Single base propellant composition

Examples of single- and double-based propellant compositions are given in Table 10.1 and Table 10.2. 

Explosive material with low rate of combustion. May be either solid or liquid. Will burn smoothly at uniform rate after ignition without depending on interaction with atmosphere. Single base propellant consists primarily of matrix of nitrocellulose. Double base propellant contains nitrocellulose and nitroglycerine. Composite propellant contains oxidizing agent in matrix of binder. 

The propellants (powder) used for military weapons is smokeless powder. Depending on composition, a differentiation is made between single base propellant, double base propellant and triple base propellant. 

Single-base propellants are used in all kinds of guns from pistols to artillery weapons. The composition consists of 90% or more of nitrocellulose which has a nitrogen content of 12.5-13.2%. The nitrocellulose is gelled by adding a plasticizer such as carbamite or... 

Current propellent explosives may be divided into three classes single base, double base and composite however double base propellants which contain picrite are often considered a separate class and called triple base. 

Though the theoretical of black powder is less than that of single-base, doublebase, and AP-based composite propellants, black powder is useful for short-duration operation of simple propulsive systems. The advantages of the use of black powder are its low cost, its minimal deterioration with age, and simple regulation of the propulsive force by adjustment of the quantities used. 

Nitrocellulose-Base Solid Propellants, Including Single-Base, Double-Base and Triple-Base Propellants (1371—1405) Composite Propellants (1405—07)... 

Since the development of this terpolymer in 1957, more solid composite rocket propellant has been produced from PBAN than from any other single prepolymer. Propellants based on this material have been used successfully in applications ranging from small tactical motors to the 260-in. diameter motor containing greater than 2,000,000 lb. of propellant. PBAN propellants, therefore, have been and are expected to be a major factor in making solid rocket motors during the next several years. The thermal stability which has been achieved, low temperature cycling characteristics, and low cost of propellants based on this prepolymer make this system attractive. 

Solid propellants may be classified as monopropellants or composite propellants. Monopropellants are substances in which the fuel and oxidizer are both contained within the same molecule or at least in a single phase. These materials may either burn slowly at subsonic rates or may decompose rapidly in detonation. Depending on the use to which this type of material is put, it may be classified either as propellant or high explosive. In general, useful monopropellants are difficult to detonate. The typical example of a monopropellant is the so-called double-base propellant. This substance consists of nitrocellulose which has been colloidized by nitroglycerine along with various minor constituents which have been added to... 

Accdg to compositions, cannon smokeless proplnts may be subdivided into single-base-, double-base- and triple-base-proplnts. The last two proplnts are sometimes called "compound proplnts. The so-called "composite proplnts, used in JATOS and rockets, are described under Composite Propellants... 

Analysis of the nny 82 ammunition as previously detailed shows that it uses a mercuric corrosive primer. Analysis of the Chinese 351/73 ammunition revealed that it has a copper-coated iron-jacketed bullet with an iron core and a lead tip, the cartridge case is steel with a brown colored lacquered finish, a brass primer cup, and the propellant is single based with DPA, 2 x nitrodiphenylamines, camphor, and contains no inorganic additives, and the discharged primer composition is antimony, potassium, chlorine, mercury, tin, sulfur, iron, manganese, phosphorus, zinc, and lead in descending order (lead, antimony, mercury type). 

High explosives may be class d according to their physical properties as powdery, meltable, semi-meltable and plastic. Propellants may be grouped on the basis of chemical composition into gun powder and similar mixtures, nitrocellulose (single base) and nitroglycerine (double base) powders, With respect to their uses and some properties they are divided into black powder, smokeless and flashless powders, and rocket propellants. 

Pyropowder = single base nitrocellulose propellant (UK) pyrotechnical compositions 28 29 ... 

The propellant which has exclusively been used for a long time in conventional military weapons is the smokeless (or, more accurately, low-smoke) powder. According to its composition, it can be classified as single-base powders (e.g., nitrocellulose powder), doublebase powders (e.g., nitroglycerine powder) and triple-base powders (e.g., nitrocellulose + nitroglycerine (or diglycol dinitrate) + nitroguanidine powders). 

Some information based on the description by Steiiiberger and Orechse [40] is given here. They give the composition of single base, double base and coiii-pi>sile cast propellants in Table 123. 

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