Toxicity rubbers

Caution Thallium compounds are highly toxic. Rubber gloves and laboratory coats should be worn and reactions should he carried out in an efficient hood. Thallium wastes should be collected and disposed of separately. 

It can be expected that some other functionalized polymers will be commercialized in the future due to an incr sed pressure of legislative requirements against physically non-persistent additives used for stabilization of polymeric materials in contact with food or regulations for handling toxic rubber chemicals [322, 323]. The main interest has been given to systems prepared by current technologies. 

The remedy is to swab with a cold water solution of commercial quality oxalic acid solution (or alternatively use a proprietary solution for the removal of scale from pots and pans) followed by rinsing with water. Oxalic acid is toxic rubber gloves and goggles are recommended. 

Cm.OROCARBONSANDCm.OROHYDROCARBONS - TOXIC AROMATICS] (Vol 6) Chlorinated butyl rubber... 

Experimentation with test animals and laboratory and plant experience indicate that the fluorophosphoric acids are less toxic and dangerous than hydrogen fluoride (58). However, they contain, or can hydrolyze to, hydrofluoric acid and must be treated with the same care as hydrofluoric acid. Rubber gloves and face shields are essential for all work with these acids, and full mbber dress is necessary for handling larger quantities. The fumes from these acids contain HF. 

Hydrofluoric acid [7664-39-3] M 20.0, b 112.2"(aq azeotrope, 38.2% HF), d 1.15 (47-53% HF), pK 3.21. Freed from lead (Pb ca 0.002ppm) by co-precipitation with Srp2, by addition of lOmL of 10% SrCl2 soln per kilogram of the cone acid. After the ppte has settled, the supernatant is decanted through a filter in a hard-rubber or paraffin lined-glass vessel [Rosenqvist Am J Sci 240 358 1942. Pure aqueous HF solutions (up to 25M) can be prepared by isothermal distn in polyethylene, polypropylene or platinum apparatus [Kwestroo and Visser Analyst 90 297 7965]. HIGHLY TOXIC. 

In general the nitroso rubbers also suffer from a poor resistanee to ionising radiation, sensitivity to degradation by organie bases, highly toxic degradation products and an exceptionally high cost. The advent of the rubbers based on perfluorofmethyl vinyl ether) considered above and of the phosphonitrilic elastomers considered below would appear to put the commercial future of these materials in extreme doubt. 

Dimethylsilicone rubbers show a high compression set which can be reduced to some extent by additives such as mercurous oxide and cadmium oxide. These materials are undesirable, however, because of their toxicity. Substantially reduced compression set values may be obtained by using a polymer containing... 

Cautionl Hydrogen selenide is very toxic. This preparation should be carried out in a well-ventilated hood. The operator should wear rubber gloves. The apparatus should be screened from any bright light. 

Provide permanent brazed or welded pipelines from the cylinders to near the points of gas use. Select pipe materials suitable for the gas and its application. Any flexible piping used should be protected against physical damage. Never use rubber or plastic connections from cylinders containing toxic gases. 

In recent years, the use of solvent-borne adhesives has been seriously restricted. Solvents are, in general, volatile, flammable and toxic. Further, solvent may react with other airborne contaminants contributing to smog formation and workplace exposure. These arguments have limited the use of solvent-bome adhesives by different national and European regulations. Although solvent recovery systems and afterburners can be effectively attached to ventilation equipment, many factories are switching to the use of water-borne rubber adhesives, hot melts or 100% solids reactive systems, often at the expense of product performance or labour efficiency. 

Phenolic-neoprene contact cements are used for structural metal-metal bonding. especially where fatigue resistance and low temperature performance are important [209]. They are also used for bonding textiles, wood, rubbers, plastics, ceramics, and glass to metal and to one another. Solvent toxicity and flammability has greatly reduced the use of contact cements in the wood products industry. Water-based contact cements persist, but generally do not perform as well as the solvent systems, thus allowing market erosion by alternative binders. 

Health Hazards Information - Recommended Personal Protective Equipment U.S. Bu. Mines approved toxic dust mask chemical goggles rubber gloves neoprene-coated shoes Symptoms Following Erqrosure Inhalation produces slight toxic effects. Contact with eyes irritates eyes and causes skin rash General Treatment for Exposure INHALATION remove to fresh air. EYES wash with water for 20 min. call a physician. SKIN wash with water Toxicity by Inhalation (ThresholdLimit Value) Data not available Short-Term Exposure Limits Data not available Toxicity by Ingestion Grade 2 oral rat LDjq 820 mg/kg Late Toxicity Data not available Vapor (Gas) Irritant Characteristics Data not available Liquid or Solid Irritant Characteristics Data not available Odor Threshold Data not available. 

---