High-Alloy Steels

Table 4-15 lists base materials Elliott has tested. This list, which is continually being expanded, includes low alloy steels, high alloy iron base, nickel base, cobalt base materials, and odiers. Table 4-16 shows some of the coatings Elliott has tested. The list indicates die supplier, coating designation, and major components of the coating composition. 

Tube O.D. Carbon Steel High Alloy Steel (750) Low Alloy Steel (850) Nickel-Cooper (600) Nickel (850) Nickel-Chromium-Iron (1000) Alum mum Almninmn Alloys, Copper Copper Alloys, Titanimn Alloys at Code Maximmn Allowable Temperature... 

Steel, low-aUoy Steel, high-alloy apparatus scafiR>lds, pipelines... 

Wensley et al. [65-68] conducted tests for several years with duplex stainless steels, highly alloyed austenitic stainless steels, and nickel-base alloys in a CIO2 washer using creviced coupons. These tests revealed that in near-neutral D-stage environments all the stainless steels suffered crevice... 

The substrate is most likely to be austenitic or ferritic stainless steel, high-alloy steels, nickel-base alloys (e.g., Inconels), or cast grades of Stellite (Co-Cr-W-C) materials. 

National Institute of Standards and Technology (NIST). The NIST is the source of many of the standards used in chemical and physical analyses in the United States and throughout the world. The standards prepared and distributed by the NIST are used to caUbrate measurement systems and to provide a central basis for uniformity and accuracy of measurement. At present, over 1200 Standard Reference Materials (SRMs) are available and are described by the NIST (15). Included are many steels, nonferrous alloys, high purity metals, primary standards for use in volumetric analysis, microchemical standards, clinical laboratory standards, biological material certified for trace elements, environmental standards, trace element standards, ion-activity standards (for pH and ion-selective electrodes), freezing and melting point standards, colorimetry standards, optical standards, radioactivity standards, particle-size standards, and density standards. Certificates are issued with the standard reference materials showing values for the parameters that have been determined. 

Plain Carbon and Low Alloy Steels. For the purposes herein plain carbon and low alloy steels include those containing up to 10% chromium and 1.5% molybdenum, plus small amounts of other alloying elements. These steels are generally cheaper and easier to fabricate than the more highly alloyed steels, and are the most widely used class of alloys within their serviceable temperature range. Figure 7 shows relaxation strengths of these steels and some nickel-base alloys at elevated temperatures (34). 

An important iadustrial use of NaH involves its in situ formation ia molten NaOH or ia fused eutectic salt baths. At concentrations of 1—2% NaH, these compositions are powerful reducing systems for metal salts and oxides (5). They have been used industrially for descaling metals such as high alloy steels, titanium, zirconium, etc. 

Calcium hydride is prepared on a commercial scale by heating calcium metal to about 300°C in a high alloy steel, covered cmcible under 101 kPa (1 atm) of hydrogen gas. Hydrogen is rapidly absorbed at this temperature and the reaction is exothermic. 

P/M Tool Steels. In conventionally produced high alloy tool steels (slowly cooled cast ingots), carbide tends to segregate (48). Segregated clusters of carbide persist even after hot working, and cause undesirable effects on tool fabrication and tool performance. P/M tool steels, on the other hand, provide very fine and uniform carbides in the compact, the final bar stock, and the tools. Several tool steel suppHers consoHdate gas-atomized tool steel powder by HIP to intermediate shapes, which are then hot-worked to final mill shapes. Water-atomized tool steel powder is also available (see also T OOL materials). ... 

Parameter Carbon and low—medium aHoy steels High speed steels Cast cobalt alloys Carbides Cemented Coated Ceramics Polycrystalline cBN Diamond... 

Low—medium alloy steels contain elements such as Mo and Cr for hardenabiHty, and W and Mo for wear resistance (Table 4) (7,16,17) (see Steel). These alloy steels, however, lose their hardness rapidly when heated above 150—340°C (see Fig. 3). Furthermore, because of the low volume fraction of hard, refractory carbide phase present in these alloys, their abrasion resistance is limited. Hence, low—medium alloy steels are used in relatively inexpensive tools for certain low speed cutting appHcations where the heat generated is not high enough to reduce their hardness significantly. 

The hydrocarbon gas feedstock and Hquid sulfur are separately preheated in an externally fired tubular heater. When the gas reaches 480—650°C, it joins the vaporized sulfur. A special venturi nozzle can be used for mixing the two streams (81). The mixed stream flows through a radiantly-heated pipe cod, where some reaction takes place, before entering an adiabatic catalytic reactor. In the adiabatic reactor, the reaction goes to over 90% completion at a temperature of 580—635°C and a pressure of approximately 250—500 kPa (2.5—5.0 atm). Heater tubes are constmcted from high alloy stainless steel and reportedly must be replaced every 2—3 years (79,82—84). Furnaces are generally fired with natural gas or refinery gas, and heat transfer to the tube coil occurs primarily by radiation with no direct contact of the flames on the tubes. Design of the furnace is critical to achieve uniform heat around the tubes to avoid rapid corrosion at "hot spots."... 

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