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Sulfuric acid amide esters

Sulfhydroxamic acids Sulfonylhydroxylamines Sulfuric acid amide esters... [Pg.252]

Sodium nitrite/hydrogen chloride Sulfuric acid amide esters and mixed sulf amides from sym. sulfamides... [Pg.328]

Iminosulfonic acid esters Sulfonic acid amides N-Sulfonylamines Sulfonylammonium salts, quaternary Sulfonyliminoesters Sulfurous acid amide esters Thionitric acid esters... [Pg.264]

Sulfamic acids Sulfenyl nitrates Sulfhydroxamic acids Sulfonylhydroxylamines 20 Sulfonyloxylamines Sulfuric acid amide esters Thionitrite ester S,S-dioxides... [Pg.546]

Sulfhydroxamic acids (Sulfonylhydroxylamines) Sulfuric acid amide esters Sulfonyloxylamines... [Pg.587]

Sulfuric acid esters with alcoholic or phenolic hydroxy groups, the mixed anhydrides adenosine-5 -sulfatophosphate and its 3 -phosphorylated derivative, as well as secondary products derived from L-cysteine occur in microorganisms, plants and animals. Sulfuric acid amides, e.g., the glucosinolates (D 9.4), are formed in certain plants. [Pg.324]

The amide group is readily hydrolyzed to acrylic acid, and this reaction is kinetically faster in base than in acid solutions (5,32,33). However, hydrolysis of N-alkyl derivatives proceeds at slower rates. The presence of an electron-with-drawing group on nitrogen not only facilitates hydrolysis but also affects the polymerization behavior of these derivatives (34,35). With concentrated sulfuric acid, acrylamide forms acrylamide sulfate salt, the intermediate of the former sulfuric acid process for producing acrylamide commercially. Further reaction of the salt with alcohols produces acrylate esters (5). In strongly alkaline anhydrous solutions a potassium salt can be formed by reaction with potassium / /-butoxide in tert-huty alcohol at room temperature (36). [Pg.134]

Sulfated Acids, Amides, and Esters. Reaction with sulfuric acid may be carried out on fatty acids, alkanolamides, and short-chain esters of fatty acids. The disodium salt of sulfated oleic acid is a textile additive and an effective lime soap dispersant. A typical sulfated alkanolamide stmcture is CiiH23C0NHCH2CH20S03Na. Others include the sulfates of mono and diethanolamides of fatty acids in the detergent range. The presence of... [Pg.244]

Antispasmodic activity, interestingly, is maintained even in the face of the deletion of the ethanolamine ester side chain. Reaction of anisaldehyde with potassium cyanide and dibutylamine hydrochloride affords the corresponding a-aminonitrile (72) (a functionality analogous to a cyanohydrin). Treatment with sulfuric acid hydrolyzes the nitrile to the amide to yield ambucet-amide (73). ... [Pg.94]

Benzyl cyanide is first reacted with 2-butylbromide in the presence of sodium amide to give 2-phenyl-3-methylvaleronitrile which is hydrolyzed by sulfuric acid to give 3-methyl-2-phenyl-pentanoic acid. 24 g of 2-phenyl-3-methyl-pentanoic acid are heated for one hour at 175° to 185°C with 30 g of 2-diethylaminoethanol and 0.5 g of sodium methylate. The excess diethyl-aminoethanol is removed in vacuo, the residue is dissolved in 300 cc of 2 N-acetic acid, the acid solution is shaken with ether and made alkaline with concentrated potassium carbonate solution and ice. The ether solution Is washed with water, dried with sodium sulfate and evaporated. The residue is distilled under high vacuum, yielding 20 to 21 g of the basic ester (60% of the theoretical) is obtained, the ester boiling at 98° to 100°C at a pressure of 0.03 mm. The hydrochloride of the ester melts at 112° to 113°C and the methobromide at 100° to 101°C. [Pg.1572]

Notice in the list of Lewis bases just given that some compounds, such as carboxylic acids, esters, and amides, have more than one atom ivith a lone pair of electrons and can therefore react at more than one site. Acetic acid, for example, can be protonated either on the doubly bonded oxygen atom or on the singly bonded oxygen atom. Reaction normally occurs only once in such instances, and the more stable of the two possible protonation products is formed. For acetic add, protonation by reaction with sulfuric acid occurs on... [Pg.59]

Surfactants are prepared which contain carboxylic acid ester or amide chains and terminal acid groups selected from phosphoric acid, carboxymethyl, sulfuric acid, sulfonic acid, and phosphonic acid. These surfactants can be obtained by reaction of phosphoric acid or phosphorus pentoxide with polyhydroxystearic acid or polycaprolactone at 180-190°C under an inert gas. They are useful as polymerization catalysts and as dispersing agents for fuel, diesel, and paraffin oils [69]. [Pg.565]

Amides are very weak nucleophiles, far too weak to attack alkyl halides, so they must first be converted to their conjugate bases. By this method, unsubstituted amides can be converted to N-substituted, or N-substituted to N,N-disubstituted, amides. Esters of sulfuric or sulfonic acids can also be substrates. Tertiary substrates give elimination. O-Alkylation is at times a side reaction. Both amides and sulfonamides have been alkylated under phase-transfer conditions. Lactams can be alkylated using similar procedures. Ethyl pyroglutamate (5-carboethoxy 2-pyrrolidinone) and related lactams were converted to N-alkyl derivatives via treatment with NaH (short contact time) followed by addition of the halide. 2-Pyrrolidinone derivatives can be alkylated using a similar procedure. Lactams can be reductively alkylated using aldehydes under catalytic hydrogenation... [Pg.513]


See other pages where Sulfuric acid amide esters is mentioned: [Pg.306]    [Pg.518]    [Pg.109]    [Pg.239]    [Pg.275]    [Pg.306]    [Pg.518]    [Pg.109]    [Pg.239]    [Pg.275]    [Pg.324]    [Pg.71]    [Pg.134]    [Pg.308]    [Pg.508]    [Pg.95]    [Pg.95]    [Pg.27]    [Pg.88]    [Pg.219]    [Pg.494]    [Pg.7]    [Pg.30]    [Pg.492]    [Pg.52]    [Pg.252]    [Pg.326]    [Pg.107]    [Pg.238]    [Pg.1184]    [Pg.22]    [Pg.147]    [Pg.231]    [Pg.38]   


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Amidation, esters

Esters amides

Sulfur amides

Sulfur esters

Sulfuric acid amides

Sulfuric acid esters

Sulfuric esters

Sulfurous acid esters

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