Shattering

CAUTION. Ethers that have been stored for long periods, particularly in partly-filled bottles, frequently contain small quantities of highly explosive peroxides. The presence of peroxides may be detected either by the per-chromic acid test of qualitative inorganic analysis (addition of an acidified solution of potassium dichromate) or by the liberation of iodine from acidified potassium iodide solution (compare Section 11,47,7). The peroxides are nonvolatile and may accumulate in the flask during the distillation of the ether the residue is explosive and may detonate, when distilled, with sufficient violence to shatter the apparatus and cause serious personal injury. If peroxides are found, they must first be removed by treatment with acidified ferrous sulphate solution (Section 11,47,7) or with sodium sulphite solution or with stannous chloride solution (Section VI, 12). The common extraction solvents diethyl ether and di-tso-propyl ether are particularly prone to the formation of peroxides. 

Furfural is very thermally stable in the absence of oxygen. At temperatures as high as 230°C, exposure for many hours is required to produce detectable changes in the physical properties of furfural, with the exception of color (17). However, accelerating rate calorimetric data shows that a temperature above 250°C, in a closed system, furfural will spontaneously and exothermically decompose to furan and carbon monoxide with a substantial increase in pressure. The pressure may increase to 5000 psi or more, sufficient to shatter the container (18). 

Safety Standards. Protection from laser beams involves not allowing laser radiation at a level higher than a maximum permissible exposure level to strike the human body. Maximum permissible exposure levels for both eyes and skin have been defined (55—57). One of the most common safety measures is the use of protective eyewear. Manufacturers of laser safety eyewear commonly specify the attenuation at various laser wavelengths. Under some conditions safety eyewear has been known to shatter or to be burned through (58), and it is not adequate to protect a wearer staring directly into the beam. 

Alkan olamines ate used in urethane coatings for glass shatter proofing (68) and have been utilized as amides, salts, or free amines in providing antifrosting, antifogging, and dirt-resistant films on glass and plastics (69—72). 

In certain diseases, such as osteomalacia, syphilis, and osteomyeHtis, bones break spontaneously and without a trauma. The severity of the fracture usually depends on the force that caused the fracture. If a bone s breaking point was exceeded only slightly, then the bone may crack rather than break all the way through. If the force is extreme, such as in an automobile collision or a gunshot, the bone may shatter. An open or compound fracture is particularly serious because infection is possible in both the wound and the bone. A serious bone infection can result in amputation. 

Most metals, concrete, and other constmction materials are corroded by hydrobromic acid. Suitable materials of constmction include some fiber glass-reinforced plastics, some chemically resistant mbbers, PVC, Teflon, polypropylene, and ceramic-, mbber-, and glass-lined steel. Metals that are used include HasteUoy B, HasteUoy C, tantalum, and titanium. The HasteUoys can only be used at ambient temperatures. Liquid hydrogen bromide under pressure in glass at or above room temperature can attack the glass resulting in unexpected shattering. 

The drop shatter test indicates the resistance of a coal or coke to breakage on impact (see D440). A sample is dropped in a standard way a number of times from a specified height. Eor the tumbler test or abrasion index (ASTM D441), the coal or coke is rotated in a dmm to determine the resistance to breakage by abrasion (18). 

Dental abrasives range in fineness from those that do not damage tooth stmcture to those that cut tooth enamel. Abrasive particles should be irregular and jagged so that they always present a sharp edge, and should be harder than the material abraded. Another property of an abrasive is its impact strength, ie, if the particle shatters on impact it is ineffective if it never fractures, the edge becomes dull. Other desirable characteristics include the abiUty to resist wear and solvation. 

The capacity of siUca gel is shown in Figures 9a and 9b, and the shape of the isotherm is similar to activated alumina. At saturation (pjp° = 1-0), sihca gel, which takes up 40 kg H2O /100 kg of adsorbent, has the highest capacity of the desiccants shown. However, some high capacity siUca gels tend to shatter in the presence of Hquid water. When Hquid water may be present, a lower capacity, water-resistant siUca gel must be used. 

Droplet breakup via impingement appears to follow a similar relationship, but much less data is available. This type of breakup can result from impingement on equipment walls or compressor blades. In general, there is less tendency to shatter on wetted surfaces. 

Solid Dispersion If the process involves the dispersion of sohds in a liquid, then we may either be involved with breaking up agglomerates or possibly physically breaking or shattering particles that have a low cohesive force between their components. Normally, we do not think of breaking up ionic bonds with the shear rates available in mixing machineiy. 

As an aside, when a large liquid droplet is broken up by shear stress, it tends initially to elongate into a dumbbell shape, which determines the particle size of the two large droplets formed. Then, the neck in the center between the ends of the dumbbell may explode or shatter. This would give a debris of particle sizes which can be quite different than the two major particles produced. 

Nonmechanical introduction of energy (Thermal shock, explosive shattering, electrohydraulic)... 

Not all rocks shatter well by impact. Impacl breaking is best suited for the reduction of relatively nonabrasive and low-silica-content materials such as hmestone, dolomite, anhydrite, shale, and cement rock, the most popular application being on limestone. 

F TgAR/Mae = FeR/mag for vessel completely shattered into many... 

Fragments Generated by Complete Shattering of Spherical Vessel Pressurized by an Inert ideal Gas... 

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