Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Thiocyanate determination

To establish the well drainage boundaries and fluid flow patterns within the TFSA-waterflood pilot, an interwell chemical tracer study was conducted. Sodium thiocyanate was selected as the tracer on the basis of its low adsorption characteristics on reservoir rocks (36-38), its low and constant background concentration (0.9 mg/kg) in produced fluids and its ease and accuracy of analysis(39). On July 8, 1986, 500 lb (227 kg) of sodium thiocyanate dissolved in 500 gal (1.89 m3> of injection brine (76700 mg/kg of thiocyanate ion) were injected into Well TU-120. For the next five months, samples of produced fluids were obtained three times per week from each production well. The thiocyanate concentration in the produced brine samples were analyzed in duplicate by the standard ferric nitrate method(39) and in all cases, the precision of the thiocyanate determinations were within 0.3 mg/kg. The concentration of the ion in the produced brine returned to background levels when the sampling and analysis was concluded. [Pg.582]

Another method is that based on the ferrous/ferric thiocyanate determination of hydroperoxides [1]. This exploits the ion-catalysed decomposition as shown by... [Pg.397]

Conversion of thiourea to ammonium thiocyanate - determination of activation energy from experimental data, 93-95... [Pg.443]

Fowler, R. C., Durbetaki, A. J. (1952). Cyanide and thiocyanate determination in multiple sclerosis and allied demyelinizing disorders. American Journal of Physiology, 171, 724. [Pg.93]

Arsonium salts have found considerable use in analytical chemistry. One such use involves the extraction of a metal complex in aqueous solution with tetraphenylarsonium chloride in an organic solvent. Titanium (TV) thiocyanate [35787-79-2] (157) and copper(II) thiocyanate [15192-76-4] (158) in hydrochloric acid solution have been extracted using tetraphenylarsonium chloride in chloroform solution in this manner, and the Ti(IV) and Cu(II) thiocyanates determined spectrophotometrically. Cobalt, palladium, tungsten, niobium, and molybdenum have been determined in a similar manner. In addition to their use for the determination of metals, anions such as perchlorate and perrhenate have been determined as arsonium salts. Tetraphenylarsonium permanganate is the only known insoluble salt of this anion. [Pg.339]

In the former, it gives precipitates with halides (except the fluoride), cyanides, thiocyanates, chromates(VI), phosphate(V), and most ions of organic acids. The silver salts of organic acids are obtained as white precipitates on adding silver nitrate to a neutral solution of the acid. These silver salts on ignition leave silver. When this reaction is carried out quantitatively, it provides a means of determining the basicity of the acid... [Pg.430]

Add a known volume ofo oaM.AgNOj solution (in excess) and boil the solution until the silver chloride has coagulated. Filter through a conical 5 cm. funnel, ensuring that the filter-paper does not protrude above the r m of the funnel. Wash the silver chloride and the filter-paper several times with a fine jet of distilled water. To the united filtrate and washings add i ml. of saturated ferric alum solution. The solution should be almost colourless if it is more than faintly coloured, add a few drops of concentrated nitric acid. Then titrate with 0 02M-ammonium thiocyanate solution until the permanent colour of ferric thiocyanate is just perceptible. (Alternatively the chloride may be determined potentiometrically.)... [Pg.507]

Control experiment. This is not necessary if the sodium peroxide is known to be chlorine-free. If there is any doubt on this point, the whole operation should be repeated precisely as before, but omitting the organic halogen compound. A small thiocyanate titration value may be found, and this should be deducted from all determinations in which the above quantity of the particular batch of sodium peroxide is used. [Pg.507]

Quantitative. Classically, silver concentration ia solution has been determined by titration with a standard solution of thiocyanate. Ferric ion is the iadicator. The deep red ferric thiocyanate color appears only when the silver is completely titrated. GravimetricaHy, silver is determined by precipitation with chloride, sulfide, or 1,2,3-benzotriazole. Silver can be precipitated as the metal by electro deposition or chemical reduciag agents. A colored silver diethjldithiocarbamate complex, extractable by organic solvents, is used for the spectrophotometric determination of silver complexes. [Pg.91]

Analysis. The abiUty of silver ion to form sparingly soluble precipitates with many anions has been appHed to their quantitative deterrnination. Bromide, chloride, iodide, thiocyanate, and borate are determined by the titration of solutions containing these anions using standardized silver nitrate solutions in the presence of a suitable indicator. These titrations use fluorescein, tartrazine, rhodamine 6-G, and phenosafranine as indicators (50). [Pg.92]

Bromide ndIodide. The spectrophotometric determination of trace bromide concentration is based on the bromide catalysis of iodine oxidation to iodate by permanganate in acidic solution. Iodide can also be measured spectrophotometricaHy by selective oxidation to iodine by potassium peroxymonosulfate (KHSO ). The iodine reacts with colorless leucocrystal violet to produce the highly colored leucocrystal violet dye. Greater than 200 mg/L of chloride interferes with the color development. Trace concentrations of iodide are determined by its abiUty to cataly2e ceric ion reduction by arsenous acid. The reduction reaction is stopped at a specific time by the addition of ferrous ammonium sulfate. The ferrous ion is oxidi2ed to ferric ion, which then reacts with thiocyanate to produce a deep red complex. [Pg.232]

For colorimetric or gravimetric determination l-nitroso-2-naphthol can be used. For chromatographic ion exchange (qv), cobalt is isolated as the nitroso-(R)-salt complex. The cyanate complex is used for photometric determination and the thiocyanate for colorimetry. A rapid chemical analysis of... [Pg.371]

Determination. The most accurate (68) method for the deterrnination of copper in its compounds is by electrogravimetry from a sulfuric and nitric acid solution (45). Pure copper compounds can be readily titrated using ethylene diamine tetracetic acid (EDTA) to a SNAZOXS or Murexide endpoint. lodometric titration using sodium thiosulfate to a starch—iodide endpoint is one of the most common methods used industrially. This latter titration is quicker than electrolysis, almost as accurate, and much more tolerant of impurities than is the titration with EDTA. Gravimetry as the thiocyanate has also been used (68). [Pg.256]

The main chemico-analytical properties of the designed ionoselective electrodes have been determined. The work pH range of the electrodes is 1 to 5. The steepness of the electrode function is close to the idealized one calculated for two-charged ions (26-29 mV/pC). The electrode function have been established in the concentration range from 0.1 to 0.00001 mole/1. The principal advantage of such electrodes is the fact that thiocyanate ions are simultaneously both complexing ligands and the ionic power. The sensitivity (the discovery limits), selectivity (coefficient of selectivity) and the influence of the main temporal factors (drift of a potential, time of the response, lifetime of the membranes) were determined for these electrodes. [Pg.35]

Stratifying water systems for selective extraction of thiocyanate complexes of platinum metals have been proposed. The extraction degree of mthenium(III) by ethyl and isopropyl alcohols, acetone, polyethylene glycol in optimum conditions amounts to 95-100%. By the help of electronic methods, IR-spectroscopy, equilibrium shift the extractive mechanism has been proposed and stmctures of extractable compounds, which contain single anddouble-chai-ged acidocomplexes [Rh(SCN)J-, [Ru(SCN)J, [Ru(SCN)J -have been determined. Constants of extraction for associates investigated have been calculated. [Pg.257]

The method of extraction of Ru(III) from thiocyanate solutions by water soluble extractants in the presence of ammonium sulfate as salting out agent followed by photometric determination of it in extract has been elaborated. [Pg.257]

Method of Rh(III) - Ru(III) separation and isolation them from rai e and nonferrous metals based on formation of different charged complexes with varied stability has been proposed. Possibility of sepai ation of Ru(III), Rh(III), Pd(II), Pt(II) by water-soluble extractants from concentrated thiocyanate solutions has been displayed. Accelerated procedures of extraction-photometric determination of Rh(III), Ru(III) in solutions and waste products, which ai e chai acterized by high selectivity, availability, usage of non-toxic extractants have been worked out. [Pg.258]

IQ. To determine the concentration of chloride ion, - a 5-mL aliquot of the methyl lithium solution is cautiously added to 25 ml of water and the resulting solution is acidified with concentrated sulfuric acid and then treated with 2-3 ml of ferric ammonium sulfate [Fe(NH4)( 04)2 12 H2O] indicator solution and 2-3 ml of benzyl alcohol. The resulting mixture is treated with 10.0 mL of standard aqueous 0.100 M silver nitrate solution and then titrated with standard aqueous 0.100 H potassium thiocyanate solution to a brownish-red endpoint. [Pg.106]

By means of colorimetric determination in the laboratory you measured the concentration of FeSCN+i, which we shall designate [FeSCN+2], in solutions containing ferric and thiocyanate ions, Fe+3 and SCN. The reaction is... [Pg.151]

Determination. To an aliquot of the silver(I) solution containing between 10 and 50 pg of silver, add sufficient EDTA to complex all those cations present which form an EDTA complex. If gold is present (>250 xg) it is masked by adding sufficient bromide ion to form the AuBr4 complex. Cyanide, thiocyanate or iodide ions are masked by adding sufficient mercury(II) ions to complex these anions followed by sufficient EDTA to complex any excess mercury(II). Add 1 mL of 20 per cent ammonium acetate solution, etc., and proceed as described under Calibration. [Pg.183]

These reactions take place with sparingly soluble silver salts, and hence provide a method for the determination of the halide ions Cl", Br, I-, and the thiocyanate ion SCN ". The anion is first precipitated as the silver salt, the latter dissolved in a solution of [Ni(CN)4]2", and the equivalent amount of nickel thereby set free is determined by rapid titration with EDTA using an appropriate indicator (murexide, bromopyrogallol red). [Pg.312]

The following sections are concerned with the use of standard solutions of reagents such as silver nitrate, sodium chloride, potassium (or ammonium) thiocyanate, and potassium cyanide. Some of the determinations which will be considered strictly involve complex formation rather than precipitation reactions, but it is convenient to group them here as reactions involving the use of standard silver nitrate solutions. Before commencing the experimental work, the theoretical Sections 10.74 and 10.75 should be studied. [Pg.348]

Thiocyanates may also be determined using adsorption indicators in exactly similar manner to chlorides and bromides, but an iron(III) salt indicator is usually preferred (Section 10.82). [Pg.351]

The method may be applied to those anions (e.g. chloride, bromide, and iodide) which are completely precipitated by silver and are sparingly soluble in dilute nitric acid. Excess of standard silver nitrate solution is added to the solution containing free nitric acid, and the residual silver nitrate solution is titrated with standard thiocyanate solution. This is sometimes termed the residual process. Anions whose silver salts are slightly soluble in water, but which are soluble in nitric acid, such as phosphate, arsenate, chromate, sulphide, and oxalate, may be precipitated in neutral solution with an excess of standard silver nitrate solution. The precipitate is filtered off, thoroughly washed, dissolved in dilute nitric acid, and the silver titrated with thiocyanate solution. Alternatively, the residual silver nitrate in the filtrate from the precipitation may be determined with thiocyanate solution after acidification with dilute nitric acid. [Pg.353]

A commercial silver alloy in the form of wire or foil is suitable for this determination. Clean the alloy with emery cloth and weigh it accurately. Place it in a 250 mL conical flask, add 5 mL water and 10 mL concentrated nitric acid place a funnel in the mouth of the flask to avoid mechanical loss. Warm the flask gently until the alloy has dissolved. Add a little water and boil for 5 minutes in order to expel oxides of nitrogen. Transfer the cold solution quantitatively to a 100 mL graduated flask and make up to the mark with distilled water. Titrate 25 mL portions of the solution with standard 0.1 M thiocyanate. [Pg.354]

Note. The presence of metals whose salts are colourless does not influence the accuracy of the determination, except that mercury and palladium must be absent since their thiocyanates are insoluble. Salts of metals (e.g. nickel and cobalt) which are coloured must not be present to any considerable extent. Copper does not interfere, provided it does not form more than about 40 per cent of the alloy. [Pg.354]

Discussion. The chloride solution is treated with excess of standard silver nitrate solution, and the residual silver nitrate determined by titration with standard thiocyanate solution. Now silver chloride is more soluble than silver thiocyanate, and would react with the thiocyanate thus ... [Pg.355]

Bromides can also be determined by the Volhard method, but as silver bromide is less soluble than silver thiocyanate it is not necessary to filter off the silver bromide (compare chloride). The bromide solution is acidified with dilute nitric acid, an excess of standard 0.1M silver nitrate added, the mixture thoroughly shaken, and the residual silver nitrate determined with standard 0.1 M ammonium or potassium thiocyanate, using ammonium iron(III) sulphate as indicator. [Pg.356]

Iodides can also be determined by this method, and in this case too there is no need to filter off the silver halide, since silver iodide is very much less soluble than silver thiocyanate. In this determination the iodide solution must be very dilute in order to reduce adsorption effects. The dilute iodide solution (ca 300 mL), acidified with dilute nitric acid, is treated very slowly and with vigorous stirring or shaking with standard 0.1 M silver nitrate until the yellow precipitate coagulates and the supernatant liquid appears colourless. Silver nitrate is then present in excess. One millilitre of iron(III) indicator solution is added, and the residual silver nitrate is titrated with standard 0.1M ammonium or potassium thiocyanate. [Pg.356]

Discussion. Arsenates in solution are precipitated as silver arsenate, Ag3 As04, by the addition of neutral silver nitrate solution the solution must be neutral, or if slightly acid, an excess of sodium acetate must be present to reduce the acidity if strongly acid, most of the acid should be neutralised by aqueous sodium hydroxide. The silver arsenate is dissolved in dilute nitric acid, and the silver titrated with standard thiocyanate solution. The silver arsenate has nearly six times the weight of the arsenic, hence quite small amounts of arsenic may be determined by this procedure. [Pg.357]

Discussion. Potassium may be precipitated with excess of sodium tetraphenyl-borate solution as potassium tetraphenylborate. The excess of reagent is determined by titration with mercury(II) nitrate solution. The indicator consists of a mixture of iron(III) nitrate and dilute sodium thiocyanate solution. The end-point is revealed by the decolorisation of the iron(III)-thiocyanate complex due to the formation of the colourless mercury(II) thiocyanate. The reaction between mercury( II) nitrate and sodium tetraphenylborate under the experimental conditions used is not quite stoichiometric hence it is necessary to determine the volume in mL of Hg(N03)2 solution equivalent to 1 mL of a NaB(C6H5)4 solution. Halides must be absent. [Pg.359]


See other pages where Thiocyanate determination is mentioned: [Pg.494]    [Pg.494]    [Pg.627]    [Pg.447]    [Pg.134]    [Pg.284]    [Pg.288]    [Pg.378]    [Pg.75]    [Pg.264]    [Pg.130]    [Pg.170]    [Pg.500]    [Pg.400]    [Pg.171]    [Pg.180]    [Pg.314]    [Pg.339]    [Pg.353]   
See also in sourсe #XX -- [ Pg.164 , Pg.166 , Pg.170 , Pg.208 , Pg.213 , Pg.413 ]




SEARCH



Determination of Thiocyanates

Determination of molybdenum by the thiocyanate method

Spectrophotometric determination as a molybdenum (V) thiocyanate complex

Thiocyanate hydrogen peroxide determination

Thiocyanate hydroperoxide determination

© 2024 chempedia.info