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Butan acid

Chemical Designations - Synonyms Butanic Acid Butanoic Acid Butyric Acid Ethylacetic Acid Propanecarboxylic Acid Chemical Formula CHjCHjCHjCOOH. [Pg.66]

Table 7.2 Kinetic parameters and physical data for the chlorination of butanic acid. Table 7.2 Kinetic parameters and physical data for the chlorination of butanic acid.
Butanediol 1-butanethiol Butanic Acid Butanoic Acid Butanol... [Pg.28]

Synonyms Butanoic acid Acide butyrique -But-anoic acid -Butyric acid Butanic acid Ethylace-tic acid Acido butirico 1-Propanecarboxylic acid Propylformic acid Kyselina maselna Butters-aeure RTECS ES5425000 UN2820 FEMA number 2221... [Pg.368]

BUTANIC ACID (107-92-6) C4H,02 CH3(CH2)2C00H Combustible liquid [explosion limits in air (vol %) 2 to 10 flash point 161°F/72°C cc autoignition tenp 842°F/450°C Fire Rating 2]. Violent reaction with amines, strong oxidizers, chromium trioxide >212°F/>100 (incandescent reaction) furfuryl alcohol (explosion), hypochlorites, isocyanides, nitromethane, chromic acid, nitric acid, hydrogen peroxide, phosphorus pentaoxide, all bases (exothermic reaction) reducing... [Pg.163]

BUTANIC ACID (107-92-6) Combustible liquid (flash point 16rF/72°C cc). Violent reaction with oxidizers. Reacts with alkylene oxides, ammonia, aliphatic amines, caustics, epichlorohydrin, sulfuric acid, isocyanates. [Pg.212]

Butanic acid. See n-Butyric acid Butanimide. SeeSuccinimide Butanoic acid n-Butanoic acid. See n-Butyric acid... [Pg.585]

CAS 107-92-6 EINECS/ELINCS 203-532-3 UN 2820 (DOT) FEMA 2221 Synonyms Butanic acid Butanoic acid n-Butanoic acid Carboxylic acid C4 Ethylacetic acid... [Pg.653]

Extraction of phenolic antioxidants from PE-HD with water at 52 °C A01 = pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, Irganox 1010 A02 = bis[3,3-bis-(4 -hydroxy-3 -tert-buty1-pheny1)butane acid] glycol ester, Hostanox 03 [510]... [Pg.282]

Normal butyl alcohol, propyl carbinol, n-butanol, 1-buianol, CH3CH2CH2CH2OH. B.p. 117 C. Manufactured by reduction of crotonaldehyde (2-buienal) with H2 and a metallic catalyst. Forms esters with acids and is oxidized first to butanal and then to butanoic acid. U.S. production 1978 300 000 tonnes. [Pg.71]

Manufactured by the liquid-phase oxidation of ethanal at 60 C by oxygen or air under pressure in the presence of manganese(ii) ethanoate, the latter preventing the formation of perelhanoic acid. Another important route is the liquid-phase oxidation of butane by air at 50 atm. and 150-250 C in the presence of a metal ethanoate. Some ethanoic acid is produced by the catalytic oxidation of ethanol. Fermentation processes are used only for the production of vinegar. [Pg.164]

CH2 CH C CH. Colourless gas with a sweet odour b.p. 5°C. Manufactured by the controlled low-temperature telomerization of ethyne in the presence of an aqueous solution of CuCI and NH Cl. Reduced by hydrogen to butadiene and, finally, butane. Reacts with water in the presence of HgSO to give methyl vinyl ketone. Forms salts. Forms 2-chloro-butadiene (chloroprene) with hydrochloric acid and certain metallic chlorides. [Pg.266]

It is known that even condensed films must have surface diffusional mobility Rideal and Tadayon [64] found that stearic acid films transferred from one surface to another by a process that seemed to involve surface diffusion to the occasional points of contact between the solids. Such transfer, of course, is observed in actual friction experiments in that an uncoated rider quickly acquires a layer of boundary lubricant from the surface over which it is passed [46]. However, there is little quantitative information available about actual surface diffusion coefficients. One value that may be relevant is that of Ross and Good [65] for butane on Spheron 6, which, for a monolayer, was about 5 x 10 cm /sec. If the average junction is about 10 cm in size, this would also be about the average distance that a film molecule would have to migrate, and the time required would be about 10 sec. This rate of Junctions passing each other corresponds to a sliding speed of 100 cm/sec so that the usual speeds of 0.01 cm/sec should not be too fast for pressurized film formation. See Ref. 62 for a study of another mechanism for surface mobility, that of evaporative hopping. [Pg.450]

Technically, acetaldehyde is mainly made by the oxidation of ethylene using a CuCl2/PdCl2 catalyst system.. Although some acetic acid is still prepared by the catalytic oxidation of acetaldehyde, the main process is the catalytic oxidation of paraffins, usually -butane. [Pg.74]

Dibromobutane from 1 4 butanediol). In a 500 ml. threenecked flask fltted with a stirrer, reflux condenser and dropping funnel, place 154 g. (105 ml.) of 48 per cent, hydrobromic acid. Cool the flask in an ice bath. Add slowly, with stirring, 130 g. (71 ml.) of concentrated sulphuric acid. To the resulting ice-cold solution add 30 g. of redistilled 1 4-butanediol dropwise. Leave the reaction mixture to stand for 24 hours heat for 3 hours on a steam bath. The reaction mixture separates into two layers. Separate the lower layer, wash it successively with water, 10 per cent, sodium carbonate solution and water, and then dry with anhydrous magnesium sulphate. Distil and collect the 1 4-dibromo-butane at 83-84°/12 mm. The yield is 55 g. [Pg.280]

It IS hard to find a class of compounds in which the common names of its members have influenced organic nomenclature more than carboxylic acids Not only are the common names of carboxylic acids themselves abundant and widely used but the names of many other compounds are derived from them Benzene took its name from benzoic acid and propane from propionic acid not the other way around The name butane comes from butyric acid present m rancid butter The common names of most aldehydes are derived from the common names of carboxylic acids—valeraldehyde from valeric acid for exam pie Many carboxylic acids are better known by common names than by their systematic ones and the framers of the lUPAC rules have taken a liberal view toward accepting these common names as permissible alternatives to the systematic ones Table 19 1 lists both common and systematic names for a number of important carboxylic acids... [Pg.792]

Polymerization of AA and BB monomers is illustrated by butane-1,4-diol and adipic acid. The aabb repeat unit in the polymer has an Mq value of 200. If Eq. (5.4) is used to evaluate it gives the number of aa plus bb units therefore = 200(hj )/2. [Pg.311]

Since 1960, the Hquid-phase oxidation of ethylene has been the process of choice for the manufacture of acetaldehyde. There is, however, stiU some commercial production by the partial oxidation of ethyl alcohol and hydration of acetylene. The economics of the various processes are strongly dependent on the prices of the feedstocks. Acetaldehyde is also formed as a coproduct in the high temperature oxidation of butane. A more recently developed rhodium catalyzed process produces acetaldehyde from synthesis gas as a coproduct with ethyl alcohol and acetic acid (83—94). [Pg.51]

Commercial production of acetic acid has been revolutionized in the decade 1978—1988. Butane—naphtha Hquid-phase catalytic oxidation has declined precipitously as methanol [67-56-1] or methyl acetate [79-20-9] carbonylation has become the technology of choice in the world market. By-product acetic acid recovery in other hydrocarbon oxidations, eg, in xylene oxidation to terephthaUc acid and propylene conversion to acryflc acid, has also grown. Production from synthesis gas is increasing and the development of alternative raw materials is under serious consideration following widespread dislocations in the cost of raw material (see Chemurgy). [Pg.66]

Currently, almost all acetic acid produced commercially comes from acetaldehyde oxidation, methanol or methyl acetate carbonylation, or light hydrocarbon Hquid-phase oxidation. Comparatively small amounts are generated by butane Hquid-phase oxidation, direct ethanol oxidation, and synthesis gas. Large amounts of acetic acid are recycled industrially in the production of cellulose acetate, poly(vinyl alcohol), and aspirin and in a broad array of other... [Pg.66]

Butane-Naphtha Catalytic Liquid-Phase Oxidation. Direct Hquid-phase oxidation ofbutane and/or naphtha [8030-30-6] was once the most favored worldwide route to acetic acid because of the low cost of these hydrocarbons. Butane [106-97-8] in the presence of metallic ions, eg, cobalt, chromium, or manganese, undergoes simple air oxidation in acetic acid solvent (48). The peroxidic intermediates are decomposed by high temperature, by mechanical agitation, and by action of the metallic catalysts, to form acetic acid and a comparatively small suite of other compounds (49). Ethyl acetate and butanone are produced, and the process can be altered to provide larger quantities of these valuable materials. Ethanol is thought to be an important intermediate (50) acetone forms through a minor pathway from isobutane present in the hydrocarbon feed. Formic acid, propionic acid, and minor quantities of butyric acid are also formed. [Pg.68]

Although acetic acid and water are not beheved to form an azeotrope, acetic acid is hard to separate from aqueous mixtures. Because a number of common hydrocarbons such as heptane or isooctane form azeotropes with formic acid, one of these hydrocarbons can be added to the reactor oxidate permitting separation of formic acid. Water is decanted in a separator from the condensate. Much greater quantities of formic acid are produced from naphtha than from butane, hence formic acid recovery is more extensive in such plants. Through judicious recycling of the less desirable oxygenates, nearly all major impurities can be oxidized to acetic acid. Final acetic acid purification follows much the same treatments as are used in acetaldehyde oxidation. Acid quahty equivalent to the best analytical grade can be produced in tank car quantities without difficulties. [Pg.68]

About half of the wodd production comes from methanol carbonylation and about one-third from acetaldehyde oxidation. Another tenth of the wodd capacity can be attributed to butane—naphtha Hquid-phase oxidation. Appreciable quantities of acetic acid are recovered from reactions involving peracetic acid. Precise statistics on acetic acid production are compHcated by recycling of acid from cellulose acetate and poly(vinyl alcohol) production. Acetic acid that is by-product from peracetic acid [79-21-0] is normally designated as virgin acid, yet acid from hydrolysis of cellulose acetate or poly(vinyl acetate) is designated recycle acid. Indeterrninate quantities of acetic acid are coproduced with acetic anhydride from coal-based carbon monoxide and unknown amounts are bartered or exchanged between corporations as a device to lessen transport costs. [Pg.69]

Liquid-phase oxidation of lower hydrocarbons has for many years been an important route to acetic acid [64-19-7]. In the United States, butane has been the preferred feedstock, whereas ia Europe naphtha has been used. Formic acid is a coproduct of such processes. Between 0.05 and 0.25 tons of formic acid are produced for every ton of acetic acid. The reaction product is a highly complex mixture, and a number of distillation steps are required to isolate the products and to recycle the iatermediates. The purification of the formic acid requires the use of a2eotropiag agents (24). Siace the early 1980s hydrocarbon oxidation routes to acetic acid have decliaed somewhat ia importance owiag to the development of the rhodium-cataly2ed route from CO and methanol (see Acetic acid). [Pg.504]

World installed capacity for formic acid is around 330,000 t/yr. Around 60% of the production is based on methyl formate. Of the remainder, about 60% comes from Hquid-phase oxidation and 40% from formate salt-based processes. The largest single producer is BASF, which operates a 100,000 t/yr plant at Ludwigshafen in Germany. The only significant U.S. producer of formic acid is Hoechst-Celanese, which operates a butane oxidation process. [Pg.505]


See other pages where Butan acid is mentioned: [Pg.49]    [Pg.812]    [Pg.163]    [Pg.164]    [Pg.99]    [Pg.832]    [Pg.132]    [Pg.456]    [Pg.49]    [Pg.812]    [Pg.163]    [Pg.164]    [Pg.99]    [Pg.832]    [Pg.132]    [Pg.456]    [Pg.11]    [Pg.22]    [Pg.163]    [Pg.347]    [Pg.138]    [Pg.7]    [Pg.68]    [Pg.69]    [Pg.81]   
See also in sourсe #XX -- [ Pg.411 ]




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Acetic Acid Synthesis via Butane or Naphtha Oxidation

Acetic acid plants butane process

Benzoic acid 73-75 butane

Butan-di-oic acid

Butane tetra carboxylic acids

Butane-1,1,4-tricarboxylic acid

Butane-1,2,3,4-tetracarboxylic acid

Butane-1,4-dicarboxylic acid

Butanes acetic acid from

Mixtures acetic acid + «-butane + water

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