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Hexa methylene

After having been cooled it is washed three times in water, three times in a 5% solution of caustic soda, and then another three times in water. The solution in xylene is dried over sodium sulfate and the xylene is completely distilled off in vacuo. Thus 11.0 parts of hexa-methylene-bis-(N-methyl carbamic acid-3-pyridyl ester) are obtained. [Pg.527]

Fig. 53.—Molecular weight distribution in poly-(hexa-methylene adipamide) as obtained by fractionation (points) compared with curves calculated from Eq. (3) for two values of p, (Taylor. )... Fig. 53.—Molecular weight distribution in poly-(hexa-methylene adipamide) as obtained by fractionation (points) compared with curves calculated from Eq. (3) for two values of p, (Taylor. )...
In the improved synthesis of Ifetroban described above, environmental concerns due to special handling of copper bromide waste and hazards associated with hexa-methylene tetramine (HMT) on manufacturing scale led to further perfection of the synthesis. Mechanistic considerations suggested that an oxidized form of aminoamide B (Scheme 4) would eliminate the necessity for a late-stage copper-mediated oxidation. This was indeed accomplished. The cyclization-elimination sequence was initiated by a Lewis acid and completed by base-mediated elimination to afford the Ifetroban penultimate. In addition to eliminating the need for copper bromide and HMT, this modification helped to reduce the cost of the product by an additional 15%. [Pg.241]

Statistical copolymerization of ethylene glycol and 1,4-butanediol with dimethyl ter-ephthalate results in products with improved crystallization and processing rates compared to poly(ethylene terephthalate). Polyarylates (trade names Ardel, Arylon, Durel), copolymers of bisphenol A with iso- and terephthalate units, combine the toughness, clarity, and proce-sibility of polycarbonate with the chemical and heat resistance of poly(ethylene terephthalate). The homopolymer containing only terephthalate units is crystalline, insoluble, sometimes infusible, and difficult to process. The more useful copolymers, containing both tere- and isophthalate units, are amorphous, clear, and easy to process. Polyarylates are used in automotive and appliance hardware and printed-circuit boards. Similar considerations in the copolymerization of iso- and terephthalates with 1,4-cyclohexanedimethanol or hexa-methylene diamine yield clear, amorphous, easy-to-process copolyesters or copolyamides,... [Pg.141]

The aerosol technique can also be used to produce polymer colloids by addition polymerization. Thus, when droplets of toluene-2,4-diisocyanate (TD1) or 1,6-hexa-methylene diisocyanate (HDI) were brought into contact with ethylenediamine (EDA) vapor (in the apparatus shown in Fig. 1.5.3) spherical polyurea particles with modal diameters of 1-3 p,m were formed. The entire process, i.e., the formation of droplets and the polymerization, was carried out at moderate temperatures (<80°C)... [Pg.106]

Ammonia is used in the production of several chemicals to make nylon adipic acid, hexa-methylene diamine, and caprolactam. It is used to treat metals in annealing, nitriding, and descaling. Ammonia is an excellent fungicide that is used to treat citric fruit. It is also used to increase the nitrogen content of crops used as feed for livestock. Ammonia dissolves readily in water to produce aqueous ammonia or ammonium hydroxide NH + 2 < > NH4+(a(i) + OH (ahydroxide ions shows that ammonia acts as a base in aqueous solution. Concentrated aqueous solutions contain 35% ammonia. Household ammonia cleaners contain between 5% and 10% ammonia. [Pg.29]

Polyurethanes. Metal-containing polyurethanes have been synthesized by poly-condensing Co2+, Cu2+ salts of mono(hydroxyethyl) phthalate with hexa-methylene diisocyanate and tolylene diisocyanates [47] (Fig. 19). [Pg.102]

In contrast to urea itself, its N-methylated derivatives enhance water-water interactions, i.e. lower the structural temperature hexa-methylene tetramine produces similar marked effects (Barone et al., 1968). Glycine and /3-alanine appear to be structure breakers (Devine and Lowe, 1971) according to their effect on the viscosity of water (Herskovitz and Kelly, 1973). The viscosities and diffusion properties of urea solutions show striking changes as the concentration increases (MacDonald and Guerrera, 1970). [Pg.261]

A new method of following rapid rates of crystallization. I. Poly(hexa-methylene adipamide). Polymer 2, 221—223 (1961). [Pg.680]

Nylon. Nylon fibers are made predominantly from either poly(hexa-methylene adipamide) (nylon 66) or polycaproamide (nylon 6). In... [Pg.221]

CsHe Tri-methylene C4H8 Tetra-methylene C5H10 Penta-methylene C6H12 Hexa-methylene... [Pg.460]

Poly-methylenes, Cycle ParaflSns.—The names tetra-methylene or cyclo butane, hexa-methylene or cycle hexane, etc., are analogous to tri-methlyene or cyclo propane. For the homologous series the names poly-methylenes or cyclo parafi s are used. [Pg.462]

While, however, penta-methylene is the most stable ali-cyclic compound of the poly-methylene group it is hexa-methylene which is of special interest and importance. This importance is due to the fact that it is the connecting link between the ali-cyclic compounds (carbo-cyclic compounds not derived from benzene, i.e. the poly methylenes) and benzene itself. Thus it becomes the connecting link between the aliphatic open-chain compounds and the very large and important division including benzene and its derivatives. [Pg.465]

Hexagon Formula.—If in hexa-methylene the six methylene groups are symmetrically arranged we shall have a structural formula represented by a hexagon, as this geometric figure is symmetrical and of six points and six sides. This has been already shown on page 464. [Pg.469]

Hexa-hydro Benzene.—With hydrogen benzene forms a hexa-hydro addition product which is hexa-methylene or cyclo-hexane. [Pg.504]

Character of Center Nucleus.—As was stated in connection with anthracene itself we can not say positively as to the character of the center nucleus in either the hydrocarbon or the quinone. In anthracene the aliphatic character of this center nucleus is indicated by its formation from an ethane residue, by the tetra-brom ethane synthesis. This does not, however, preclude the possibility of its becoming a true benzene nucleus when condensed with two benzene rings, for benzene itself may be made from aliphatic hydrocarbons, from acetylene by polymerization (p. 478), and from hexane through hexa-methylene with the loss of hydrogen after the formation of the cyclo-paraffin (p. 469). Also naphthalene, in which there is no doubt of the benzene character of the two nuclei, may have one nucleus formed from an aliphatic chain as in the syntheses given (p. 767) from phenyl butylene bromide, from phenyl vinyl acetic acid and from tetra-carboxy ethane. In the same way the facts in regard to anthraquinone do not prove... [Pg.798]

The first commercial aliphatic diisocyanate to be available is 1,6-hexa-methylene diisocyanate (HDI). It is a colourless liquid with a boiling point of 127 C at 10 mm Hg. It is less reactive than either TDI or MDI, but in the presence of a catalyst the rate of reaction is enhanced. The use of HDI leads to urethane polymers with better resistance to discolouration, hydrolysis and heat degradation than has TDI (Frisch, 1969). A number of aliphatic diisocyanates have become available commercially. These aliphatic diisocyanates have been reported to give excellent colour stability. Some important ahphatic diisocyanates are illustrated in Figure 2.16. [Pg.45]

One more example of flash pyrolysis is given below for nylon 6,10 or poly(hexa-methylene sebacamide), CAS 9008-66-6, with the idealized formula [-NH(CH2)6NHCO(CH2)8CO-]n. The Py-GC/MS results are shown in Figure 13.3.7. The pyrolysis was done in similar conditions as for other examples, at 600° C in He, and the separation was done on a Carbowax column (see Table 4.2.2). The peak identification was done using MS spectral library searches only and is given in Table 13.3.5. [Pg.608]

Cramer studied the mechanism using Rh compounds [123, 124], The linear dimerization of acrylonitrile in the presence of hydrogen and a ruthenium catalyst to form 1,4-dicyano-l-butene [125-127] received much interest in industrial laboratories, mostly in Japan, so a large number of patents have been filed, in some of which palladium catalysts have also been claimed. The above compound can be hydrogenated to give the industrially important adipodinitrile and hexa-methylene diamine. [Pg.1335]


See other pages where Hexa methylene is mentioned: [Pg.221]    [Pg.741]    [Pg.3]    [Pg.132]    [Pg.691]    [Pg.139]    [Pg.24]    [Pg.186]    [Pg.472]    [Pg.70]    [Pg.98]    [Pg.667]    [Pg.31]    [Pg.12]    [Pg.345]    [Pg.384]    [Pg.3]    [Pg.344]    [Pg.133]    [Pg.132]    [Pg.24]    [Pg.12]    [Pg.701]    [Pg.345]    [Pg.464]    [Pg.465]    [Pg.476]    [Pg.504]    [Pg.621]    [Pg.693]    [Pg.694]    [Pg.822]   
See also in sourсe #XX -- [ Pg.461 , Pg.464 , Pg.468 , Pg.504 , Pg.694 ]

See also in sourсe #XX -- [ Pg.421 ]




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Hexa-methylene diamine

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