Surface structure adhesion

Surface science Surface structure, adhesion of materials, phase structures, crystal structures, catalytic processes, clusters... 

Other topics recently studied by XPS include the effects of thermal treatment on the morphology and adhesion of the interface between Au and the polymer trimethylcy-clohexane-polycarbonate [2.72] the composition of the surfaces and interfaces of plasma-modified Cu-PTFE and Au-PTFE, and the surface structure and the improvement of adhesion [2.73] the influence of excimer laser irradiation of the polymer on the adhesion of metallic overlayers [2.74] and the behavior of the Co-rich binder phase of WC-Co hard metal and diamond deposition on it [2.75]. 

As with chemical etches, developing optimum conversion coatings requires assessment of the microstructure of the steel. Correlations have been found between the microstructure of the substrate material and the nature of the phosphate films formed. Aloru et al. demonstrated that the type of phosphate crystal formed varies with the orientation of the underlying steel crystal lattice [154]. Fig. 32 illustrates the different phosphate crystal morphologies that formed on two heat-treated surfaces. The fine flake structure formed on the tempered martensite surface promotes adhesion more effectively than the knobby protrusions formed on the cold-rolled steel. 

ASTM D3933, Standard Guide for Preparation of Aluminum Surfaces for Structural Adhesives Bonding, Phosphoric Acid Anodization, A.STM, West Conshohocken, PA. El-Mashri, S.M., Jones, R.G. and Forty, A.J., Philo.s. Mag. A, 48, 665 (1983). 

Mazza, J.J. and Kuhbander, R.J., Grit blast/silane (GBS) aluminum surface preparation for structural adhesive bonding, WL-TR-94-4111. Materials Laboratory, Air Force Materiel Command, September 1999. 

Example 10. Two-Component, Nonsagging, Polyurea Structural Adhesive. This example is an all-urea formulation unusual for a 100% solids, hand-castable system. It is also a two-component, one-shot system designed to be nonsagging so that it may be applied to nonhorizontal surfaces without dripping or running. This and similar examples are described in U.S. Patent 5,654,085. See also Guether et al., presented at Polyurethanes Conference 2000, October 8—11, 2000 CRC Press Boca Raton, FL, 2000. 

Chapter 1 is a view of the potential of surface forces apparatus (SFA) measurements of two-dimensional organized ensembles at solid-liquid interfaces. At this level, information is acquired that is not available at the scale of single molecules. Chapter 2 describes the measurement of surface interactions that occur between and within nanosized surface structures—interfacial forces responsible for adhesion, friction, and recognition. 

Effect of Surface Preparation on the Durability of Structural Adhesive Bonds... 

In order to calculate polymer/filler interaction, or more exactly the reversible work of adhesion characterizing it, the surface tension of the polymer must also be known. This quantity is usually determined by contact angle measurements or occasionally the pendant drop method is used. The former method is based on the Young, Dupre and Eowkes equations (Eqs. 21,8, and 10), but the result is influenced by the surface quality of the substrate. Moreover, the surface (structure, orientation, density) of polymers usually differs from the bulk, which might bias the results. Accuracy of the technique maybe increased by using two or more liquids for the measurements. The use of the pendant drop method is limited due to technical problems (long time to reach equilibrium, stability of the polymer, evaluation problems etc.). Occasionally IGC is also used for the characterization of polymers [30]. 

Abstract— The use of organosilanes as adhesion promoters for surface coatings, adhesives and syntactic foams is described and reviewed in the light of published work. Data are presented on the beneficial effect of silanes, when used as pretreatment primers and additives, on the bond strength of two pack epoxide and polyurethane paints applied to aluminium and mild steel. It is shown that silanes when used as additives to structural epoxide and polyurethane adhesives are less effective than when used as pretreatment primers on metals but are highly effective on glass substrates. The compressive properties of glass microballoon/epoxide syntactic foams are shown to be markedly improved by the addition of silanes. 

In all adhesive joints, the interfacial region between the adhesive and the substrate plays an important role in the transfer of stress from one adherend to another [8]. The initial strength and stability of the joint depend on the molecular structure of the interphase after processing and environmental exposure, respectively. Characterization of the molecular structure near the interface is essential to model and, subsequently, to maximize the performance of an adhesive system in a given environment. When deposited on a substrate, the silane primers have a finite thickness and constitute separate phases. If there is interaction between the primer and the adherend surface or adhesive, a new interphase region is formed. This interphase has a molecular structure different from the molecular structure of either of the two primary phases from which it is formed. Thus, it is essential to characterize these interphases thoroughly. 

In 1987 he was promoted to distinguished member of the technical staff and technical manager. His efforts broadened to include projects on polymer-surface interactions adhesion promotion corrosion protection chemical vapor deposition and thin film growth optical fiber coating synthesis, structure, and reactivity of model organic surfaces and time-resolved surface vibrational spectroscopy. 

The diagrams in Fig. llc-f can be measured by the force probe method, when the amplitude and phase are measured as the tip approaches and retracts the surface vertically. In the non-contact range, both the amplitude and the phase retain their constant values (Fig. llc,e). When the tip enters the intermittent contact range (Zphase reduces almost linearly on approaching the surface. The deviation of the amplitude signal from a certain set-point value As is used by a feedback loop to maintain the separation Zc between the tip and sample constant, and hereby visualise the surface structure. When the surface composition is uniform, the amplitude variation is mainly caused by the surface topography. However, if the surface is heterogeneous, the variation in the amplitude can be affected by local differences in viscoelasticity [108-110 ] and adhesion [111] of the sample (Sect. 2.2.2). 

Concerning properties, SFM has become a unique technique in probing local adhesion, friction and elastic response of various materials. This is based on the ability to measure forces as small as picoNewtons and probe areas well below 100 nm. The peculiar sensitivity of the force probe to different types of static and dynamic interactions provides a great number of contrast mechanisms which can map the surface structure regarding the chemical composition and physical properties. However, in most SFM measurements the interpretation of the surface maps remain to be very intricate, mostly because of the concurrent contribution of different forces into the net force. The progress in this field relies on new developments in technique which would allow to measure the properties like stiffness, adhesion, friction and viscosity, separately. 

---