Free chlorine

Control experiment. This is not necessary if the sodium peroxide is known to be chlorine-free. If there is any doubt on this point, the whole operation should be repeated precisely as before, but omitting the organic halogen compound. A small thiocyanate titration value may be found, and this should be deducted from all determinations in which the above quantity of the particular batch of sodium peroxide is used. 

Caro s acid is effective ia delignifying wood pulp (qv) made by chlorine-free bleaching sequences. When conditions are carefully controlled, the mechanical properties of the final paper (qv) are not impaired. These processes were developed ia the 1980s and commercialized ia the 1990s (68). 

Very unstable modifications, like the reddish, chlorine-free a-copper phthalocyanine, can be stabilized with amides or salts of copper phthalocyanine sulfonic acids (59—63). Mixture with other metal phthalocyanines, eg, tin, vanadium, aluminum, or magnesium, also inhibits crystallization change and poor performance in binders and prints (flocculation) due to the hydrophobic character of unsubstituted phthalocyanines. 

The principal oxidi2ing agent used in degradative shrink-resist treatments is chlorine. Free chlorine reacts very rapidly with wool hence it is difficult... 

A process for producing chlorine-free chlorine dioxide, called the 01 PROCESS technology, was aimounced by Olin Corp. in early 1992 (72). The process uses a pure chloric acid feedstock and proprietary catalysts that uti1i2e water as the reducing agent. The overall reaction chemistry of the process is... 

Chlorine free radicals used for the substitutioa reactioa are obtaiaed by either thermal, photochemical, or chemical means. The thermal method requites temperatures of at least 250°C to iaitiate decomposition of the diatomic chlorine molecules iato chlorine radicals. The large reaction exotherm demands close temperature control by cooling or dilution, although adiabatic reactors with an appropriate diluent are commonly used ia iadustrial processes. Thermal chlorination is iaexpeasive and less sensitive to inhibition than the photochemical process. Mercury arc lamps are the usual source of ultraviolet light for photochemical processes furnishing wavelengths from 300—500 nm. 

A process giving a chlorine free product is as follows —i... 

Methane is the most difficult alkane to chlorinate. The reaction is initiated by chlorine free radicals obtained via the application of heat (thermal) or light (hv). Thermal chlorination (more widely used industrially) occurs at approximately 350-370°C and atmospheric pressure. A typical product distribution for a CH4/CI2 feed ratio of 1.7 is mono- (58.7%), di-(29.3%) tri- (9.7%) and tetra- (2.3%) chloromethanes. 

The highly exothermic chlorination reaction produces approximately 95 KJ/mol of HCI. The first step is the breaking of the Cl-Cl bond (bond energy = -1- 584.2 KJ), which forms two chlorine free radicals (Cl atoms) ... 

HFC-Chlorine free-blends-(long-term alternatives) ... 

Titanium, vanadium or chromium oxides activated with chlorine-free organo-aluminum compounds, triethyl- or triisobutyl aluminum, have also been used as catalysts [285],... 

The stratosphere contains, however, only small amounts--a few tenths of a ppb-of chlorine free radicals of natural origin. They are produced by the decomposition of methyl chloride, CH3Q. The nitrogen oxides (NO and NO2) are more abundant and are produced in the stratosphere by the decomposition of nitrous oxide, N2O. Both CH3CI and N2O are of biological origin these compounds, released at the Earth s surface, are sufficiently stable to reach the stratosphere in significant amounts. 

VCH Verlagsgesellschaft mbH, D-694S1 Weinheim (Federal Republic of Germany), 1994 Printed on add-bee and chlorine-free paper. 

A novel process to produce chlorine-free fuel gas and char from waste PVC and waste glass... 

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