Surface plastic deformation

Bastaninejad M, Ahmadi G. Modeling the effects of abrasive size distribution, adhesion, and surface plastic deformation on chemical-mechanical polishing. J Electrochem Soc 2005 152(9) G720-G730. 

The combination of the processes of the severe plastic deformation of the surface with their physical-chemical treatment can provide the unique opportunity of the controlled formation of nano-sized grain structure for the strength and corrosion stability increasing. By applying both surface plastic deformation and nitriding process simultaneously nanostructured material could be determined. This kind of surface treatment related to refinement of grain could be helpful for considerable modification of material service properties. 

Kojinia Y, Usuki A, Kawasumi M, Okada A, Fukushima Y, Kurauchi T and Kaniiga-ito O (1993) Mechanical properties of nylon 6-clay hybrid, J Muter 8 1185-1189. Aoike T, Uehara H, Yamanobe T and Komoto T (2001) Comparison of macro- and nanotribological behavior with surface plastic deformation of polystyrene, Langmuir 17 2153-2159. 

Figure 3. Critical stages in wear and rolling contact fatigue. (1) Material subject to rolling-sliding contact may detach as wear debris, or (2) small cracks may develop. (3) Early propagation of cracks will be in the near surface plastically deformed material. (4) Later propagation will be driven by contact stress and fluid pressurisation of the cracks in deeper, elastic, material. (5) As the crack extends it may branch and be driven by rail bending stress. (6) Eventual rail failure occurs by fast fracture after a critical crack length is reached.

The application of load in materials produces internal modifications such as crack growth, local plastic deformation, corrosion and phase changes, which are accompanied by the emission of acoustic waves in materials. These waves therefore contain information on the internal behaviour of the material and can be analysed to obtain this information. The waves are detected by the use of suitable sensors, that converts the surface movements of the material into electric signal. These signals are processed, analysed and recorded by an appropriate instrumentation. 

Dislocation theory as a portion of the subject of solid-state physics is somewhat beyond the scope of this book, but it is desirable to examine the subject briefly in terms of its implications in surface chemistry. Perhaps the most elementary type of defect is that of an extra or interstitial atom—Frenkel defect [110]—or a missing atom or vacancy—Schottky defect [111]. Such point defects play an important role in the treatment of diffusion and electrical conductivities in solids and the solubility of a salt in the host lattice of another or different valence type [112]. Point defects have a thermodynamic basis for their existence in terms of the energy and entropy of their formation, the situation is similar to the formation of isolated holes and erratic atoms on a surface. Dislocations, on the other hand, may be viewed as an organized concentration of point defects they are lattice defects and play an important role in the mechanism of the plastic deformation of solids. Lattice defects or dislocations are not thermodynamic in the sense of the point defects their formation is intimately connected with the mechanism of nucleation and crystal growth (see Section IX-4), and they constitute an important source of surface imperfection. 

A number of friction studies have been carried out on organic polymers in recent years. Coefficients of friction are for the most part in the normal range, with values about as expected from Eq. XII-5. The detailed results show some serious complications, however. First, n is very dependent on load, as illustrated in Fig. XlI-5, for a copolymer of hexafluoroethylene and hexafluoropropylene [31], and evidently the area of contact is determined more by elastic than by plastic deformation. The difference between static and kinetic coefficients of friction was attributed to transfer of an oriented film of polymer to the steel rider during sliding and to low adhesion between this film and the polymer surface. Tetrafluoroethylene (Telfon) has a low coefficient of friction, around 0.1, and in a detailed study, this lower coefficient and other differences were attributed to the rather smooth molecular profile of the Teflon molecule [32]. 

Machine components ate commonly subjected to loads, and hence stresses, which vary over time. The response of materials to such loading is usually examined by a fatigue test. The cylinder, loaded elastically to a level below that for plastic deformation, is rotated. Thus the axial stress at all locations on the surface alternates between a maximum tensile value and a maximum compressive value. The cylinder is rotated until fracture occurs, or until a large number of cycles is attained, eg, lO. The test is then repeated at a different maximum stress level. The results ate presented as a plot of maximum stress, C, versus number of cycles to fracture. For many steels, there is a maximum stress level below which fracture does not occur called the... 

Case Hardening by Surface Deformation. When a metaUic material is plastically deformed at sufficiently low temperature, eg, room temperature for most metals and alloys, it becomes harder. Thus one method to produce a hard case on a metallic component is to plastically deform the surface region. This can be accomplished by a number of methods, such as by forcing a hardened rounded point onto the surface as it is moved. A common method is to impinge upon the surface fine hard particles such as hardened steel spheres (shot) at high velocity. This process is called shot... 

Fig. 9. Effect on fatigue strength of the plastic deformation of a carburized steel surface by shot peening (B) as compared to nitriding (A) and heat treating...

Machining of metals involves extensive plastic deformation (shear strain of ca 2—8) of the work material in a narrow region ahead of the tool. High tool temperatures (ca 1000°C) and freshly generated, chemically active surfaces (underside of the chip and the machined surface) that interact extensively with the tool material, result in tool wear. There are also high mechanical and thermal stresses (often cycHc) on the tool (3). 

A typical shock-compression wave-profile measurement consists of particle velocity as a function of time at some material point within or on the surface of the sample. These measurements are commonly made by means of laser interferometry as discussed in Chapter 3 of this book. A typical wave profile as a function of position in the sample is shown in Fig. 7.2. Each portion of the wave profile contains information about the microstructure in the form of the product of and v. The decaying elastic wave has been an important source of indirect information on micromechanics of shock-induced plastic deformation. Taylor [9] used measurements of the decaying elastic precursor to determine parameters for polycrystalline Armco iron. He showed that the rate of decay of the elastic precursor in Fig. 7.2 is given by (Appendix)... 

Initially, at very low loads, the asperities deform elastically where they touch. However, for realistic loads, the high stress causes extensive plastic deformation at the tips of asperities. If each asperity yields, forming a junction with its partner, the total load transmitted across the surface (Fig. 25.3) is... 

Let US now look at how this contact geometry influences friction. If you attempt to slide one of the surfaces over the other, a shear stress fj/a appears at the asperities. The shear stress is greatest where the cross-sectional area of asperities is least, that is, at or very near the contact plane. Now, the intense plastic deformation in the regions of contact presses the asperity tips together so well that there is atom-to-atom contact across the junction. The junction, therefore, can withstand a shear stress as large as k approximately, where k is the shear-yield strength of the material (Chapter 11). 

That fraction of the applied work which is not consumed in the elastic-plastic deformation remains to create the new crack surface, i.e., the crack driving force. Therefore, a nonlinear fracture toughness, G, may be defined as follows ... 

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