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Chloride dichloride

Chlorides —Dichloride — Trichloride — Pentachloride — Chlorobromides — Chloroiodides. [Pg.255]

Most of the ethylene dichloride produced is utilized for the manufacture of vinyl chloride, which may be obtained from it by pyrolysis or the action of caustic soda. Large quantities are also used in anti-knock additives for gasoline. As a solvent It has been displaced by trichloroethylene and tetrachloroelhyJene. U.S. production 1978 4-75 megatonnes. [Pg.134]

To date there is no evidence that sodium forms any chloride other than NaCl indeed the electronic theory of valency predicts that Na" and CU, with their noble gas configurations, are likely to be the most stable ionic species. However, since some noble gas atoms can lose electrons to form cations (p. 354) we cannot rely fully on this theory. We therefore need to examine the evidence provided by energetic data. Let us consider the formation of a number of possible ionic compounds and first, the formation of sodium dichloride , NaCl2. The energy diagram for the formation of this hypothetical compound follows the pattern of that for NaCl but an additional endothermic step is added for the second ionisation energy of sodium. The lattice energy is calculated on the assumption that the compound is ionic and that Na is comparable in size with Mg ". The data are summarised below (standard enthalpies in kJ) ... [Pg.75]

We see, therefore, that magnesium normally forms a dichloride and not a mono- or tri-chloride. Similar calculations can be made for many systems, but greater uncertainties arise, especially when... [Pg.76]

Sulphur dioxide is oxidised by chlorine in the presence of charcoal or camphor to give sulphur dichloride dioxide sulphuryl chloride), SOjCl ... [Pg.290]

Sulphur and selenium form the chlorides disulphur dichloride S2CI2 and diselenium dichloride Se2Cl2. They are made by the direct combination of the elements. Both are covalent, yellow liquids which are readily hydrolysed by water ... [Pg.306]

Sulphur and tellurium form a chloride of formula XClj. Sulphur dichloride SClj is a red liquid at room temperature whilst the corresponding tellurium compound is a black solid. [Pg.307]

SULPHUR DICHLORIDE OXIDE, THIONYL CHLORIDE, SOClj... [Pg.307]

Sulphur oxide dichloride is used as a chlorinating agent in organic chemistry, for example in the preparation of acid chlorides ... [Pg.308]

A somewhat similar reaction is the power of sulphur oxide dichloride to remove water of crystallisation from hydrated chlorides, the hydroxyl groups of the water molecule reacting as do those in the acid molecules in the above reaction. [Pg.308]

In both reactions above, the oxide dichloride is refluxed with the acid or the hydrated chloride the sulphur dioxide and hydrogen chloride pass off and any unused sulphur oxide dichloride is distilled off in vacuo. [Pg.308]

Sulphur dichloride oxide (thionyl chloride) on the hydrated chloride can also be used to produce the anhydrous chloride in certain cases, for example copper(II) chloride and chromium(III) chloride ... [Pg.343]

If the chloride is heated with sodium or potassium dichromate-(VI) and concentrated sulphuric acid, a red gas, chromium(VI) dichloride dioxide, CrOjClj, is evolved if this is passed into water, a yellow solution of a chromate(VI) is formed. [Pg.349]

The addition of concentrated sulphuric acid to a solid dichromate mixed with a chloride produces a red vapour, chromium(VI)dioxide dichloride, Cr02Cl2 (cf. sulphur dioxide dichloride, SO2CI2). Chromium(VI) dioxide dichloride reacts with water immediately ... [Pg.379]

By the reaction of sulphur dichloride oxide with the hydrated chloride ... [Pg.380]

Nickel forms yellow anhydrous halides NiXjlX = F. Cl. Br) and a black iodide Nil2 all these halides are made by direct combination of the elements, and the chloride by reaction of sulphur dichloride oxide with the hydrated salt. All dissolve in water to give green solutions from which the hydrates can be crystallised the solutions contain the ion [NifHjOls], and the chloride crystallises as NiCl2.6H2O, nickel(II) chloride hexahydrate. [Pg.406]

Xow visually named vinamhigiioiisly as phenylarsonoiis dichloride, f Similarly numed Jimcthylarsinoiis chloride. [Pg.314]

The dichlorides of aliphatic glycols are obtained by reaction with thionyl chloride in the presence of a small quantity of pyridine, for example ... [Pg.270]

Place a mixture of 1 0 g. of the hydrocarbon, 10 ml. of dry methylene chloride or ethylene dichloride or syw.-tetrachloroethane, 2 5 g. of powdered anhydrous aluminium chloride and 1-2 g. of pure phthalic anhydride in a 50 ml. round-bottomed flask fitted with a short reflux condenser. Heat on a water bath for 30 minutes (or until no more hydrogen chloride fumes are evolved), and then cool in ice. Add 10 ml. of concentrated hydrochloric acid cautiously and shake the flask gently for 5 min utes. Filter oflf the solid at the pump and wash it with 10-15 ml. of cold water. Boil the resulting crude aroylbenzoic acid with 10 ml. of 2 -5N sodium carbonate solution and 0 2 g. of decolourising carbon for 5 minutes, and filter the hot solution. Cool, add about 10 g. of crushed ice and acidify... [Pg.519]

Method A. Cool a solution of the nitrate-free dichloride, prepared from or equivalent to 5 0 g. of palladium or platinum, in 50 ml. of water and 5 ml. of concentrated hydrochloric acid in a freezing mixture, and treat it with 50 ml. of formahn (40 per cent, formaldehyde) and 11 g. of the carrier (charcoal or asbestos). Stir the mixture mechanically and add a solution of 50 g. of potassium hydroxide in 50 ml. of water, keeping the temperature below 5°. When the addition is complete, raise the temperature to 60° for 15 minutes. Wash the catalyst thoroughly by decantation with water and finally with dilute acetic acid, collect on a suction filter, and wash with hot water until free from chloride or alkali. Dry at 100° and store in a desiccator. [Pg.948]

Prepare a saturated solution of sodium sulphide, preferably from the fused technical sodium polysulphide, and saturate it with sulphur the sulphur content should approximate to that of sodium tetrasulphide. To 50 ml. of the saturated sodium tetrasulphide solution contained in a 500 ml. round-bottomed flask provided with a reflux condenser, add 12 -5 ml. of ethylene dichloride, followed by 1 g. of magnesium oxide to act as catalyst. Heat the mixture until the ethylene dichloride commences to reflux and remove the flame. An exothermic reaction sets in and small particles of Thiokol are formed at the interface between the tetrasulphide solution and the ethylene chloride these float to the surface, agglomerate, and then sink to the bottom of the flask. Decant the hquid, and wash the sohd several times with water. Remove the Thiokol with forceps or tongs and test its rubber-like properties (stretching, etc.). [Pg.1024]

C/760 mmHg) sulfur dichloride After the addition stirring v/as stopped and the flask was allowed to stand for 15 h in the ice-bath. The condenser was replaced with a drying tube containing CaCl (refluxing of the vinyl chloride had stopped completely after the addition of sulfur dichloride). [Pg.123]

It is possible to prepare 1-acetoxy-4-chloro-2-alkenes from conjugated dienes with high selectivity. In the presence of stoichiometric amounts of LiOAc and LiCl, l-acetoxy-4-chloro-2-hutene (358) is obtained from butadiene[307], and cw-l-acetoxy-4-chloro-2-cyclohexene (360) is obtained from 1.3-cyclohexa-diene with 99% selectivity[308]. Neither the 1.4-dichloride nor 1.4-diacetate is formed. Good stereocontrol is also observed with acyclic diene.s[309]. The chloride and acetoxy groups have different reactivities. The Pd-catalyzed selective displacement of the chloride in 358 with diethylamine gives 359 without attacking allylic acetate, and the chloride in 360 is displaced with malonate with retention of the stereochemistry to give 361, while the uncatalyzed reaction affords the inversion product 362. [Pg.69]

Boon has observed that when 2,4-dimethyl-5-thiazolecarboxylic acid (22) is heated with an excess of thionyl chloride, the main product (76%) is 4-methyl-2,5-thiazoledicarboxylic acid dichloride (23) (Scheme 14 (7). [Pg.528]

Trichlorothiazole, which behaves as an insecticide, can be prepared by the reaction at 150 to 200°C of sulfur with either 1.2.2.2-tetrachlorethylisocyanide dichloride (103), JV-(l,2,2,2-tetrachlor-ethyl)formimidine (104), or by the reaction of sulfur chlorides at... [Pg.575]

Chlorination of ethane yields in addition to ethyl chloride a mixture of two isomeric dichlorides What are the structures of these two dichlorides ... [Pg.175]

Acid Halogenides. For acid halogenides the name is formed from the corresponding acid radical if this has a special name (Sec. 3.1.2.10) for example, NOCl, nitrosyl chloride. In other cases these compounds are named as halogenide oxides with the ligands listed alphabetically for example, BiClO, bismuth chloride oxide VCI2O, vanadium(lV) dichloride oxide. [Pg.220]

Acid rhodamines are made by the iatroduction of the sulfonic acid group to the aminoxanthene base. The preferred route is the reaction fluorescein (2) with phosphorous pentachloride to give 3,6-dichlorofluoran (fluorescein dichloride) (23), which is then condensed with a primary aromatic amine in the presence of 2inc chloride and quicklime. This product is then sulfonated. For example, if compound (23) (fluorescein dichloride) is condensed with aniline and the product is sulfonated. Acid Violet 30 Cl45186) (24) is produced. [Pg.401]

Other acetyl chloride preparations include the reaction of acetic acid and chlorinated ethylenes in the presence of ferric chloride [7705-08-0] (29) a combination of ben2yl chloride [100-44-7] and acetic acid at 85% yield (30) conversion of ethyUdene dichloride, in 91% yield (31) and decomposition of ethyl acetate [141-78-6] by the action of phosgene [75-44-5] producing also ethyl chloride [75-00-3] (32). The expense of raw material and capital cost of plant probably make this last route prohibitive. Chlorination of acetic acid to monochloroacetic acid [79-11-8] also generates acetyl chloride as a by-product (33). Because acetyl chloride is cosdy to recover, it is usually recycled to be converted into monochloroacetic acid. A salvage method in which the mixture of HCl and acetyl chloride is scmbbed with H2SO4 to form acetyl sulfate has been patented (33). [Pg.82]

Once the principal route to vinyl chloride, in all but a few percent of current U.S. capacity this has been replaced by dehydrochlorination of ethylene dichloride. A combined process in which hydrogen chloride cracked from ethylene dichloride was added to acetylene was advantageous but it is rarely used because processes to oxidize hydrogen chloride to chlorine with air or oxygen are cheaper (7) (see Vinyl polymers). [Pg.102]

Chlorine cannot be stored economically or moved long distances. International movements of bulk chlorine are more or less limited to movements between Canada and the United States. In 1987, chlorine moved in the form of derivatives was 3.3 million metric tons or approximately 10% of total consumption (3). Exports of ethylene dichloride, vinyl chloride monomer, poly(vinyl chloride), propylene oxide, and chlorinated solvents comprise the majority of world chlorine movement. Countries or areas with a chlorine surplus exported in the form of derivatives include Western Europe, Bra2il, USA, Saudi Arabia, and Canada. Countries with a chlorine deficit are Taiwan, Korea, Indonesia, Vene2uela, South Africa, Thailand and Japan (3). [Pg.478]


See other pages where Chloride dichloride is mentioned: [Pg.270]    [Pg.288]    [Pg.85]    [Pg.1046]    [Pg.1046]    [Pg.258]    [Pg.132]    [Pg.132]    [Pg.758]    [Pg.270]    [Pg.288]    [Pg.85]    [Pg.1046]    [Pg.1046]    [Pg.258]    [Pg.132]    [Pg.132]    [Pg.758]    [Pg.186]    [Pg.460]    [Pg.534]    [Pg.540]    [Pg.541]    [Pg.147]    [Pg.477]   
See also in sourсe #XX -- [ Pg.228 ]




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Chloride ethylene dichloride

Diphenyl palladium chloride/dichloride

Ethylene dichloride and vinyl chloride

From Carbonimidoyl Dichlorides or Imidoyl Chlorides

Oxalyl chloride: Ethanedioyl dichloride

Phosphoryl chlorides dichlorides)

Sulfur dichloride, reaction with ammonium chloride

Tin dichloride imidoyl chlorides

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