilize supercritical fluid fractionation (SFF) or supercritical fluid reactions (SFR) to affect the desired end result. [Pg.451]

Impurities, surface-active agents, and small changes in chemical composition can be critical in determining drop size distribution. Performance can change dramatically due to small changes in composition, even at the parts per million level, particularly for reactions, separations, and preparation of... [Pg.1427]

The controlled thermal decomposition of dry aromatic diazonium fluoborates to yield an aromatic fluoride, boron trifluoride and nitrogen is known as the Schiemann reaction. Most diazonium fluoborates have definite decomposition temperatures and the rates of decomposition, with few exceptions, are easily controlled. Another procedure for preparing the diazonium fluoborate is to diazotise in the presence of the fluoborate ion. Fluoboric acid may be the only acid present, thus acting as acid and source of fluoborate ion. The insoluble fluoborate separates as it is formed side reactions, such as phenol formation and coupling, are held at a minimum temperature control is not usually critical and the temperature may rise to about 20° without ill effect efficient stirring is, however, necessary since a continuously thickening precipitate is formed as the reaction proceeds. The modified procedure is illustrated by the preparation of -fluoroanisole ... [Pg.594]

Batch vs Continuous Reactors. Usually, continuous reactors yield much lower energy use because of increased opportunities for heat interchange. Sometimes the savings are even greater in downstream separation units than in the reaction step itself Especially for batch reactors, any use of refrigeration to remove heat should be critically reviewed. Batch processes often evolve Httle from the laboratory-scale glassware setups where refrigeration is a convenience. [Pg.83]

Such a reaction is controlled by the rate of addition of the acid. The two-phase system is stirred throughout the reaction the heavy product layer is separated and washed thoroughly with water and alkaU before distillation (Fig. 3). The alkaU treatment is particularly important and serves not just to remove residual acidity but, more importantiy, to remove chemically any addition compounds that may have formed. The washwater must be maintained alkaline during this procedure. With the introduction of more than one bromine atom, this alkaU wash becomes more critical as there is a greater tendency for addition by-products to form in such reactions. Distillation of material containing residual addition compounds is ha2ardous, because traces of acid become self-catalytic, causing decomposition of the stiU contents and much acid gas evolution. Bromination of alkylthiophenes follows a similar pattern. [Pg.21]

The oxide exiting either the Barton or ball mill reactor is conveyed by an air stream to separating equipment, ie, settling tank, cyclone, and baghouse, after which it is stored in large hoppers or dmmmed for use in paste mixing. Purity of the lead feed stock is extremely critical because minute quantities of some impurities can either accelerate or slow the oxidation reaction markedly. Detailed discussions of the oxide-making process and product are contained in references 55—57. [Pg.576]

The hydrocarbon gas feedstock and Hquid sulfur are separately preheated in an externally fired tubular heater. When the gas reaches 480—650°C, it joins the vaporized sulfur. A special venturi nozzle can be used for mixing the two streams (81). The mixed stream flows through a radiantly-heated pipe cod, where some reaction takes place, before entering an adiabatic catalytic reactor. In the adiabatic reactor, the reaction goes to over 90% completion at a temperature of 580—635°C and a pressure of approximately 250—500 kPa (2.5—5.0 atm). Heater tubes are constmcted from high alloy stainless steel and reportedly must be replaced every 2—3 years (79,82—84). Furnaces are generally fired with natural gas or refinery gas, and heat transfer to the tube coil occurs primarily by radiation with no direct contact of the flames on the tubes. Design of the furnace is critical to achieve uniform heat around the tubes to avoid rapid corrosion at "hot spots."... [Pg.30]

The reaction conditions can be selected so as to be able to separate substances with the same or similar chromatographic properties (critical substance pairs) by exploiting their differing chemical behavior, thus, making it easier to identify them. Specific chemical derivatization allows, for example, the esterification of... [Pg.56]

The gas chromatograph (GC) resembles the MS in providing both qualitative and quantitative EGA but is significantly slower in operation. The interval between analyses is normally controlled by the retention time of the last component to be eluted from the column such delay may permit the occurrence of secondary reactions between primary products [162]. Several systems and their applications have been described [144,163— 167] sample withdrawal can be achieved [164] without the necessity for performing the reaction in an atmosphere of carrier gas. By suitable choice of separation column or combination of columns [162], it is possible to resolve species which are difficult to measure in a small low-resolution MS, e.g. H20, NH3, CH4, N2 and CO. Wiedemann [168] has made a critical comparison of results obtained by MS and GC techniques and adjudged the quality of data as being about equal. [Pg.22]


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