Coal flame temperature

In this work the mode of occurrence of coal silicate minerals, and the flame induced vitrification and sodium initiated sintering mechanisms have been studied. The pulverized coal flame temperature is sufficiently high to vitrify the quartz particles. 

Figure 4 illustrates the trend in adiabatic flame temperatures with heat of combustion as described. Also indicated is the consequence of another statistical result, ie, flames extinguish at a roughly common low limit (1200°C). This corresponds to heat-release density of ca 1.9 MJ/m (50 Btu/ft ) of fuel—air mixtures, or half that for the stoichiometric ratio. It also corresponds to flame temperature, as indicated, of ca 1220°C. Because these are statistical quantities, the same numerical values of flame temperature, low limit excess air, and so forth, can be expected to apply to coal—air mixtures and to fuels derived from coal (see Fuels, synthetic). 

Air for the hot blast may also be considered a raw material. The air is preheated in stoves to between 900 and 1300°C. Over 1.5 t of air is required to produce 11 of hot metal (pig iron). SoHd, Hquid, or gaseous fuels, eg, coal, fuel oil, or natural gas, may be added to the hot blast at the tuyeres to replace some of the coke. Oxygen may also be added to the hot blast to increase flame temperature. 

Computer controls are likewise used for stove operation, to control deUvery of the hot blast. High hot blast temperatures are generally desirable, as these reduce the coke rate. Control of the flame temperature in the raceway is effected by controlled additions to the hot blast, primarily of moisture. Injectants into the tuyeres such as coal, oil, and natural gas are often used to replace some of the coke. The effect of these injectants on flame temperature must be accounted for, and compensation is performed by lowering moisture or adding oxygen. 

Another furnace that does not require fuel preparation is the stoker boiler, which was used by New York State Electric Gas Corporation (NYSEG) in its TDE tests. At NYSEG, the stoker boiler, which has a 1649°C (3000°E) flame temperature (as does the cyclone boiler), has routinely blended low quaUty coal, and more recently, wood chips with its standard coal to reduce fuel costs and improve combustion efficiency. In the tire-chip tests, NYSEG burned approximately 1100 t of tire chips (smaller than 5x5 cm) mixed with coal and monitored the emissions. The company determined that the emissions were similar to those from burning coal alone. In a second test-bum of 1900 t of TDE, magnetic separation equipment removed metal from the resulting ash, so that it could be recycled as a winter traction agent for roadways. 

An interesting feature of these high-temperature-calcination apph-cations is the direct injeciion of either heavy oil, natural gas, or nue coal into the fluidized bed. Combustion takes place at well below flame temperatures without atomization. Considerable care in the design of the fuel- and air-supply system is necessary to take full advantage of the fluidized bed, which sei ves to mix the air and fuel. 

It is interesting to note that stratified combustible gas mixtures can exist in tunnel-like conditions. The condition in a coal mine tunnel is an excellent example. The marsh gas (methane) is lighter than air and accumulates at the ceiling. Thus a stratified air-methane mixture exists. Experiments have shown that under the conditions described the flame propagation rate is very much faster than the stoichiometric laminar flame speed. In laboratory experiments simulating the mine-like conditions the actual rates were found to be affected by the laboratory simulated tunnel length and depth. In effect, the expansion of the reaction products of these type laboratory experiments drives the flame front developed. The overall effect is similar in context to the soap bubble type flame experiments discussed in Section C5c. In the soap bubble flame experiment measurements, the ambient condition is about 300 K and the stoichiometric flame temperature of the flame products for most hydrocarbon fuels... 

Low-NO burners are designed to delay and control the mixing of coal and air in the main combustion zone. A typical low-NO air-staged burner is illustrated in Fig. 24-16. This combustion approach can reduce NO emissions from coal burning by 40 to 50 percent. Because of the reduced flame temperature and delayed mixing in a low-NO burner, unburned carbon emissions may increase in some apphcations and for some coals. Overfire air is another technique for... 

Although the data presented here are limited to a single coal burned in two combustor operating modes, several important observations can be made about the fine particles generated by pulverized coal combustion. The major constituents of the very small nucleation generated particles vary with combustion conditions. High flame temperatures lead to the volatilization of refractory ash species such as silica and alumina, probably by means of reactions which produce volatile reduced species such as SiO or Al. At lower flame temperatures which minimize these reactions other ash species dominate the fine particles. Because the major constitutents of the fine particles are relatively refractory, nucleation is expected to occur early in the combustion process. More volatile species which condense at lower temperatures may also form new particles or may condense on the surfaces of the existing particles. Both mechanisms will lead to substantial enrichment of the very small particles with the volatile species, as was observed for zinc. 

Around 60% of the commercial explosives produced in India are used by the mining industry. Permitted and conventional explosives are extensively used for gassy and open pit mines. In the majority of coal mines, particularly those located in the Indian State of Bihar, there is a continuous evolution of methane gas which forms an explosive mixture with air. By suitably reducing the flame temperature (Tf) and duration of explosion, the ignition of explosive mixture (methane + air) is considerably reduced. 

After World War I the use of ammonals was restricted to quarrying in coal mines they were banned since their high flame temperature (due to presence of metallic aluminium) makes them inherently dangerous there. 

All boiler temperatures were measured just prior to and after the collection of the coal samples and their respective fly ashes, since it was physically impractical to collect the samples and measure the temperatures at the same times. In all cases, the temperatures remained essentially constant. An optical pyrometer was used to measure flame temperatures, and water-cooled jacketed thermocouples were used to monitor the boiler temperatures. The wall effects on the temperature measurements were minimized by insertion of the thermocouple into the boiler until temperatures remained constant with distance upon further insertion of the thermocouple into the boiler. 

Howard and Essenhigh [5] pyrolyzed coal particles, burning them in a one-dimensional plane-flame furnace. They measured the solid composition and the flame temperature along the axis of propagation. Particles attained a temperature of about 1100°C without ignition or significant devolatilization. They found that devolatilization of 0-200 p,m particles seems to be a volumetric reaction that is independent of particle size. 

---