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Chlorites

Kinetic studies showed that the dihydroxylation of styrene using NaC102 was twice as fast as in the established Sharpless K3[Fe(CN)6] protocol. This higher reaction rate can be attributed to the oxidation of an osmium(VI) mono(glycolate) to corresponding osmium(VIII) mono (glycolate) before hydrolysis. As the concentration [Pg.8]

The reaction involving chlorite and iodide ions in the presence of malonic acid, the CIMA reaction, is another that supports oscillatory behaviour in a batch system (the chlorite-iodide reaction being a classic clock system the CIMA system also shows reaction-diffusion wave behaviour similar to the BZ reaction, see section A3.14.4). The initial reactants, chlorite and iodide are rapidly consumed, producing CIO2 and I2 which subsequently play the role of reactants . If the system is assembled from these species initially, we have the CDIMA reaction. The chemistry of this oscillator is driven by the following overall processes, with the empirical rate laws as given ... [Pg.1102]

De Kepper P, Boissonade J and Epstein I R 1990 Chlorite-iodide reaotion a versatile system for the study of nonlinear dynamioal behaviour J. Phys. Chem. 94 6525-36... [Pg.1116]

Consequently, when D /Dj exceeds the critical value, close to the bifurcation one expects to see the appearance of chemical patterns with characteristic lengtli i= In / k. Beyond the bifurcation point a band of wave numbers is unstable and the nature of the pattern selected (spots, stripes, etc.) depends on the nonlinearity and requires a more detailed analysis. Chemical Turing patterns were observed in the chlorite-iodide-malonic acid (CIMA) system in a gel reactor [M, 59 and 60]. Figure C3.6.12(a) shows an experimental CIMA Turing spot pattern [59]. [Pg.3069]

Ammonia, anhydrous Mercury, halogens, hypochlorites, chlorites, chlorine(I) oxide, hydrofluoric acid (anhydrous), hydrogen peroxide, chromium(VI) oxide, nitrogen dioxide, chromyl(VI) chloride, sulflnyl chloride, magnesium perchlorate, peroxodisul-fates, phosphorus pentoxide, acetaldehyde, ethylene oxide, acrolein, gold(III) chloride... [Pg.1207]

Oxalic acid Furfuryl alcohol, silver, mercury, sodium chlorate, sodium chlorite, sodium hypochlorite... [Pg.1210]

Sodium chlorite [sodium chlorate (IV)] Sodium peroxide ... [Pg.1213]

Chlorine oxygen acids and salts, chlorous acid, chlorites, and chlorine dioxide... [Pg.196]

Cm ORINE OXYGEN ACIDS AND SALTS - DICTD ORINE MONOXIDE, HYPOCTD.OROUS ACID, AND HYPOCm ORITES] (Vol 5) Chlorous acid, chlorites, and chlorine dioxide... [Pg.204]

The most common chemical bleaching procedures are hypochlorite bleach for cotton hydrogen peroxide bleach for wool and cotton sodium chlorite bleach for cotton, polyamide, polyester, and polyacrylonitrile and reductive bleaching with dithionite for wool and polyamide. [Pg.119]

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ALKYL CHLORITES

Acidified Sodium Chlorite Solutions

Acidified chlorite

Acidified sodium chlorite

Acidified sodium chlorite developmental toxicity

Activators chlorite bleaching

Advantage chlorite

Ammonium Chlorite

Analytical Procedures for Chlorites

Barium chlorate chlorite

Barium chlorite

Barium chlorite, decomposition

Bleaching with sodium chlorite

Bromate-chlorite-iodide reaction

CHLORITE SALTS

CHLOROUS ACID, CHLORITES, AND CHLORINE DIOXIDE

Calcium Chlorite

Calcium bromate chlorite

Carboxylic acids Sodium chlorite

Carboxylic acids with sodium chlorite

Cation exchange capacity chlorite

Chemical chlorite

Chlorine dioxide chlorite complex

Chlorine dioxide sodium chlorite

Chlorine dioxide sodium chlorite feed

Chlorine dioxide/chlorite

Chlorine sodium chlorite solid generator

Chlorite allevardite

Chlorite and chlorate

Chlorite anions

Chlorite bleaching

Chlorite bleaching corrosion

Chlorite cement

Chlorite cement authigenic

Chlorite chemical analyses

Chlorite classification

Chlorite clay interlayers

Chlorite clay minerals

Chlorite clay occurrence

Chlorite clay octahedral sheet, composition

Chlorite clay origin

Chlorite clay structural formulas

Chlorite coatings

Chlorite composition

Chlorite determination

Chlorite dioctahedral

Chlorite dismutase

Chlorite esters

Chlorite exchange capacity

Chlorite formation from biotite

Chlorite formation from vermiculite

Chlorite group minerals

Chlorite hydrothermal studies

Chlorite illite facies

Chlorite in soils

Chlorite ion

Chlorite ion and chlorine dioxide

Chlorite layer charge

Chlorite luminescence

Chlorite macroscopic

Chlorite minerals

Chlorite occurrence

Chlorite octahedral sheet

Chlorite oxidation

Chlorite phase compositions

Chlorite polymorphs

Chlorite process

Chlorite properties

Chlorite reaction with

Chlorite removal

Chlorite rims

Chlorite stacking

Chlorite structure

Chlorite synthesis

Chlorite tetrahedral sheet, composition

Chlorite trioctahedral

Chlorite variations, structural

Chlorite, 221 table

Chlorite, iodine oxidation

Chlorite, layered silicate

Chlorite, oxidation with

Chlorite-based oscillators

Chlorite-iodide reaction

Chlorite-iodide reaction mechanism

Chlorite-iodide reaction model

Chlorite-iodide-malonic acid

Chlorite-iodide-malonic acid reaction

Chlorite-iodide-malonic acid reaction, Turing patterns

Chlorite-iodine-malonic acid reaction

Chlorite-montmorillonite

Chlorite-tetrathionate reaction

Chlorite-thiosulfate reaction

Chlorite-thiosulfate reaction, chaotic

Chlorite-thiosulfate reaction, chaotic oscillation

Chlorite-thiosulfate system

Chlorite-vermiculite

Chlorites, CIO

Chlorites, inorganic

Chlorites, metal, decompositions

Chloritization

Chlorous acid and the chlorites

Cobalt complexes chlorites

Cupric Chlorite

Dimethyl sulfoxide chlorite

Drinking water chlorite

Experimental Studies on Magnesian Chlorites

F Malononitrile Mercury chlorite

Holocellulose chlorite

Hydrazine chlorite

Hydroxylamine chlorite

Illite-chlorite

Illite-chlorite-montmorillonite

Infrared absorption chlorites

Isomorphous substitution chlorites

Lead bromate chlorite

Lead chlorite

Lead chlorite, decomposition

Lithium chlorite

Maturity chlorite

Mercuric bromate chlorite

Mercurous bromate chlorite

Mercury chlorites

Merits and demerits of chlorite bleaching

Metamorphism chlorites

Mg-chlorite

Nickel chlorite

Oscillator chlorite

Oscillator chlorite-iodate-arsenite

Oscillatory reactions chlorite-iodide reaction

Oxidation of chlorite

Oxidation using hypochlorite and chlorite anions

Oxidation with Chlorous Acid and the Chlorites

Oxidation with sodium chlorite

Oxidizers chlorites

Polymorphism chlorites

Polytypes chlorite

Potassium chlorite

Sedimentary 7 A Chlorites

Silver bromate chlorite

Silver chlorite

Silver chlorite, decomposition

Sodium Chlorite Feed Calculators

Sodium bisulfite chlorite

Sodium chlorate chlorite

Sodium chlorite

Sodium chlorite and chlorate

Sodium chlorite bleaching

Sodium chlorite example)

Sodium chlorite manufacture

Sodium chlorite oxidant

Sodium chlorite oxidation

Sodium chlorite preparation

Sodium chlorite reproductive and developmental toxicity

Sodium chlorite, analysis

Sodium chlorite, decomposition

Sodium chlorite, hazards with

Soil chlorites

Solvation chlorites

Strontium bromate chlorite

Strontium chlorite

Structural chlorite

Structural serpentine-chlorite

Sulfuric acid chlorite

Synthetic minerals chlorites

Talc chlorite

Tetramethylammonium chlorite

Thallous Chlorite

The Chlorites

Thermal characteristics and estimation of soil chlorites

Trioctahedral clay chlorite

Trioctahedral minerals chlorites

Vermiculite association with chlorite

Weathering chlorites

With sodium chlorite

Zinc chlorite

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