Polymerization induced

V-viiiyIpyrrolidone (NVP) polymerization induced decomposition of BPO 86 RAFT 507 stibine-metliated 524... 

Cortese., J.D., Schwab III, B., Frieden, C., Elson, E.L. (1989). Actin polymerization induces a shape change in actin-containing vesicles. Proc. Natl. Acad. Sci. USA 86, 5773-5777. 

Styrene Free radical polymerization similar to the above. Also susceptible to rapid cationic polymerization induced by AlCb at —80°C and to anionic polymerization using alkali metals or their hydrides —CH2—CH— (ieHs T = 100 Amorphous, even when stretched. Hard. Soluble in aromatic hydrocarbons, higher ketones, and esters... 

Free radical polymerization is slow and yields only very low polymers. Vigorous cationic polymerization induced by BFs-ether complex at temperatures down to —... 

Not susceptible to free radical or anionic polymerization, but cationic polymerization induced by BFs, AICI3, etc., is extremely rapid even at — 100°C... 

The temperature coefficient of the rate of a polymerization induced by a thermally decomposing initiator must depend according to Eq. (12) both on the temperature coefficient of kp/k] and on that of kd. Upon substituting Arrhenius expressions for each of the rate constants... 

New Views on Cationic Polymerizations Induced by Ionizing Radiations (1993)... 

Graphite and carbon fibers have been used at templates. Thus, nylon 6 has been polymerized on a graphite matrix. Such syntheses of polymers in the presence of a solid template, where the solid acts as a template have been described as polymerization-induced epitaxy (PIE). The monomer and resulting film is adsorbed on the template surface through only van der Waals forces. After polymerization, the polymer is washed from the template. The recovered polymer retains special structural features introduced by the template. 

As seen with the thin films, addition of a competitive small molecule hgand for the vims reduced the CR. Longer UV irradation resulted in the formation of purple hpo-somes that were more sensitive to the influenza vims. The increased sensitivity was suggested to arise as a consequence of the greater degree of polymerization induced by the longer irradiation time. 

Trialkyl derivatives of boron, and in fact many other molecules such as boroxines with carbon-boron bonds, react readily with oxygen. The initial products are peroxy derivatives with BOOR bonds, which tend to react further to form borate esters. The ease of the initial reaction is shown by the fact that reported examples of vinyl polymerization induced by trialkyl borons require oxygen and are actually radical processes induced by the boron oxygen reaction or intermediate peroxides (7). 

---