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Acids reaction with insoluble bases

The driving force for double substitution reactions is formation of insoluble ionic compounds or covalent compounds from ions in solution. However, if an equation has an insoluble compound on one side and a covalent compound on the other, which way does the reaction go In many cases like this, the formation of covalent compounds is more important than the formation of insoluble ionic compounds, as shown by the reaction of Ba(OH)2 with HCl. Acids usually react with insoluble bases to produce salts and water ... [Pg.240]

Two examples of the reactions of insoluble bases with acids are CuO(s) + H2SO4 CuS04(aq) + H20(l)... [Pg.92]

These experimental and computational data, combined with the lack of any observable kinetic isotope effect, strongly support an electrophilic mechanism for all these arylation reactions. In some cases, the beneficial effect of pivalic acid, in conjunction with insoluble bases, could also be rationalized by invoking a CMD pathway (Fig. 4) [95]. [Pg.210]

Oxides and hydroxides react with HCl to form a salt and water as in a simple acid—base reaction. However, reactions with low solubiHty or insoluble oxides and hydroxides is complex and the rate is dependent on many factors similar to those for reactions with metals. Oxidizing agents such as H2O2, H2SeO, and V2O3 react with aqueous hydrochloric acid, forming water and chlorine. [Pg.444]

Solid-liquid PTC conditions in which the nucleophilic salts (organic or mineral) are transferred from the solid state (as they are insoluble) to the organic phase by means of a phase-transfer agent. Most often the organic nucleophilic species can be formed by reaction of their conjugated acids with solid bases (sodium or potassium hydroxides, or potassium carbonate) (Scheme 5.1 path b). Another proposed mechanism suggests that interfacial reactions occur as a result of absorption of the liquid phase on the surface of the solid. [Pg.148]

The titration of an acid with a base, or vice versa, and the precipitation of an ion in an insoluble compound are examples of chemical methods of analysis used to determine the concentration of a species in a liquid sample removed from a reactor. Such methods are often suitable for relatively slow reactions. This is because of the length of time that may be required for the analysis the mere collection of a sample does not stop further reaction from taking place, and a method of quenching the reaction may be required. For a BR, there is the associated difficulty of establishing the time t at which the concentration is actually measured. This is not a problem for steady-state operation of a flow reactor (CSTR or PFR). [Pg.46]

The amphoteric character of water (i.e., the ability to act either as an acid or as a base) makes water so special. While this renders the use of water as a solvent in acid-or base-sensitive reactions problematic, the possibility to have the solvent as a reactant in acid- or base-initiated reactions is often desirable. These qualities led chemists to rediscover water as a solvent in organic chemistry. Unfortunately, from a chemical point of view, not all transformations are feasible in aqueous solvent systems. Many reagents decompose when brought into contact with water while many others are insoluble. Consequently, it is not surprising that water has not been a very popular solvent in organic chemistry in the past, but this picture is changing rapidly. [Pg.1030]

Strategies for preparing mixed, acyclic acetals on insoluble supports include the oxidative haloalkoxylation of support-bound enol ethers (Entry 6, Table 6.1) and the acid-catalyzed reaction of alcohols with resin-bound enol ethers [627]. Alternatively, resin-bound a-chloro ethers can be converted to mixed acetals by reaction with alcohols or phenols in the presence of strong bases (KO/Bu, HOfBu, DMF, 5 h) [550,628]. Polystyrene-bound a-(phenylseleno)ethers react with aliphatic alcohols under slightly acidic conditions (NIS, TfOH, DCM/dioxane (1 1), 0°C to 20 °C, 1 h) to yield mixed, acyclic acetals [628],... [Pg.109]

Carbamates are by far the most common type of amine protection used in solid-phase synthesis. Various types of carbamate have been developed that can be cleaved under mild reaction conditions on solid phase. Less well developed, however, are techniques that enable the protection of support-bound amines as carbamates. Protection of amino acids as carbamates (Boc or Fmoc) is usually performed in solution using aqueous base (Schotten-Baumann conditions). These conditions enable the selective protection of amines without simultaneous formation of imides or acylation of hydroxyl groups. Unfortunately, however, Schotten-Baumann conditions are not compatible with insoluble, hydrophobic supports. Other bases and solvents have to be used in order to prepare carbamates on, for example, cross-linked polystyrene, and more side reactions are generally observed than in aqueous solution. [Pg.287]

Carbon monoxide is a colorless, odorless, flammable, almost insoluble, very toxic gas that condenses to a colorless liquid at — 90°C. It is not very reactive, largely because its bond enthalpy (1074 kj-mol ) is the highest for any molecule. However, it is a Lewis base, and the lone pair on the carbon atom forms covalent bonds with d-block atoms and ions. It is also a Lewis acid, because its empty antibonding tr-orbitals can accept electron density from a metal (Fig. 14.39). This dual character makes carbon monoxide very useful for forming complexes, and numerous metal carbonyls are known. An example of this behavior is its reaction with nickel to give nickel carbonyl, a toxic, volatile liquid ... [Pg.835]

The yellow crust is then finely ground and extracted with 95% alcohol. This dissolves the toluidine, thiotoluidine, and the dehydrothiotoluidine, leaving the insoluble primuline base (p. 389). The extract is evaporated to dryness and heated to 250°, which removes the toluidine and part of the thiotoluidine. The mixture is then sulphonated with 25% oleum and poured on to ice, filtered, and well washed with water until the washings give only a faint acid reaction. The toluidine and thiotoluidine sulphonic acids pass into solution. The residue is dissolved in 50 gms. of 20% ammonia solution and 800 c.cs. water, and heated to 80°, other 100 c.cs. of water being then added. The solution is filtered hot, if necessary, and the ammonium salt of dehydrothiotoluidine sulphonic acid separates out in the course of 2 days. Primuline can be obtained from the mother liquor by saturating with common salt at the boiling point. [Pg.326]

Reactions of typical acids with bases and carbonates. Use a selection of alkalis, insoluble bases and carbonates with hydrochloric, sulfuric and nitric acids. [Pg.267]

The reaction mixture containing 100 g potassium hydroxide, 85 mL water, 400 mL ethylene glycol and 9.50 g of N-methyl-N-cyano-3-(p-trifluoromethylphenoxy)-3-phenylpropylamine was heated to refluxing temperature for 20 hours, and was then cooled. 500 mL of water were added. The reaction mixture was extracted with three 500 mL portions of ether. The combined extracts washed with water. The water wash was discarded. The ether solution was next contacted with 2 N aqueous hydrochloric acid. The acidic aqueous layer was separated. A second aqueous acidic extract with 2 N hydrochloric acid was made followed by three aqueous extracts and an extract with saturated aqueous sodium chloride. The aqueous layers were all combined and made basic with 5 N aqueous sodium hydroxide. N-methyl 3-(p-trifluoromethylphenoxy)-3-phenylpropylamine, formed in the above reaction, was insoluble in the basic solution and separated. The amine was extracted into ether. Two further ether extractions were carried out. The ether extracts were combined, and the combined extracts washed with saturated aqueous sodium chloride and then dried. Evaporation of the ether in vacuo yielded about 6.3 g of N-methyl-3-(p-trifluoromethylphenoxy)-3-phenylpropylamine. The amine free base was converted to the corresponding hydrochloride salt. [Pg.1675]

Dioiganotin dihalides are moderately strong Lewis acids and form stable complexes with ammonia and amines. The commercially important diorganotin compounds are most frequently the oxides, carboxylates, and mercaptocarboxylic acid esters. The oxides are amorphous or polycrystalline, highly polymeric, infusible, and insoluble solids. They are moderately strong bases and react readily with a wide variety of strongly and weakly acidic compounds. Their insolubility in all nonreactive solvents makes the choice of proper reaction conditions for such a neutralization reaction an important consideration for optimum yields. [Pg.72]

The best bases in liquid S02 are sulfites of organic amines, for example, tetramethyl ammonium sulfite, [(CH NhSOg (for most of the inorganic sulfites are quite insoluble in this solvent). As expected, the conductivity of liquid S02 increases when either S03 (an acid) or a soluble sulfite (a base) is dissolved in it, but the conductivity drops if one of these solutions is mixed with the other (neutralization). Thionyl chloride, SOCL, also exhibits acidic reactions when dissolved in S02 but does not, as is sometimes supposed, yield the S02+ ion (Exercise 1). It is interesting that aluminum sulfite, Als(SOs)s, is amphoteric in liquid S02, just as aluminum... [Pg.292]


See other pages where Acids reaction with insoluble bases is mentioned: [Pg.156]    [Pg.436]    [Pg.418]    [Pg.209]    [Pg.69]    [Pg.380]    [Pg.28]    [Pg.298]    [Pg.64]    [Pg.132]    [Pg.263]    [Pg.506]    [Pg.106]    [Pg.88]    [Pg.456]    [Pg.218]    [Pg.533]    [Pg.378]    [Pg.332]    [Pg.334]    [Pg.706]    [Pg.947]    [Pg.1015]    [Pg.132]    [Pg.205]    [Pg.371]    [Pg.276]    [Pg.278]    [Pg.297]    [Pg.4]    [Pg.158]    [Pg.64]    [Pg.67]    [Pg.163]   


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Acid base reactions

Bases reaction with acids

Bases, acid-base reactions

Insoluble bases

Reaction with base

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