Surfactant, ceramics

Servoxyl VPIZ100 surfactant, ceramic binders C20-40 pareth-10 surfactant, ceramics Hydioxypiopyl guar Methocel 310 Series Methocel E15LV Methocel J5MS PEG-10 oleate Surtonic JL-80X surfactant, chain lubes Mackamide CDM surfactant, chain lubricants Dehyton CL... 

The current or potential iadustrial appHcations of microemulsions iaclude metal working, catalysis, advanced ceramics processiag, production of nanostmctured materials (see Nanotechnology), dyeiag, agrochemicals, cosmetics, foods, pharmaceuticals, and biotechnology (9,12—18). Environmental and human-safety aspects of surfactants have begun to receive considerable attention (19—21). 

Forming additives or processing aids (2,33—37) are commonly used to render ceramic powders more processible. Binders and plasticizers (qv) are typically added to improve or aid dry powder and plastic forming, whereas deflocculants, surfactants (qv), and antifoams are commonly used in slurry processing. 

Trisodium phosphate [7601-54-9] trisodium orthophosphate, Na PO, is an important constituent of hard-surface cleaners including those for ceramic, metal, or painted surfaces. It may be used with soaps, surfactants, or other alkaHes. It precipitates many heavy-metal ions but does not sequester to form soluble chelates. It is thus a precipitant builder and additionally an alkaH. 

The alkahes do not sequester heavy-metal ions and have Httie soil-suspending effect. They are effective in maintaining a high pH and saponify the acidic constituents of soil and thus promote cleaning. In the cleaning of ceramics, glass, and metal surfaces, however, the alkahes act as primary detergents even in the absence of surfactants in these systems. 

Microelectronic circuits for communications. Controlled permeability films for drug delivery systems. Protein-specific sensors for the monitoring of biochemical processes. Catalysts for the production of fuels and chemicals. Optical coatings for window glass. Electrodes for batteries and fuel cells. Corrosion-resistant coatings for the protection of metals and ceramics. Surface active agents, or surfactants, for use in tertiary oil recovery and the production of polymers, paper, textiles, agricultural chemicals, and cement. 

The formation of ordered two- and three-dimensional microstructuies in dispersions and in liquid systems has an influence on a broad range of products and processes. For example, microcapsules, vesicles, and liposomes can be used for controlled drug dehvery, for the contaimnent of inks and adhesives, and for the isolation of toxic wastes. In addition, surfactants continue to be important for enhanced oil recovery, ore beneficiation, and lubrication. Ceramic processing and sol-gel techniques for the fabrication of amorphous or ordered materials with special properties involve a rich variety of colloidal phenomena, ranging from the production of monodispersed particles with controlled surface chemistry to the thermodynamics and dynamics of formation of aggregates and microciystallites. 

Upon reaction, the heterogenized catalyst can be easily separated from the reaction mixture by filtration and then recycled. The hydro-phobic substrate is microemulsified in water and subjected to an orga-nometallic catalyst, which is entrapped within a partially hydrophobized sol-gel matrix. The surfactant molecules, which carry the hydrophobic substrate, adsorb/desorb reversibly on the surface of the sol-gel matrix breaking the micellar structure, spilling their substrate load into the porous medium that contains the catalyst. A catalytic reaction then takes place within the ceramic material to form the desired products that are extracted by the desorbing surfactant, carrying the emulsified product back into the solution. 

The ultrafiltration of the microemulsion is a very useful operation for separating water and oil in these mixtures [117-120]. Because of the limited availability of solvent stable membranes, most of the work pubHshed so far was performed using ceramic membranes, which show a high adsorption of surfactant at the membrane surface and comparably low rejection rates of reverse micelles. Using electro ultrafiltration, where the concentration polarisation phenomenon of the reverse micelles (using the ionic surfactant AOT) at the membrane surface is depressed by asymmetric high voltage electrical fields, the rejection rates can be increased,but not to economical values [121,122]. 

Synthesis of solid state materials using surfactant molecules as template has been extensively used in this decade. Among the advantages of the use of amphiphilic molecules, the self-assembling property of the surfactants can provide an effective method for synthesising ceramic and composite materials with interesting characteristics, such as nanoscale control of morphology, and nano or mesopore structure with narrow and controllable size distribution [1-5]. 

Abrasive cleaners arc used lo remove soils and stains from hard surfaces that are durable lo the scouring action. Such surfaces include stainless steel and porcelain plumbing fixtures, metal and ceramic cooking utensils, and various stone, metal, and ceramic building surfaces. Typically, these products consist of a very high level of abrasive (commonly silica flour) with moderate to low levels of a dry chlorine bleach (KDCC or chlorinaled trisodium phosphate) and low levels of surfactant (LAS) and builder (STP) for wetting action and improved stain removal... 

Ning, J., Zhang, J., Pan, Y. and Guo, J., Surfactants assisted processing of carbon nanotube-reinforced Si02 matrix composites , Ceramics International, 2004, 30, 63-67. 

Raw and Bulk Materials Petrochemicals Inorganic Minerals/ores Ceramics/Glass Detergents Surfactants... 

An excellent article by Bernhardt [69] tabulates dispersion systems for hundreds of ceramic powders. These dispersion systems consist of a solvent and surfactant with a range of useful concentrations listed. The solvents are both aqueous and nonaqueous and the surfactants are ionic, nonionic, and ionic polymers. This is the most extensive table of established dispersion systems available in the literature today. 

The use of the HLB number to select a surfactant (or mixture of surfactants) is achieved by matching the surfactant HLB number to that of the material being dispersed. Unfortunately, little information is available on the HLB munber for ceramic powder surfaces. What data there exists is given in Table 9.16. For ceramic systems, the HLB of the surfactant is usually optimized by experiments with various surfactants. 

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