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Bromide copper

Traces of bromine, carried over with the gas, are removed by the copper turnings as black copper bromide if the level of the blackened copper in tube F rises appreciably, excessive amounts of bromine are being carried over. [Pg.182]

Brom-jod, n. iodine bromide, -kalium, n. potassium bromide, -kalzium, n., kalk, tn. calcium bromide, -kampher, tn. bromo-camphor, Pharm.) monobromated camphor, -kohlenstoff, tn. carbon (tetra)bromide. -korper, tn. Colloids) "bromide body (bromide ion), -kupfer, n. copper bromide, lauge, /. bromine lye (solution of sodium hypobromite and bromide made by passing bromine into sodium hydroxide solution), -lithium, n. lithium bromide. -Idsung, /. bro-nune solution, -magnesium, n. magnesium bromide. -metall, n. metallic bromide. [Pg.83]

Kupfer-bromid, n. copper bromide, specif, cupric bromide, copper(II) bromide, -bro-mtir, n. cuprous bromide, copper(I) bromide, -chlorid, n. copper chloride, specif, cupric chloride, copper(II) chloride, -chloriir, n. cuprous chloride, copper(I) chloride, -cyamd, Ti. copper cyanide, specif, cupric cyanide, copper(II) cyanide, -cyaniir, n. cuprous cyanide, copper(I) cyanide, -dom, m. slag from liquated copper, -draht, m. copper wire, -drahtnetz, n. copper gauze, -drehspane,... [Pg.265]

The asymmetric addition of different types of nucleophiles at the C-l position of 3,4-dihydroisoquinolines were highlighted in a number of publications. Schreiber et al. described an enantioselective addition of terminal alkynes 136 to 3,4-dihydroisoquinolinium bromide 137 in the presence of triethylamine, catalytic copper bromide, and QUINAP <06OL143>. The resulting 1-substituted tetrahydroquinolines 138 were isolated in high yield and high enantiomeric excess in most cases. [Pg.332]

Scheme 1 Arylcopper-copper bromide aggregates and biaryl formation. Scheme 1 Arylcopper-copper bromide aggregates and biaryl formation.
C for 20 hours. A catalyst system based on copper bromide, an amine, and oxygen was employed in these polymerizations, resulting in PPO yields as high as 83% and M s as high as 1.7 x 104 g/mol. [Pg.135]

Unsymmetrical 3,4-dihalo-l,2,5-thiadiazoles 118 and 119 were prepared from 3-amino-4-chloro-l,2,5-thiadiazole 117 via a Sandmeyer-like reaction involving successively tert-butyl nitrite and either copper bromide or copper iodide in anhydrous acetonitrile (Scheme 17) <2003H(60)29>. The bromo and iodo thiadiazoles 118 and 119 undergo selective Stille and Suzuki C-C coupling chemistry (see Section 5.09.7.6). [Pg.538]

The selective functionalization of methylamines can be effected with catalytic amounts of copper bromide in the presence of peroxides. Both sp3 - and r/>-bonds are functionalized in this reaction (Equation (29)).38... [Pg.112]

Copper bromide has been used by Srebnik and co-workers to homocouple vinyl zirco-nocenes 75, thereby providing access to 2,3-dibora-1,3-butadienes (e. g., 76 Scheme 4.45), which retain their original geometrical relationships [76], These dimerizations readily take place at room temperature the products are stable to both air and moisture and can be purified by column chromatography on silica gel. Prolonged heating of the product at 150 °C was found not to lead to decomposition or even isomerization. Similarly, precur-... [Pg.131]

A new heterocyclic system, 3 ,4-dihydro-3//-benzo[4,5]imidazo[l,2-f]oxazol-l-one 462, was synthesized by reaction of 4,4-dimethyl-5-methylene-l,3-dioxolan-2-one with o-phenylenediamine in the presence of copper bromide as catalyst in carbone dioxide at 60-80 °C under high pressure (Equation 217) <1999CHC216>. [Pg.187]

Copper ) bromide, molecular formula and uses, 7 1111 Copper cable, 17 848 Copper-cadmium alloys, 4 502 Copper(II) carbonate, molecular formula and uses of basic, 7 1111 Copper(II) carbonate hydroxide, 7 768-769 Copper(II) carboxylates, in VDC polymer stabilization, 25 720... [Pg.218]

The beneficial effect of added phosphine on the chemo- and stereoselectivity of the Sn2 substitution of propargyl oxiranes is demonstrated in the reaction of substrate 27 with lithium dimethylcyanocuprate in diethyl ether (Scheme 2.9). In the absence of the phosphine ligand, reduction of the substrate prevailed and attempts to shift the product ratio in favor of 29 by addition of methyl iodide (which should alkylate the presumable intermediate 24 [8k]) had almost no effect. In contrast, the desired substitution product 29 was formed with good chemo- and anti-stereoselectivity when tri-n-butylphosphine was present in the reaction mixture [25, 31]. Interestingly, this effect is strongly solvent dependent, since a complex product mixture was formed when THF was used instead of diethyl ether. With sulfur-containing copper sources such as copper bromide-dimethyl sulfide complex or copper 2-thiophenecarboxylate, however, addition of the phosphine caused the opposite effect, i.e. exclusive formation of the reduced allene 28. Hence the course and outcome of the SN2 substitution show a rather complex dependence on the reaction partners and conditions, which needs to be further elucidated. [Pg.56]

Copper bromide and pentakis-A-(heptadecafluoroundecyl)-l,4,7-triazeheptane (1 in Figure 10.9), along with an initiator, ethyl-2-bromoisobutyrate (2 in Figure 10.9), in a perfluoromethylcyclohexane-toluene biphase efficiently catalyse the polymerization of methyl methacrylate, with a conversion of 76 % in 5 h at 90 °C. The resultant polymer has a Mn = 11100 and a molar mass distribution of 1.30. After polymerization, the reaction was cooled to ambient temperature, the organic layer removed and found to contain a copper level of 0.088 % (as opposed to 1.5% if all the catalyst were to have remained in the polymer). A further toluene solution of monomer and 2 could be added,... [Pg.214]

The protected propargylamines 224 (R = H, CH2C02Me or CH2CH2C02Me) react with aqueous formaldehyde under copper bromide catalysis to yield the allene derivatives 225. Deprotection with ethereal hydrogen chloride affords the free amines218. [Pg.576]

So far, only cuprates with a 1 1 copper/lithium ratio have been considered. Treatment of phenyllithium with various substoichiometric quantities of copper bromide in DMS as solvent afforded so-called higher order cuprates, of which two were characterizable by X-ray crystallography. These have the overall stoichiometries Cu2Li3Ph5(DMS)4 and Cu4Li5Ph9(DMS)4 [114, 115). The structure of the former compound in the solid state is shown in Fig. 1.26. [Pg.30]

In the improved synthesis of Ifetroban described above, environmental concerns due to special handling of copper bromide waste and hazards associated with hexa-methylene tetramine (HMT) on manufacturing scale led to further perfection of the synthesis. Mechanistic considerations suggested that an oxidized form of aminoamide B (Scheme 4) would eliminate the necessity for a late-stage copper-mediated oxidation. This was indeed accomplished. The cyclization-elimination sequence was initiated by a Lewis acid and completed by base-mediated elimination to afford the Ifetroban penultimate. In addition to eliminating the need for copper bromide and HMT, this modification helped to reduce the cost of the product by an additional 15%. [Pg.241]

Commercial copper bromide or its dimethyl sulfide complex contains impurities that are deleterious to the reaction. Therefore, the copper(l) bromide-dimethyl sulfide complex is prepared according to the method of House from copper(l) bromide generated by reduction of copper(ll) bromide (Aldrich Chemical Company, Inc., 99%) with sodium sulfite. Best results ctre obtained using copper(l) bromide-dimethyl sulfide complex freshly recrystallized according to the following procedure. [Pg.154]

The reaction of o-nitrobenzaldehydes with some benzene derivatives in the presence of strong acid (H2S04, PPA) is a classical synthesis of acridinol N-oxides (373) (37BSF240) The synthesis works for benzyl alcohol, benzene, toluene and halobenzenes, but not for benzoic acid, benzonitrile, dimethylaniline, or nitrobenzene. Isoquinoline N-oxides (374) have been obtained from o-bromobenzaldoxime or the acetophenone derivative, and active methylene compounds with copper bromide and sodium hydride (77S760). The azobenzene cobalt tricarbonyl (375) reacts with hexafluorobut-2-yne to give a quinol-2-one (72CC1228), and the 3,4,5-tricyanopyridine (376) is formed when tetracyanoethylene reacts with an enaminonitrile (80S471). [Pg.449]

When more than 0.50 mol of Mg is used and the allyl bromide is added too quickly, the solution may contain some H2C-CHCH2MgBr. The copper bromide is added to complete the reaction between allyl bromide and HjCsCHCf MgBr. [Pg.203]

Cumene Hydroperoxide Copper Acetate Copper Arsenite Copper Bromide Copper Chloride Copper Fluoioborate Copper Arsenite Copper Cyanide Copper Nitrate Copper Oxalate Copper Sulfate... [Pg.37]


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1,2-diols, copper®) bromide

1.2- Diol oxidations, copper bromide

Acids Copper bromide

Alkenes brominations, copper bromide

Alkynes brominations, copper®) bromide

Amides copper bromide

Amines oxidations, copper bromide

Amines, copper®) bromide

Aromatic compounds copper bromide

Brominations copper bromide

Complex with copper bromide

Copper I) bromide

Copper bromide carbonyl compounds

Copper bromide halogenation

Copper bromide ketone dehydrogenation

Copper bromide methoxide

Copper bromide values of properties

Copper bromide, bromination of ketones

Copper bromide, chloride

Copper bromide, solubility

Copper bromide-Dimethyl sulfide

Copper bromide-dimethyl sulfide complex

Copper bromide-dioxane

Copper complexes bromides

Copper compounds bromide

Copper cuprous bromide

Copper® bromide catalyst

Copper® bromide purification

Copper® bromide, calculating solubility

CuBr Copper bromide

Dehydrogenation copper bromide

Diphenyl copper bromide

Diphenyl copper bromide/chloride

Ketones copper bromide

Lewis acids copper bromide

Oxidants, palladium-catalyzed reactions, copper®) bromide

Oxidations copper®) bromide

Oxidative coupling copper® bromide

Palladium-catalyst oxidants copper®) bromide

Primary alcohols copper bromide

Sandmeyer reactions, copper®) bromide

Session IV Thermochemical copper chloride and calcium bromide processes

Triphenylphosphine-copper bromide

Ullmann coupling copper® bromide

Vinylmagnesium bromide-copper iodide

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