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Amphiphilic acids

Acetaminophen, the amphiphilic acids acetylsalicylic acid (ASA), ibuprofen, and others, as well as some pyrazolone derivatives, such as aminopyrine and dipyrone, are grouped under the label antipyretic analgesics to distinguish them from opioid analgesics, because they share the ability to reduce fever. [Pg.198]

A more complex protocol is sometimes used, in which the acidified solution that has been passed through XAD-2 or XAD-8 resin is then passed through a column of XAD-4 resin. Back-elution of adsorbed DOM from the XAD-4 resin with NaOH yields an additional quantity of DOM that is variably known as hydrophilic acids, XAD-4 acids, transphilic acids, or amphiphilic acids. [Pg.423]

The soft-template methods are based on the use of structure-directing molecules, such as various soluble oligomers and polymers, as well as surfactants and amphiphilic acids which are able to form, alone or with aniline, aggregates such as cylindrical micelles, and other supramolecular 1-D aggregates. [Pg.24]

Surfactant- and Amphiphilic Acid-Assisted Synthesis PANI-NTs have been prepared by the oxidative polymerization of aniline with APS in an aqueous solution in the presence of SDS [82,328], SDBS [329], a mixture of ionic surfactants (CTAB and SDBS) [204], polymeric acids [330] e.g. poly(methyl vinyl ether-alt-maleic acid) [331-334] (Figure 2.16), poly(3-thiopheneacetic acid) [70], PSSA and PAA (Figure 2.16) [333],... [Pg.44]

Fig. 33. Schemes of supermolecules consisting of the emeraldine-base form of PANI complexed by (a) a protonating amphiphilic acid, such as DBSA and (b) a protonating amphiphilic acid and plasticizing am-phiphiles, which are strongly bound to the backbone due to hydrogen bonds [100,188] or coordination bonds [113]. Fig. 33. Schemes of supermolecules consisting of the emeraldine-base form of PANI complexed by (a) a protonating amphiphilic acid, such as DBSA and (b) a protonating amphiphilic acid and plasticizing am-phiphiles, which are strongly bound to the backbone due to hydrogen bonds [100,188] or coordination bonds [113].
While most vesicles are formed from double-tail amphiphiles such as lipids, they can also be made from some single chain fatty acids [73], surfactant-cosurfactant mixtures [71], and bola (two-headed) amphiphiles [74]. In addition to the more common spherical shells, tubular vesicles have been observed in DMPC-alcohol mixtures [70]. Polymerizable lipids allow photo- or chemical polymerization that can sometimes stabilize the vesicle [65] however, the structural change in the bilayer on polymerization can cause giant vesicles to bud into smaller shells [76]. Multivesicular liposomes are collections of hundreds of bilayer enclosed water-filled compartments that are suitable for localized drug delivery [77]. The structures of these water-in-water vesicles resemble those of foams (see Section XIV-7) with the polyhedral structure persisting down to molecular dimensions as shown in Fig. XV-11. [Pg.549]

The behavior of insoluble monolayers at the hydrocarbon-water interface has been studied to some extent. In general, a values for straight-chain acids and alcohols are greater at a given film pressure than if spread at the water-air interface. This is perhaps to be expected since the nonpolar phase should tend to reduce the cohesion between the hydrocarbon tails. See Ref. 91 for early reviews. Takenaka [92] has reported polarized resonance Raman spectra for an azo dye monolayer at the CCl4-water interface some conclusions as to orientation were possible. A mean-held theory based on Lennard-Jones potentials has been used to model an amphiphile at an oil-water interface one conclusion was that the depth of the interfacial region can be relatively large [93]. [Pg.551]

Most of the Langmuir films we have discussed are made up of charged amphiphiles such as the fatty acids in Chapter IV and the lipids in Sections XV-4 and 5. Depending on the pH and ionic strength of the subphase, electrostatic effects can become quite important. Here we develop the theoretical foundation for charged films with the Donnan relationship. Then we mention the influence of subphase pH on film behavior. [Pg.553]

Chemical properties of deposited monolayers have been studied in various ways. The degree of ionization of a substituted coumarin film deposited on quartz was determined as a function of the pH of a solution in contact with the film, from which comparison with Gouy-Chapman theory (see Section V-2) could be made [151]. Several studies have been made of the UV-induced polymerization of monolayers (as well as of multilayers) of diacetylene amphiphiles (see Refs. 168, 169). Excitation energy transfer has been observed in a mixed monolayer of donor and acceptor molecules in stearic acid [170]. Electrical properties have been of interest, particularly the possibility that a suitably asymmetric film might be a unidirectional conductor, that is, a rectifier (see Refs. 171, 172). Optical properties of interest include the ability to make planar optical waveguides of thick LB films [173, 174]. [Pg.560]

Most LB-forming amphiphiles have hydrophobic tails, leaving a very hydrophobic surface. In order to introduce polarity to the final surface, one needs to incorporate bipolar components that would not normally form LB films on their own. Berg and co-workers have partly surmounted this problem with two- and three-component mixtures of fatty acids, amines, and bipolar alcohols [175, 176]. Interestingly, the type of deposition depends on the contact angle of the substrate, and, thus, when relatively polar monolayers are formed, they are deposited as Z-type multilayers. Phase-separated LB films of hydrocarbon-fluorocarbon mixtures provide selective adsorption sites for macromolecules, due to the formation of a step site at the domain boundary [177]. [Pg.560]

Nakamura E 1995 Langmuir-Blodgett film of amphiphilic Cgg carboxylic acid Langmuir 660-5... [Pg.2431]

A typical biomembrane consists largely of amphiphilic lipids with small hydrophilic head groups and long hydrophobic fatty acid tails. These amphiphiles are insoluble in water (<10 ° mol L ) and capable of self-organization into uitrathin bilaycr lipid membranes (BLMs). Until 1977 only natural lipids, in particular phospholipids like lecithins, were believed to form spherical and related vesicular membrane structures. Intricate interactions of the head groups were supposed to be necessary for the self-organization of several ten thousands of... [Pg.350]

Monolayers at the Air—Water Interface. Molecules that form monolayers at the water—air interface are called amphiphiles or surfactants (qv). Such molecules are insoluble in water. One end is hydrophilic, and therefore is preferentially immersed in the water the other end is hydrophobic, and preferentially resides in the air, or in a nonpolar solvent. A classic example of an amphiphile is stearic acid, C H COOH, wherein the long hydrocarbon... [Pg.531]

The monolayer resulting when amphiphilic molecules are introduced to the water—air interface was traditionally called a two-dimensional gas owing to what were the expected large distances between the molecules. However, it has become quite clear that amphiphiles self-organize at the air—water interface even at relatively low surface pressures (7—10). For example, x-ray diffraction data from a monolayer of heneicosanoic acid spread on a 0.5-mM CaCl2 solution at zero pressure (11) showed that once the barrier starts moving and compresses the molecules, the surface pressure, 7T, increases and the area per molecule, M, decreases. The surface pressure, ie, the force per unit length of the barrier (in N/m) is the difference between CJq, the surface tension of pure water, and O, that of the water covered with a monolayer. Where the total number of molecules and the total area that the monolayer occupies is known, the area per molecules can be calculated and a 7T-M isotherm constmcted. This isotherm (Fig. 2), which describes surface pressure as a function of the area per molecule (3,4), is rich in information on stabiUty of the monolayer at the water—air interface, the reorientation of molecules in the two-dimensional system, phase transitions, and conformational transformations. [Pg.531]

The first synthesis of amphiphilic porphyrin molecules involved replacement of the phenyl rings in TPP with pyridine rings, quaternized with C2QH 2Br to produce tetra(3-eicosylpyridinium)porphyrin bromide (3) (36). The pyridinium nitrogen is highly hydrophilic the long C2Q hydrocarbon serves as the hydrophobic part. Tetra[4-oxy(2-docosanoic acid)]phenyl-porphyrin (4) has also been used for films (37). [Pg.533]

The pursuit of further miniaturization of electronic circuits has made submicrometer resolution Hthography a cmcial element in future computer engineering. LB films have long been considered potential candidates for resist appHcations, because conventional spin-coated photoresist materials have large pinhole densities and variations of thickness. In contrast, LB films are two-dimensional, layered, crystalline soHds that provide high control of film thickness and are impermeable to plasma down to a thickness of 40 nm (46). The electron beam polymerization of CO-tricosenoic acid monolayers has been mentioned. Another monomeric amphiphile used in an attempt to develop electron-beam-resist materials is a-octadecylacryUc acid (8). [Pg.534]

The conditions for surfactants to be useful to form Hquid crystals exist when the cross-sectional areas of the polar group and the hydrocarbon chain are similar. This means that double-chain surfactants are eminently suited, and lecithin (qv) is a natural choice. Combiaations of a monochain ionic surfactant with a long-chain carboxyHc acid or alcohol yield lamellar Hquid crystals at low concentrations, but suffer the disadvantage of the alcohol being too soluble ia the oil phase. A combination of long-chain carboxyHc acid plus an amine of equal chain length suffers less from this problem because of extensive ionisa tion of both amphiphiles. [Pg.204]

The use of arachidic acid and different amphiphilic calixarenes for modifying of field effect transistor sensors and determination of some volatile organic contaminants will be considered. [Pg.308]

Another interesting class of phase transitions is that of internal transitions within amphiphilic monolayers or bilayers. In particular, monolayers of amphiphiles at the air/water interface (Langmuir monolayers) have been intensively studied in the past as experimentally fairly accessible model systems [16,17]. A schematic phase diagram for long chain fatty acids, alcohols, or lipids is shown in Fig. 4. On increasing the area per molecule, one observes two distinct coexistence regions between fluid phases a transition from a highly diluted, gas -like phase into a more condensed liquid expanded phase, and a second transition into an even denser... [Pg.635]

For the separation of amino acids, the applicability of this principle has been explored. For the separation of racemic phenylalanine, an amphiphilic amino acid derivative, 1-5-cholesteryl glutamate (14) has been used as a chiral co-surfactant in micelles of the nonionic surfactant Serdox NNP 10. Copper(II) ions are added for the formation of ternary complexes between phenylalanine and the amino acid cosurfactant. The basis for the separation is the difference in stability between the ternary complexes formed with d- or 1-phenylalanine, respectively. The basic principle of this process is shown in Fig. 5-17 [72]. [Pg.145]

The transformation of the hydrophobic periphery composed of bromo substituents into a hydrophilic wrapping of carboxylic acid functions was achieved by reacting 31 with (i) n-butyllithium and (ii) carbon dioxide. The polymer-analogous transformation provides water soluble, amphiphilic derivatives of 31 which constitute useful covalently bonded unimolecular models for micellar structures. [Pg.41]


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Amino acid Amphiphilic molecule

Amino acid amphiphiles

Amino acids, amphiphiles, chiral molecular

Amphiphilic compound carboxylic acid

Boronic acid-appended amphiphiles

Chain conformation amino acid amphiphiles

Helical conformation amino acid amphiphiles

Interfacial Molecular Recognition by Boronic Acid-Appended Amphiphiles

Modification of Polypeptides with Fatty Acids and Amphiphilic Block Copolymers

Monolayers of Bile Acids and Other Amphiphiles

Temperature dependence amino acid amphiphiles

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