Stress and Temperature Effects

FigMre 8.30 Influence of stress cr and temperature T on creep behavior. 

Empirical relationships have been developed in which the steady-state creep rate as a function of stress and temperature is expressed. Its dependence on stress can be written 

How do I Solve Problems Using the Stress vs. Rupture Lifetime Graph  

Dependence of creep strain rate on stress and temperature (inK) 

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The first two terms on the right-hand side of equation [12.6] are viscoelastic terms proposed by Schapery, where e represents uniaxial kinematic (or total) strain at time t, o is the Cauchy stress at time t, is the instantaneous compliance and AD(r[i ) is a transient creep compliance function. The factor g defines stress and temperature effects on the instantaneous elastic compliance and is a measure of state dependent reduction (or increase) in stiffness. Transient compliance factor gi has a similar meaning, operating on the creep compliance component. The factor gj accounts for the influence of loading rate on creep. The function i ) represents a reduced timescale parameter defined by ... 

Chul Kim, U. R. and van Rooyen, D., Strain rate and temperature effects on the stress corrosion cracking of Inconel 600 steam generator tubing in the (PWR) primary water conditions , Proc. 2nd Int. Conf. on Environmental Degradation of Materials in Nuclear Power Systems-VIalet Reactors, Monterey, USA, 9-12 Sept. 1985, American Nuclear Society, pp. 448-55 (1986)... 

These recent tests were conducted at applied stress levels similar to those that might be experienced by ASME Section Vm, Division 2 vessels. Test exposure times exceeded 50,000 hours depending on applied stress and temperature. The test specimens were from weldments of thick section plates and represented base metal, weld metal, and heat-affected zone. Detrimental effects of hydrogen were found down to the Figure 1 limit of 850°F (454°C) at 2000 pounds per square inch absolute (14 megapascals) and 3000 pounds per square inch absolute (21 megapascals) hydrogen partial pressure. 

Thus the effects of the rate of application of stress and the ambient temperature must be recognized when polymers are used as structural materials, and definite rates and temperatures must be specified for tests, such as those for tensile and flexural strengths cited in Chapter 3. A knowledge of the structure of polymers is essential for the understanding of these effects, which differ from the effects of stress and temperature on all other materials of construction. 

Creep rates of three glassy polymers are much greater during electron irradiation than before or after. Radiation heating is eliminated as a possible cause. Essentially the same concentration of unpaired electrons and ratio of cross-linking to scission were found in polystyrene samples in the presence or absence of stress. The effects of radiation intensity, stress, and temperature on creep during irradiation are examined. The accelerated creep under stress is directly related to a radiation-induced expansion in the absence of stress. This radiation expansion is decreased by increase in temperature or plasticizer content and decrease in sample thickness. It is concluded that gas accumulation within the sample during irradiation causes both the expansion under no stress and the acceleration of creep under stress. 

The physical factors include mechanical stresses and temperature. As discussed above, IFP is uniformly elevated in solid tumors. It is likely that solid stresses are also increased due to rapid proliferation of tumor cells (Griffon-Etienne et al., 1999 Helmlinger et al., 1997 Yuan, 1997). The increase in IFP reduces convective transport, which is critical for delivery of macromolecules. The temperature effects on the interstitial transport of therapeutic agents are mediated by the viscosity of interstitial fluid, which directly affects the diffusion coefficient of solutes and the hydraulic conductivity of tumor tissues. The temperature in tumor tissues is stable and close to the body temperature under normal conditions, but it can be manipulated through either hypo- or hyper-thermia treatments, which are routine procedures in the clinic for cancer treatment. 

If desired, plasma oxide films can be doped much as the plasma nitride film we discussed earlier. In fact, doping with boron and phosphorus has been carried out as an alternative to the standard atmospheric-pressure thermal CVD process for BPSG.11 12 The latter process has the drawbacks of high defect density and poor thickness uniformity, so it was hoped that plasma BPSG would be an improvement. However, there are differences in the films in terms of H2 and N2 content, and their effect on reflow temperature, intrinsic stress and passivation effectiveness had to be examined. 

Moisture degradation of adhesive bonds occurs within the bulk adhesive material, at the adhesive-adherend interface, and within certain substrates. These degradation mechanisms are discussed below. Particularly insidious is the effect of the combined elements of moisture, stress, and temperature. Unfortunately, this synergistic effect occurs at relatively low temperatures, and such a service environment is common to many adhesive applications. For these reasons, this combined environment is given special focus in Sec. 15.5.2. 

RATE AND TEMPERATURE EFFECTS ON THE PLANE STRESS ESSENTIAL WORK OF FRACTURE IN SEMICRYSTALLINE PET... 

Aim of this paper is to investigate if the rate and temperature effects on the fracture parameters obtained by the EWF approach under plane stress condition are in some way related to the viscoelastic nature of the selected material (semicrystalline PET). 

Two mechanisms of yielding may be distinguished in polymers diear yielding, which occurs essentially at constant volume, and crazing, which is a dilatation process. There are important differences between the two mechanisms, both in their dependence upon stress and temperature, and in their effects on fracture behaviour. 

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