Consumption textiles

Synthetic emulsion polymers account for approximately 70% of the U.S. consumption of acrylate monomers. Major end uses for these latex polymers are coatings (32%), textiles (17%), adhesives (7%), paper (5%), and floor poHshes (3%). The U.S. producers of acryflc copolymer emulsions include Rohm and Haas, Reichhold, National Starch, Union Carbide, Air Products, Unocal, B. F. Goodrich, and H. B. Fuller. 

Textile Applications. A 1971 estimate of world textile fiber consumption (2) showed that approximately 60% of textile goods are dyed and about 30% are whites. The proportion of white goods (>40%) is highest for cotton. These percentages also hold tme in the 1990s. 

The greatest amount of surfactant consumption is in packaged soaps and detergents for household and industrial use. The remainder is used in processing textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture of agricultural sprays, cosmetics, elastomers, food, lubricants, paint, pharmaceuticals, and a host of other products. 

Bleaching. The largest single use for hydrogen peroxide in the United States and North America is wood pulp bleaching, but consumption for the manufacture of chemicals, environmental appHcations, and for bleaching cotton (qv), wool (qv), and other textiles (qv) is significant. 

Phthalocyanine pigments account for approximately 23% of the total worldwide organic pigment consumption of 225,000 tons. Approximately 20,000 t are used in printing inks, 10,000 t in paints, 9,000 t in plastics, 3,000 t in textiles, 7,000 t in dyes, and 2,000 t in specialty uses. Table 1 shows the worldwide distribution of cmde phthalocyanine capacity. The production history of phthalocyanine in the United States from 1980 to 1990 is given in Table 2 (161). The 1990 prices of phthalocyanine blue and green pigments were ca 11—22/kg and 21—27/kg, respectively. 

Sulfates of sodium are iadustriaUy important materials commonly sold ia three forms (Table 1). In the period from 1970 to 1981, > 1 million metric tons were consumed aimuaHy ia the United States. Siace then, demand has declined. In 1988 consumption dropped to 890,000 t, and ia 1994 to 610,000 t (1,2). Sodium sulfate is used principally (40%) ia the soap (qv) and detergent iadustries. Pulp and paper manufacturers consume 25%, textiles 19%, glass 5%, and miscellaneous iadustries consume 11% (3). About half of all sodium sulfate produced is a synthetic by-product of rayon, dichromate, phenol (qv), or potash (see Chromium compounds Fibers, regenerated cellulosics Potassium compounds). Sodium sulfate made as a by-product is referred to as synthetic. Sodium sulfate made from mirabilite, thenardite, or naturally occurring brine is called natural sodium sulfate. In 1994, about 300,000 t of sodium sulfate were produced as a by-product another 300,000 t were produced from natural sodium sulfate deposits (4). 

Pig. 3. U.S. consumption of poly(vinyl acetate), where A represents paints B, adhesives C, paper coatings D, textiles E, other and P, total. 

Wool belongs to a family of proteins, the keratins, that also includes hair and other types of animal protective tissues such as horn, nails, feathers, and the outer skin layers. The relative importance of wool as a textile fiber has declined over the decades as synthetic fibers have increa singly been used in textile consumption. Wool is still an important fiber in the middle and upper price ranges of the textile market. It is also an extremely important export for several nations, notably AustraUa, New Zealand, South Africa, and Argentina and commands a price premium over most other fibers because of its outstanding natural properties of soft handle (the feel of the fabric), moisture absorption abiUties (and hence comfort), and superior drape (the way the fabric hangs) (see Fibers Textiles). Table 2 shows wool production and sheep numbers in the world s principal wool-producing countries. 

The largest volume commercial derivatives of 1-butanol are -butyl acrylate [141-32-2] and methacrylate [97-88-1] (10). These are used principally ia emulsion polymers for latex paints, ia textile appHcations and ia impact modifiers for rigid poly(vinyl chloride). The consumption of / -butanol ia the United States for acrylate and methacrylate esters is expected to rise to 182,000—186,000 t by 1993 (10). 

From 1980 to 1988, aimual cellulose acetate flake production in the United States showed a slight decrease in production from 392,000 t to 323,000 t with an aimual decline of —0.4 to —0.1% (Table 6). World demand for cellulose acetate flake has also fallen. A modest recovery has occurred in recent years as a result of the increased demand for cigarette-filter tow world consumption of cigarette-filter tow has risen about 2.5% per year since 1980 (Tables 7 and 8). In contrast, world demand for textile fibers and cellulose ester plastics decline 4.6% and 4.2% per year, respectively (Fig. 9). 

The cellulose esters with the largest commercial consumption are cellulose acetate, including cellulose triacetate, cellulose acetate butyrate, and cellulose acetate propionate. Cellulose acetate is used in textile fibers, plastics, film, sheeting, and lacquers. The cellulose acetate used for photographic film base is almost exclusively triacetate some triacetate is also used for textile fibers because of its crystalline and heat-setting characteristics. The critical properties of cellulose acetate as related to appHcation are given in Table 10. 

A rather impressive Hst of materials and products are made from renewable resources. For example, per capita consumption of wood is twice that of all metals combined. The ceUulosic fibers, rayon and cellulose acetate, are among the oldest and stiU relatively popular textile fibers and plastics. Soy and other oilseeds, including the cereals, are refined into important commodities such as starch, protein, oil, and their derivatives. The naval stores, turpentine, pine oil, and resin, are stiU important although their sources are changing from the traditional gum and pine stumps to tall oil recovered from pulping. 

Consumption. Anthraquinone dyes are the most important dye class after azo dyes. Wodd textile production is estimated in Table 14. Estimates of the consumption of dyes for textiles ate given in Figure 14, together with the figures for fiber consumption. This shows that the consumption of each dye class or classes is approximately parallel to the consumption of fibers to which they ate apphed. 

In 1997 it was estimated that global production of PET was about 16.7 X 10 t.p.a., of which 12 million tonnes was used in textiles, 2 million tonnes for audio and video film (with a small quantity for technical mouldings) and 3 million tonnes for packaging, particularly bottles. The tremendous growth in the bottles market from zero in the late 1970s to 1.5 million tonnes in the USA alone in 1998 is, in consumption terms, one of the most spectacular examples of growth in plastics materials in recent times and will be considered later in this section. 

The most prominent aliphatic polyamides are polyamide 6 and polyamide 6.6. Polyamides are used in a broad range of applications as performance polymers in medicine, textile, and car manufacturing industries. In 2003, the European production ofpolyamides was approximately 3 million tons for technical applications. Of the total polyamide consumption, 94% was polyamide 6 and polyamide 6.6. 

The consumption of these phosphonates in textile processing is small in relation to that of the aminopolycarboxylates they are mainly used in detergent formulations [21,22] as sodium, potassium, ammonium or alkanolamine salts. 

Based on the previous studies and the above discussions, it is required to achieve environmentally sustainable development in textile industry since closing of water cycle is highly recommended [29]. It can often be done by the application of the combined membrane-biological processes, especially by the implementation of NF-biological and RO-biological processes, which enables the water reuse process, thereby the minimization of freshwater consumption. 

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