Sunflower modified

An alternative method of produciag hydrocarbon fuels from biomass uses oils that are produced ia certaia plant seeds, such as rape seed, sunflowers, or oil palms, or from aquatic plants (see Soybeans and other oilseeds). Certain aquatic plants produce oils that can be extracted and upgraded to produce diesel fuel. The primary processiag requirement is to isolate the hydrocarbon portion of the carbon chain that closely matches diesel fuel and modify its combustion characteristics by chemical processiag. 

Maleic anhydride is important as a chemical hecause it polymerizes with other monomers while retaining the double bond, as in unsaturated polyester resins. These resins, which represent the largest end use of maleic anhydride, are employed primarily in fiber-reinforced plastics for the construction, marine, and transportation industries. Maleic anhydride can also modify drying oils such as linseed and sunflower. 

Even today renewable resources play a dominant role as raw materials for surfactants, but only because of the great contribution made by soaps to the production of surfactants. If the soaps are left out of consideration as native surfactants, petrochemistry holds 65-70% of the production of synthetic surfactants [2]. But for the future a further increase of renewable raw materials is expected in surfactant production [3]. The main reason for this development is the superior digestibility in the environment of products produced from natural materials. The future importance of the renewable raw materials becomes evident from the fact that even now new plants are cultivated or plants are modified to obtain an improved yield. A new type of sunflower has been cultivated to obtain a higher proportion of monounsaturated oleic acid compared with doubly unsaturated linoleic acid [4],... 

N. G. Kashkarov, N. N. Verkhovskaya, A. A. Ryabokon, A. N. Gnoevykh, E. A. Konovalov, and V. I. Vyakhirev. Lubricating reagent for drilling fluids—consists of spent sunflower oil modified with additive in form of aqueous solutions of sodium alkylsiliconate(s). Patent RU 2076132-C, 1997. 

The plant of choice which can be used for PHA production will be influenced by a number of factors. Of prime importance is cost, i. e., in which crop will PHA production be cheapest. The answer to this question is likely to be different depending on the agricultural economics of each country. For example, if one considers oilseed crops, rapeseed may be the best crop for Northern European countries and Canada, sunflower for Southern European countries, and soybean for the USA. Other important factors which may influence the choice of target plant are the nature of the metabolic pathway that needs to modified for synthesis of a particular PHA, the procedure used for PHA purification, and the other uses of the crop besides PHA production. 

For measuring water absorption by the excess water method, the techniques developed by Janicki and Walczak (described by Hamm, 21) for meats and by Sosulski (22) for wheat flour are modified. Lin et al. (17) modified the Sosulski technique for use with sunflower and soy meal products. This modified procedure has been employed for much of the research on water absorption of plant protein additives. Water absorption capacities of a soy flour, two soy concentrates, and two soy isolates were compared by Lin et al. (17) to those of a sunflower flour, three sunflower concentrates, and one sunflower isolate. The percent water absorption of the soy products increased as the total protein content of the samples increased from flour to isolate. The soy flour absorbed 130% water, the soy concentrates absorbed an average of 212% water, and the soy isolates absorbed an average of 432% water. No calculations were made, however, that related the percent water absorbed to protein content of the samples. The sunflower products, though similar in protein content, did not respond in the same magnitude or direction as the soy products. 

Figure 9. Effect of pH on emulsifying capacity of native and chemically modified (succinylation, acetylation) sunflower seed protein concentrates (47)...

If that does occur, then the present system of classification of oils may be impossible to police, and a modified system may become necessary. Perhaps the sale and perceived value of oils will necessarily become dependent on the performance, not the source of the oil. With bulk oils such as palm, peanut, sunflower, safflower, sesame, soya, rapeseed, com, fish, and animal fats and oils, the fatty acid composition will obviously be important for health reasons. If the oil is to be used for frying then the frying properties will be important. In the case of palm products the physical properties and minor components such as carotenoids will be defined. Similarly animal fats will be judged mainly on physical behaviour and effect on the product in which they are used. In all cases the oxidative and stability of the oil will have to be defined. Sesame is a very stable oil, and thus its stability, together with its low level of linolenic acid, would be its major attribute, except for toasted sesame, which would probably be classed as a specialist oil. Already most baking fats sold to the public are blends developed to give the best performance, with no mention on the pack as to the source. If a bulk oil of this type had the desired chemical composition, stability and cooking behaviour, then perhaps the source would not be a matter of concern. 

The earliest efforts to modify the composition of milk fat used an insoluble formaldehyde-crosslinked protein to encapsulate unsaturated vegetable oils. In numerous studies using this approach, linoleic acid was increased to as high as 35%, w/w, of the total milk fatty acids (reviewed by McDonald and Scott, 1977). Bitman et al. (1973) fed increasing amounts of safflower oil encapsulated in formaldehyde-treated casein. The content of milk fat increased linearly from 3.5 to 4.6% as supplemental protected oil was increased from 0 to 1320 g/day per cow. The concentration of linoleic acid increased to 33% of total milk fatty acids, with a compensating decrease in Ci6 o and a smaller decrease in Ci4 0. The concentration of milk fat decreased to lower than pretreatment levels when the supplement was removed, a common observation (Pan et al., 1972). A typical milk fatty acid profile from cows fed a protected sunflower/soybean (70/30) supplement is shown in Table 2.1. 

The above list does not include cocoa butter nor minor oils such as rice bran oil or safflower oil. Nor does it distinguish between oils from a common botanical source with a modified fatty acid composition, such as canola oil and high-erucic rape seed oil, linseed oil and linola, or the various types of sunflower oil. 

The fatty acid composition of the new crop has been modified, and the level of linolenic acid has been reduced from over 50% to 2% (6). This greatly improves oxidative stability of the oil, which by fatty acid composition is very close to sunflower and soybean oils (Table 2). Linola has been found to be more resistant to oxidation than regular flax oil, and its stability is comparable with soybean, canola, and sunflower oils (Przybylski, unpublished data). 

SUNFLOWER SEED OF MODIFIED FATTY ACID COMPOSITION... 

Until two decades ago, the fatty acid composition of vegetable oils was closely related with their origin. The fatty acid profile of sunflower oil was thus defined within namral variation ranges. Current practices, however, are widely based on the production of oilseed of modified fatty acid composition. Several methods have been developed to this end. 

It is worth noting that the name Sunola for modified oils is used in Austraha for high-oleic sunflower oil, whereas, in Canada, it is a registered trademark of two oils of different composition one of higher hnoleic acid content than traditional sunflower and another of high-oleic type. Care must be taken that this should not lead to confusion. Canadian Western Grower Seed Corporation has also developed... 

SUNFLOWER SEED OE MODIFIED EATTY ACID COMPOSITION 679 TABLE 7. Fatty Acid Composition (%) of High-Oieic Sunfiower Oii (37, 41, 43). 

Breeding a mid-oleic sunflower requires at least one oleic parent. The USDA/ ARS Northern Crop Science Laboratory in Fargo, North Dakota, provided private companies with crossing lines of mid-oleic sunflower. Hybrid seeds were developed by traditional crossing methods no hybrids of transgenic sunflower were used. The mid-oleic concentration appears to be controlled by a partially dominant major gene and one or more dominant minor modifier genes (46, 47). 

The equilibrium moisture of seeds is modified upon dehulling. Equilibrium moisture values for undehulled sunflower seeds, hulls, and kernels are compared as a function of the relative humidity of the surrounding air at 25°C (Figure 16). The initial moisture content of all seeds was 5% (dry basis). Those samples stored at a relative humidity below 33% reached the equilibrium by desorption, and those at a relative humidity above 33% reached the equilibrium by adsorption (51). 

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