Silica sands

This type of sand is the most commonly used, mostly because of its wide availability and its relatively low cost. Silica sand is composed of the mineral quartz (Si02), which is more or less pure and clean, depending on its origin. Its dry piece specific weight fluctuates between 2.5 to 2.8 kg/dm. The dry bulk density (or loose volume weight) of silica sand is 1.4 to 1.6 kg/dm.  

Silica sand is neutral and is compatible with all binders and normal cast alloys. The respirable particulate matter (RPM) fraction of quartz is classified by lARC as carcinogenic [233, lARC, 1997]. This is a health and safety issue. Studies are ongoing to determine whether or not an air pollution issue also exists. The amount of quartz in dust is defined by the content of quartz in the input materials. 

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Silica sand (white, sterilized and washed) or Celite... 

Transparent fused silica can be formed at a temperature of 1200°C and a pressure of 13.8 MPa (2000 psi) from silica powder consisting of 15 nm ultimate particles (92) or by electric arc fusion of pure silica sand having low iron and alkali metal contents. The cooled product is ground to the desired particle size. Fused sihca is primarily manufactured by C-E Minerals, Minco, and Precision Electro Minerals in the United States by Chuo Denko, Denki Kagaku Kogyo, NKK, Showa Denko, and Toshiba Ceramics in Japan. Based on 1988 data and projected growth, an estimated 135,000 metric tons of fused siUca were used in 1994 as a sacrificial component or investment casting in the manufacture of metals and as a component in refractory materials (62). 

The hot-water separation process involves extremely compHcated surface chemistry with interfaces among various combinations of soUds (including both silica sand and alurninosilicate clays), water, bitumen, and air. The control of pH is critical. The preferred range is 8.0—8.5, achievable by use of any of the monovalent bases. Polyvalent cations must be excluded because they tend to flocculate clays and thus raise viscosity of the middlings in the separation cell. 

Hydraulic limes (84) may be used for mortar, stucco, or the scratch coat for plaster. They harden slowly under water, whereas high calcium limes, after slaking with water, harden in air to form the carbonate but not under water at ordinary temperatures. However, at elevated temperatures achieved with steam curing, lime—silica sand mixtures do react to produce durable products such as sand—lime bricks. 

Typical applications include primary devv atering of phosphate rock matrix and silica sand products following vv et screening. In ore dressing it is used rnainlv to protect large-diameter thickeners bv scalping out-l-65-mesh material,... 

Feldspar Silica sand Enamel frit Grog... 

Coal (hard) and coke are used in water filtration, primarily for the removal of coarse suspensions, care being taken to prevent them from scouring or washing away, because of their relative lighmess and fine division. Coal is principally composed of carbon, and is inert to acids and alkalies. Its irregular shapes are advantageous at times over silica sand. 

Spat lackp m. barytes lake, -sandp m. silica sand. Saure, /. hydrofluoric acid, -stein, m. selenite (the mineral). 

Traditionally ceramic raw materials have been dug out of the ground and used with little or no treatment or purification. Sand, fireclay, talc, and gypsum are examples. The energy expenditure for producing these materials is therefore small. Some of these materials can be found naturally in high purity. Silica sands (SiO,) with less than 100 ppm (parts per mil-... 

The name derives from the firebed produced by containing a mixture of silica sand and ash through which air is blown to maintain the particles in suspension. The beds are in three categories, shallow bed, deep bed and... 

Iron is associated with silica sand, usually as a light surface stain on the grains. Amber glass develops ionic color centers or complexes of Fe-S-C added to the batch as iron sulfide and powdered anthracite. Although the Fe content be four or five times that shown in the example in Table I, it appears to be bound in the complex so that no greater extraction occurs with the S and C. Titanium is associated with sand as... 

Massimilla et al. (M5) measured the rate of absorption of carbon dioxide in water from a mixture of carbon dioxide and nitrogen. Used as solid phase were silica sand particles of average equivalent diameter 0.22 mm, or glass ballotini of average equivalent diameter 0.50 and 0.80 mm. Columns of 30-and 90-mm i.d. were used, and the column height was varied from 100 to 1200 mm. 

FIGURE 14.33 Three common forms of silica (Si02) (a) quartz (b) quartzite and (c) cristobalite. The black parts of the sample of cristobalite are obsidian, a volcanic rock that contains silica. Sand consists primarily of small pieces of impure quartz. 

A preliminary test for the biodegradability of the 3-phenyl- and 3-carbamoyl-2(lH)pyridones was conducted in a barnyard humus suspension. The analysis by HPLC showed some loss, and the fluorescent compounds seemed to be adsorbed onto the solid. The 3-carbamoyl-2(lH)pyridone (II) also hydrolyzed to 3-carboxylic acid-2(lH)pyridone both in the slurry test and in water solutions that had been left standing 1-2 weeks. In preliminary tests both the 3-phenyl- and the 3-carbamoyl-2(lH)pyridones apparently adsorbed to some extent on silica sand columns. In addition, the solubility of both 1-H compounds was somewhat low, 1.3 x 10 M for II, and 1.0 x 10 M for IV. 

Interactions of Metal Salts with the Formation. Interactions of metal salts with the formation and distribution of the retained aluminum in a porous medium may significantly affect the location and strength of gels. This interaction was demonstrated with polyacrylamide-aluminum citrate gels [1514]. Solutions were displaced in silica sand. The major findings of this study are that as the aluminum-to-citrate ratio increases, the aluminum retention increases. Furthermore, the amount of aluminum retained by silica sand increases as the displacing rate decreases. The process is reversible, but the aluminum release rate is considerably slower than the retention rate. The amount of aluminum released is influenced by the type and the pH level of the flowing solution. The citrate ions are retained by silica sand primarily as a part of the aluminum citrate complex. Iron, cations, and some divalent cations cannot be used in the brine environment. 

C. A. Rocha, D. W. Green, G. P. Willhite, and M. J. Michnick. An experimental study of the interactions of aluminum citrate solutions and silica sand. In Proceedings Volume, pages 403-413. SPE Oilfield Chem Int Symp (Houston, TX, 2/8-2/10), 1989. 

After the silica flour or soil mixture has set, add a layer of silica sand as a filter pack, then fill the remainder of the borehole with bentonite or a grout seal (Figure 5). Access lines may be run from the lysimeter reservoir through a protective PVC riser pipe to the land surface. A locking protective casing should be used to secure the abovegrade lysimeter components. If the lysimeter is used immediately after installation, it is necessary to purge any water used to prepare the siiica flour or soil slurry. Remove at least the water volume equivalent to approximately one third of that used to make slurry. 

The flotation unit maximum loading is 2.1 L/s/m2 (3.1 gal/min/ft2). The maximum filtration rate is 1.7 L/s/m2 (2.5 gal/min/ft2). Each filter compartment is backwashed at or more than 10.2 L/s/m2 (15 gal/min/ft2) during the backwash operation. The single-medium backwash filter consists of 28 mm (11 in.) high-grade silica sand. The effective size and uniformity coefficient for the sand are 0.35 mm and 1.55, respectively. 

The composition of the particles is related to that of the source rocks. Quartz sand [composed of silica (silicon dioxide)], which makes up the most common variety of silica sand, is derived from quartz rocks. Pure quartz is usually almost free of impurities and therefore almost colorless (white). The coloration of some silica sand is due to chemical impurities within the structure of the quartz. The common buff, brown, or gray, for example, is caused by small amounts of metallic oxides iron oxide makes the sand buff or brown, whereas manganese dioxide makes it gray. Other minerals that often also occur as sand are calcite, feldspar and obsidian Calcite (composed of calcium carbonate), is generally derived from weathered limestone or broken shells or coral feldspar is an igneous rock of complex composition, and obsidian is a natural glass derived from the lava erupting from volcanoes see Chapter 2. 

It seems that sometime during the third millennium b.c.e., somewhere in the Middle East, it was discovered that when a mixture of silica sand and soda is heated to relatively high temperatures, the mixture fuses to form glass. Few other human-made materials are derived, as is glass, from such common and abundant raw materials. Its remarkable physical and chemical properties made glass, already in antiquity, one of the most useful and ubiquitous materials in many areas of the world. 

The addition of a relatively small amount of such substances as soda, potash, or borax, all known as fluxes or fluxing materials, lowers the melting temperature of silica sand from over 1700°C to below 1000°C, a temperature feasible in ancient furnaces (see Textbox 28). 

Hollow sand casting is a relatively simple process for making cast metal objects that for thousands of years was the most widely used of all casting methods. For the most basic castings, the molds are made from ordinary silica sand mixed with water so as to keep the sand particles compacted together to maintain the required hollow-shaped form. The hot, fluid... 

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