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Chlorine-Chlorosulfonic acid

The chemical resistance of PTFE is almost universal It resists attack by aqua regia, hot fummg nitnc acid, hot caustic, chlorine, chlorosulfonic acid, and all solvents. Despite this broad chemical resistance, PTFE is attacked by molten alkali metals, ammonia solutions of such metals, chlorine trifluoride, and gaseous fluonne at elevated temperature and pressure PTFE swells or dissolves m certam highly fluonnated oils near its melting point. Specific lists of chemicals compatible with PTFE are available [/.8]... [Pg.1106]

The selective a-chlorination of propionic acid was achieved by heating the acid with a mixture of chlorine, chlorosulfonic acid and oxygen in a semibatch reactor at 70-110 °C. The kinetics of the chlorination were autocatalytic, when the concentration of the chlorosulfonic acid catalyst was kept constant. The primary product was sulfopropionic acid and the autocatalytic kinetics were explained by a mechanism involving acid-catalysed enolization of the key intermediate, propanoyl chloride, as the rate-determining step. ° ... [Pg.171]

This simplified method gives 2-aminothiazole in good yield (50 to 70%) (311, 330), Other reactants can replace iodine, for example, chlorine, bromine, sulfuryl chloride, chlorosulfonic acid, or sulfur monochloride also give good results. [Pg.214]

Alkylation. Ben2otrifluoride can also be alkylated, eg, chloromethyl methyl ether—chlorosulfonic acid forms 3-(trifluoromethyl)ben2yl chloride [705-29-3] (303,304), which can also be made from / -xylene by a chlorination—fluorination sequence (305). Exchange cyanation of this product in the presence of phase-transfer catalysts gives 3-(trifluoromethylphenyl)acetonitrile [2338-76-3] (304,305), a key intermediate to the herbicides flurtamone... [Pg.329]

Bischloromethyl ether has been prepared by saturation of formalin with dry hydrogen chloride by the reaction of paraformaldehyde with phosphorus trichloride or phosphorus oxychloride, by solution of paraformaldehyde in concentrated sulfuric acid and treatment with ammonium chloride or dry hydrogen chloride, and by suspension of paraformaldehyde in seventy or eighty percent sulfuric acid and treatment with chlorosulfonic acid. It is formed together with the asymmetrical isomer when methyl ether is chlorinated and when paraformaldehyde is treated with chlorosulfonic acid. The present method has been published. ... [Pg.2]

Chlor-siure, /. chloric acid. -sMureanhydrid, n. chloric anhydride, chlorine(V) oxide, -schwefel, n. sulfur chloride (esp. the monochloride). -silber, n. silver chloride, -sili-cium, n. silicon tetrachloride, -soda, /. = Chlornatron. -stickstoff, m. nitrogen chloride. -Strom, m. stream of chlorine, -strontium, n. strontium chloride, -suifonsaure, /. chlorosulfonic acid, chlorosulfuric acid, -toluol, n. chlorotoluene. -fibertrager, m. chlorine carrier. [Pg.91]

Caution Since chlorine is poisonous, this procedure should be conducted in an efficient hood. Chlorosulfonic acid is a strong skin irritant and should be handled with gloves and a protective face... [Pg.11]

A 4 1 0.04 molar ratio of carboxylic acid, chlorosulfonic acid, and chloranil was used. A 2 1 mixture of chlorine and oxygen was passed into the reaction for 3 hours. [Pg.13]

When two polymers interact or react with each other, they are likely to provide a compatible, even a miscible, blend. Epoxidized natural rubber (ENR) interacts with chloro-sulfonated polyethylene (Hypalon) and polyvinyl chloride (PVC) forming partially miscible and miscible blends, respectively, due to the reaction between chlorosulfonic acid group and chlorine with epoxy group of ENR. Chiu et al. have studied the blends of chlorinated polyethylene (CR) with ENR at blend ratios of 75 25, 50 50, and 25 75, as well as pure rubbers using sulfur (Sg), 2-mercapto-benzothiazole, and 2-benzothiazole disulfide as vulcanizing agents [32]. They have studied Mooney viscosity, scorch... [Pg.316]

This compound is a dangerous explosive. When chlorosulfonic acid reacts with a perchlorate, the product is C1204, which is more accurately written as C10C103, chlorine perchlorate. [Pg.559]

Aluminum phosphide Amyl trichlorosilane Benzoyl chloride Boron tribromide Boron trifluoride Boron trifluoride etherate Bromine pentafluoride Bromine trifluoride n-Butyl isocyanate Butyllithium Butyric anhydride Calcium Calcium carbide Chlorine trifluoride Chloro silanes Chlorosulfonic acid Chromium oxychloride Cyanamide Decaborane Diborane... [Pg.61]

Less widely used methods include acid pasting, i.e., dissolving the material in a medium such as chlorosulfonic acid and precipitating it in water, or milling the crude pigment. These methods gain importance whenever phthalocyanine is to be chlorinated by a route other than with aluminum chloride or acids. [Pg.435]

Bromine (dry gas) Bromine (liquid) Bromobenzene Butanol Butyl acetate Butylamine Butylchloride Butyric acid Calcium chloride Carbon tetrachloride Castor oil Cellosolve Cellosolve acetate Chlorine (dry gas) Chlorine water Chloroacetic acid Chlorobenzene Chloroform Chlorosulfonic acid Chromic acid Citric acid Colza oil Copper sulfate Cyclohexane Cyclohexanol Cyclohexanone... [Pg.511]

Both types of wax are readily oxidized (24) and halogenated (116). The latter is an important commercial outlet, the products of which are used as extreme pressure additives for oil (112,113) and as intermediates in Friedel-Crafts condensations (119). Air oxidation leads to carboxylic acids, for which considerable use has been found both here and abroad. Sulfonates can be made by reaction of waxes with chlorosulfonic acid (37,104) or with sulfur dioxide and chlorine (46,99). [Pg.275]

Monosubstitution at a occurs in 255 with N-bromosuccinimide, N-chlorosuccinimide, and 25% nitric acid at 0° disubstitution (a a ) occurs with bromine or chlorine in acetic acid, thionyl chloride, chlorosulfonic acid, and 70% nitric acid and tetrasubstitution (a a bb ) is obtained with 90% nitric acid 254b behaves similarly. Tetra-cyanoethylene forms -complexes with 255 and 328,340 and the latter compound is slowly converted on standing to a C-substituted derivative with loss of HCN. [Pg.285]

The support originally used for solid-phase synthesis was partially chloromethy-lated cross-linked polystyrene, which was prepared by chloromethylation of cross-linked polystyrene with chloromethyl methyl ether and tin(IV) chloride [1-3] or zinc chloride [4] (Figure 6.1). Haloalkylations of this type are usually only used for the functionalization of supports, and not for selective transformation of support-bound intermediates. Because of the mutagenicity of a-haloethers, other methods have been developed for the preparation of chloromethyl polystyrene. These include the chlorination of methoxymethyl polystyrene (Figure 6.1 [5]), the use of a mixture of dimethoxymethane, sulfuryl chloride, and chlorosulfonic acid instead of chloromethyl methyl ether [6], the chlorination of hydroxymethyl polystyrene [7], and the chlorination of cross-linked 4-methylstyrene-styrene copolymer with sodium hypochlorite [8], sulfuryl chloride [8], or cobalt(III) acetate/lithium chloride [9] (Figure 6.1, Table 6.1). [Pg.205]

Pcrchloro- and pcrchlorobromo copper phthalocyanine arc important organic green pigments. They are accessible through direct chlorination of copper phthalocyanine in a eutectic melt of aluminum and sodium chloride or in a chlorosulfonic acid medium. Bromine can he used instead of chlorine in the MCI—NaCl melt to obtain polybromochloio copper phthalocyanine. [Pg.1301]

Furosemide can also be synthesized starting with 2,4-dichlorobenzoic acid (formed by chlorination and oxidation of toluene). Reaction with chlorosulfonic acid is an electrophilic aromatic substitution via the species -S02C1 attacking ortho and para to the chlorines and meta to the carboxy-late. Ammonolysis to the sulfonamide is followed by nucleophilic aromatic substitution of the less hindered chlorine by furfurylamine (obtained from furfural—a product obtained by the hydrolysis of carbohydrates). [Pg.246]


See other pages where Chlorine-Chlorosulfonic acid is mentioned: [Pg.351]    [Pg.170]    [Pg.351]    [Pg.170]    [Pg.491]    [Pg.116]    [Pg.505]    [Pg.133]    [Pg.397]    [Pg.12]    [Pg.150]    [Pg.5]    [Pg.435]    [Pg.528]    [Pg.152]    [Pg.416]    [Pg.432]    [Pg.279]    [Pg.24]    [Pg.13]    [Pg.63]    [Pg.167]    [Pg.243]    [Pg.8]    [Pg.86]    [Pg.680]    [Pg.131]    [Pg.27]    [Pg.487]    [Pg.26]   
See also in sourсe #XX -- [ Pg.83 ]




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