Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Solubility synthesis

Higuchi, T. Pitman, I.H. Caffeine complexes with low water solubility synthesis and dissolution rates of 1 1 and 1 2 caffeine-gentisic acid complexes. J. Pharm. Sci. 1973, 62, 55-58. [Pg.634]

Schreiner et al. developed thiourea catalyst as a promising hydrogen donor, which has more benefit in solubility, synthesis and catalytic mrn over number compared with urea catalyst, in the Diels-Alder reaction of A-crotonyloxazolidinone and cyclopentadiene [22,23] (Table 9.7). A,A -Di[3,5-bis(trifluoromethyl)phenyl]thiourea accelerates the reaction and improves stereoselectivity (run 4) similar to a metal catalyst such as aluminium chloride (AICI3) (mn 2) or titanium chloride (TiCls) (run 3). [Pg.281]

H2N-CH2 [CH2j3.CH(NH2) COOH. Colourless needles, m.p. 224 C (decomp.), very soluble in water, insoluble in alcohol. L-(-H)-Lysine is one of the basic amino-acids occurring in particularly large quantities in the protamine and histone classes of proteins. It is an essential amino-acid, which cannot be synthesized by the body and must be present in the food for proper growth. It can be manufactured by various fermentation processes or by synthesis. [Pg.244]

Transfer or soluble RNAs are specific carrier molecules for amino-acids during protein synthesis on ribosomes with ribosomal RNA as the template. There is at least one t-RNA molecule for each amino-acid. [Pg.283]

There are, indeed, many biological implications that have been triggered by the advent of fullerenes. They range from potential inhibition of HIV-1 protease, synthesis of dmgs for photodynamic therapy and free radical scavenging (antioxidants), to participation in photo-induced DNA scission processes [156, 157, 158, 159, 160, 161, 162 and 163]. These examples unequivocally demonstrate the particular importance of water-soluble fullerenes and are summarized in a few excellent reviews [141, 1751. [Pg.2420]

The first step in designing a precursor synthesis is to pick precursor molecules that, when combined in organic solvents, yield the bulk crystalline solid. For metals, a usual approach is to react metal salts with reducing agents to produce bulk metals. The main challenge is to find appropriate metal salts that are soluble in an organic phase. [Pg.2901]

Leff D V, Brandt L and Heath J R 1996 Synthesis and oharaoterization of hydrophobio organioally-soluble gold nanoorystals funotionalized with primary amines Langmuir 12 4723... [Pg.2917]

Then N-Boc-O-benzylserine is coupled to the free amino group with DCC. This concludes one cycle (N° -deprotection, neutralization, coupling) in solid-phase synthesis. All three steps can be driven to very high total yields (< 99.5%) since excesses of Boc-amino acids and DCC (about fourfold) in CHjClj can be used and since side-reactions which lead to soluble products do not lower the yield of condensation product. One side-reaction in DCC-promoted condensations leads to N-acylated ureas. These products will remain in solution and not reaa with the polymer-bound amine. At the end of the reaction time, the polymer is filtered off and washed. The times consumed for 99% completion of condensation vary from 5 min for small amino acids to several hours for a bulky amino acid, e.g. Boc-Ile, with other bulky amino acids on a resin. A new cycle can begin without any workup problems (R.B. Merrifield, 1969 B.W. Erickson, 1976 M. Bodanszky, 1976). [Pg.232]

K. Osseo-Asare, F. J. Arriagada, and J. H. Adair, "Solubility Relationships in the Coprecipitation Synthesis of Barium Titanate Heterogeneous Equihbria in the Ba—Ti—C2O4—H2O System," in G. L. Messing, E. R. Fuller, Jr., and Hans Hausin, eds.. Ceramic Powder Science Vol. 2,1987, pp. 47-53. [Pg.315]

Nizatidine. Nizatidine, or Axid [76963 1-2] (3), is an off-white to buff crystalline solid. It is soluble in water and its method of synthesis is available (4). [Pg.199]

Cyclizine Hydrochloride. l-(Diphenylmethyl)-4-methylpipera2ine monohydrochloride [303-25-3] (Mare2ine) (17) is a white crystalline powder, or small colorless crystals, that is odorless or nearly so and has a bitter taste. It melts indistinctly and with decomposition at ca 285°C. One gram of cycli2ine hydrochloride [303-25-3] is soluble in 115 mL water, 115 mL ethanol, and 5 mL chloroform it is insoluble in diethyl ether. It may be made by the synthesis shown in Reference 15. [Pg.204]

Meclizine Hydrochloride. Pipera2ine Antivert, and Bonine are trade names for mech2ine dihydrochloride monohydrate [31884-77-2] (20). It is a white or slightly yellowish crystalline powder with a slight odor, no taste, and a melting point of 217—224°C. The hydrochloride is practically insoluble in water and ether. It is freely soluble in chloroform, pyridine, methylacetamide, and mild acid alcohol—water mixtures, and is slightly soluble in dilute acids or alcohol. See Reference 16 for synthesis. [Pg.204]

It has also been found that polymers possessing functional groups such as amines and pyridines are soluble in pregeUed sol solutions, especially, poly(2-vin5ipyridine) and poly(N-vinylpyrroHdinone) (PVP) (49). There, materials were made as part of a study of the synthesis of nonshrinking sol—gel-derived networks (49). [Pg.329]

Synthesis and Properties. Several methods have been suggested to synthesize polyimides. The predominant one involves a two-step condensation reaction between aromatic diamines and aromatic dianhydrides in polar aprotic solvents (2,3). In the first step, a soluble, linear poly(amic acid) results, which in the second step undergoes cyclodehydration, leading to an insoluble and infusible PL Overall yields are generally only 70—80%. [Pg.530]

A successful synthesis of novel, soluble aromatic Pis involving 3,4-bis-(4-aminophen5l)-2,5-diphen5lfuran by polymerization with aromatic tetracarboxyhc dianhydrides through the conventional two-step method has been reported (6) (Fig. I). [Pg.530]

The synthesis of phenoxaphosphine-containing PODs by the cyclodehydration of polyhydra2ides obtained from 2,8-dichloroformyl-lO-phenylphenoxaphosphine-lO-oxide and aUphatic and aromatic dihydra2ides has been described (60). All polymers are soluble in formic acid, y -cresol, and cone H2SO4, but insoluble or partially soluble in ben2ene, chloroform, and hexamethylphosphoric triamide. [Pg.535]

The polymerization of A/-(2-tetrahydropyranyl)aziridine with subsequent hydrolysis of the resulting polymers has been described as an alternative route for the synthesis of linear polyethyleneimine (359). Linear polyethyleneimine, in contrast to branched polyethyleneimines, is only sparingly soluble in water at room temperature. [Pg.11]

FK-506 (37) interferes with IL-2 synthesis and release and has a cyclosporin-like profile, but is considerably more potent in vitro. IC q values are approximately 100-fold lower. This neutral macroHde suppresses the mixed lymphocyte reaction T-ceU proliferation generation of cytotoxic T-ceUs production of T-ceU derived soluble mediators, such as IL-2, IL-3, and y-IFN and IL-2 receptor expression (83). StmcturaHy, FK-506 is similar to sirolimus. Mycophenolate mofetil (33), brequinar (34), and deoxyspergualin are in various phases of clinical evaluation. Identification of therapeutic efficacy and safety are important factors in the deterrnination of their utiUty as immunosuppressive agents. [Pg.42]

Soluble and weU-characterized polygermane homopolymers, (R Ge), and their copolymers with polysdanes have been prepared by the alkaH metal coupling of diorgano-substituted dihalogermanes (137—139), via electrochemical methods (140), and by transition-metal catalyzed routes (105), as with the synthesis of polysdanes. [Pg.263]

Nitrates. Iron(II) nitrate hexahydrate [14013-86-6], Fe(N03)2 6H20, is a green crystalline material prepared by dissolving iron in cold nitric acid that has a specific gravity of less than 1.034 g/cm. Use of denser, more concentrated acid leads to oxidation to iron(III). An alternative method of preparation is the reaction of iron(II) sulfate and barium or lead nitrate. The compound is very soluble in water. Crystallisation at temperatures below — 12°C affords an nonahydrate. Iron(II) nitrate is a useful reagent for the synthesis of other iron-containing compounds and is used as a catalyst for reduction reactions. [Pg.437]

Tris(2,4-pentanedionato)iron(III) [14024-18-1], Fe(C H202)3 or Fe(acac)3, forms mby red rhombic crystals that melt at 184°C. This high spin complex is obtained by reaction of iron(III) hydroxide and excess ligand. It is only slightly soluble in water, but is soluble in alcohol, acetone, chloroform, or benzene. The stmcture has a near-octahedral arrangement of the six oxygen atoms. Related complexes can be formed with other P-diketones by either direct synthesis or exchange of the diketone into Fe(acac)3. The complex is used as a catalyst in oxidation and polymerization reactions. [Pg.438]

Examples of polymers which form anisotropic polymer melts iaclude petroleum pitches, polyesters, polyethers, polyphosphaziaes, a-poly- -xyljlene, and polysdoxanes. Synthesis goals iaclude the iacorporation of a Hquid crystal-like entity iato the maia chaia of the polymer to iacrease the strength and thermal stabiHty of the materials that are formed from the Hquid crystal precursor, the locking ia of Hquid crystalline properties of the fluid iato the soHd phase, and the production of extended chain polymers that are soluble ia organic solvents rather than sulfuric acid. [Pg.201]


See other pages where Solubility synthesis is mentioned: [Pg.23]    [Pg.133]    [Pg.10]    [Pg.252]    [Pg.191]    [Pg.330]    [Pg.317]    [Pg.205]    [Pg.254]    [Pg.254]    [Pg.255]    [Pg.419]    [Pg.539]    [Pg.45]    [Pg.218]    [Pg.478]    [Pg.481]    [Pg.500]    [Pg.75]    [Pg.256]    [Pg.434]    [Pg.437]    [Pg.437]    [Pg.440]    [Pg.440]    [Pg.227]    [Pg.45]   
See also in sourсe #XX -- [ Pg.209 , Pg.210 , Pg.211 , Pg.212 , Pg.213 , Pg.214 , Pg.215 , Pg.216 , Pg.217 , Pg.218 , Pg.219 , Pg.220 , Pg.221 , Pg.222 , Pg.223 , Pg.224 ]




SEARCH



Biodegradable water-soluble polymers synthesis

Chemical synthesis solubility problem

Chemical synthesis, polymers solubility

Chemical synthesis, polymers soluble

Enzymatic synthesis solubility

OLIGOSACCHARIDE SYNTHESIS ON SOLID, SOLUBLE POLYMER, AND TAG SUPPORTS

Organic synthesis on soluble polymeric supports

Other Soluble Multivalent Supports in Organic Synthesis

Peptide synthesis soluble polymeric reagents

Polybenzimidazole synthesis solubility

Polymer synthesis solubility

Silica Existence, Solubility, and Synthesis

Soluble Supports in Solution-Phase Combinatorial Synthesis

Soluble guanylate cyclase activation synthesis

Soluble polymer-supported combinatorial synthesis,

Soluble polymer-supported enzymatic synthesis

Soluble polymer-supported synthesis

Soluble polysilane synthesis

Soluble resin-based synthesis

Soluble supports synthesis

Soluble synthesis

Soluble synthesis

Syntheses multistep, soluble polymers

Synthesis and Characterization of New Highly Soluble Organic Polyimides

Synthesis of Biodegradable Water-Soluble Polymers

Synthesis of synthetic water soluble polymers

Synthesis of water-soluble polyaniline

Synthesis on soluble polymers

Synthesis water-soluble polymers, influence

Water soluble, synthesis using

Water-soluble cellulose ether synthesis

Water-soluble polyaniline, synthesis

© 2024 chempedia.info