Carbon epoxy mechanical properties

Fig. 3.27. Effect of the interface shear strength on mechanical properties of carbon fiber-epoxy matrix composites ( ) tran.sverse tensile strength (A) maximum transverse tensile strain (O) transverse tensile modiilns. After Madhukar and Drzal (1991),...

Mechanical properties of carbon fiber-epoxy matrix and Kevlar fiber-epoxy matrix composites with and without PVAL coaling at room temperature". 

Mechanical properties of carbon fiber-epoxy matrix composites . 

Piggott M.R., Lam P.K., Lim J.T. and Woo M.S. (1985). The internal pressure, mechanical properties and water absorption of carbon fiber composites with spiro-epoxy copolymer matrices. Composites Sci. Technol. 23, 247-262. 

The complex sorption behavior of the water in amine-epoxy thermosets is discussed and related to depression of the mechanical properties. The hypothesized sorption modes and the corresponding mechanisms of plasticization are discussed on the basis of experimental vapor and liquid sorption tests, differential scanning calorimetry (DSC), thermomechanical analysis (TMA) and dynamic mechanical analysis. In particular, two different types of epoxy materials have been chosen low-performance systems of diglycidyl ether of bisphenol-A (DGEBA) cured with linear amines, and high-performance formulations based on aromatic amine-cured tetraglycidyldiamino diphenylmethane (TGDDM) which are commonly used as matrices for carbon fiber composites. 

Until recently, the materials made from epoxy binders and glass microspheres were believed to be the strongest syntactic foams. However, several papers 26,39) have shown that, when carbon microspheres replace those of glass, the material becomes stronger, more water resistant, and more capable to withstand hydrostatic pressure (for the same filler concentration) (Table 13). The smaller the carbon microspheres, the stronger are the resulting foams, 9 135). Carbon microspheres also improve the mechanical properties of phenolic and resol syntactic materials (Table 14) 38). 

Fig. 9. Effect of sub-Tg annealing on the ultimate mechanical properties of carbon-fiber-reinforced epoxies...

Figure 35. Mechanical properties of carbon/carbon epoxy-resin hybrid composites, compared with the properties of the composite skeletons before resin impregnation (61,62). The composite skeletons were prepared from Sigrafil HM 3 PAN-based fiber, rigidized with a phenolic resin, and densified by four cycles with coal-tar pitch plus sulfur the carbonization temperature was 1000°C. (a) Young s modulus.

Two case studies are presented in which polymer nanotube composites are proposed as replacements for conventional materials. We evaluate the technical and economic feasibility of using them as smart materials for strain gauges thus, exploiting their electrical properties, and as structural materials for aircraft panels bringing into play their mechanical properties. Our analysis shows that as new strain gauge materials, polymer nanotube composites offer many advantages. As a possible replacement for aluminum in an aircraft panel, it is found that a hybrid composite of (Epoxy 33% carbon fabric + 30% carbon fibers + 3% CVD-MWNT) is an attractive candidate. 

Organic matrices are divided into thermosets and thermoplastics. The main thermoset matrices are polyesters, epoxies, phenolics, and polyimides, polyesters being the most widely used in commercial applications (3,4). Epoxy and polyimide resins are applied in advanced composites for structural aerospace applications (1,5). Thermoplastics Uke polyolefins, nylons, and polyesters are reinforced with short fibers (3). They are known as traditional polymeric matrices. Advanced thermoplastic polymeric matrices like poly(ether ketones) and polysulfones have a higher service temperature than the traditional ones (1,6). They have service properties similar to those of thermoset matrices and are reinforced with continuous fibers. Of course, composites reinforced with discontinuous fibers have weaker mechanical properties than those with continuous fibers. Elastomers are generally reinforced by the addition of carbon black or silica. Although they are reinforced polymers, traditionally they are studied separately due to their singular properties (see Chap. 3). 

Carbon fibers, which are relatively inert under physiological conditions, are selected particularly to enhance the mechanical properties of various biomedical materials, such as their incorporation in bone cement [127]. Metal implants for total hip joint replacements do not match the mechanical properties of human bone, and epoxy-graphite implants may have better properties [128]. 

Ghiorse, S.R. Effect of void content on the mechanical properties of carbon/epoxy laminates. SAMPE Q. 1993, 23 (1), 54-59. 

The addition of aluminum trihydrate improved fire resistance of glass epoxy laminates but, because of the high loading required, it decreased the mechanical properties of the laminate. Various components of formulation were studied to improve performance. It was found that the curing agent and impact modifier help to improve the mechanical properties of the laminates. Other fillers were also studied in order to understand the impact of filler on properties. It was found that all fillers (glass beads, quartz, calcium carbonate, mica) reduce mechanical properties of laminates, not just aluminum trihydrate. " Aluminum trihydrate was found to be one of better performers in this system. 

In some epoxy systems ( 1, ), it has been shown that, as expected, creep and stress relaxation depend on the stoichiometry and degree of cure. The time-temperature superposition principle ( 3) has been applied successfully to creep and relaxation behavior in some epoxies (4-6)as well as to other mechanical properties (5-7). More recently, Kitoh and Suzuki ( ) showed that the Williams-Landel-Ferry (WLF) equation (3 ) was applicable to networks (with equivalence of functional groups) based on nineteen-carbon aliphatic segments between crosslinks but not to tighter networks such as those based on bisphenol-A-type prepolymers cured with m-phenylene diamine. Relaxation in the latter resin followed an Arrhenius-type equation. 

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