Wavelength, laser

As an example, we mention the detection of iodine atoms in their P3/2 ground state with a 3 + 2 multiphoton ionization process at a laser wavelength of 474.3 run. Excited iodine atoms ( Pi/2) can also be detected selectively as the resonance condition is reached at a different laser wavelength of 477.7 run. As an example, figure B2.5.17 hows REMPI iodine atom detection after IR laser photolysis of CF I. This pump-probe experiment involves two, delayed, laser pulses, with a 200 ns IR photolysis pulse and a 10 ns probe pulse, which detects iodine atoms at different times during and after the photolysis pulse. This experiment illustrates a frindamental problem of product detection by multiphoton ionization with its high intensity, the short-wavelength probe laser radiation alone can photolyse the... 

In a MALDl experiment, the sample is mixed or dissolved in a matrix material that has an absorption spectrum matching the laser wavelength of energy, The sample may not have a matching absorption peak (a), but this is not important because the matrix material absorbs the radiation, some of which is passed on to the dissolved sample. Neutral molecules and ions from both sample and matrix material are desorbed (b). 

Lasing substances Physical state Laser wavelength (nm) Pulse length or continuous wave Typical maximum power output (watts)... 

Chemical reactants Excited state species Laser wavelength (nm)... 

If the target at which a laser beam is directed can absorb light of the laser wavelength, then the target will absorb a large amount of energy in a very small space in a very short time. 

Most Ar and Kr lasers are CW. A gas pressure of about 0.5 Torr is used in a plasma tube of 2-3 mm bore. Powers of up to 40 W distributed among various laser wavelengths can be obtained. 

Safety Standards. Protection from laser beams involves not allowing laser radiation at a level higher than a maximum permissible exposure level to strike the human body. Maximum permissible exposure levels for both eyes and skin have been defined (55—57). One of the most common safety measures is the use of protective eyewear. Manufacturers of laser safety eyewear commonly specify the attenuation at various laser wavelengths. Under some conditions safety eyewear has been known to shatter or to be burned through (58), and it is not adequate to protect a wearer staring directly into the beam. 

A,/2 for topography characterization much smaller for periodic structure characterization (A, is the laser wavelength used to illuminate the sample)... 

Fig. 23. Experimental room temperature Raman spectrum from a sample consisting primarily of bundles or ropes of single-wall nanotubes with diameters near that of the (10,10) nanotube. The excitation laser wavelength is 514.5 nm. The inset shows the lineshape analysis of the vibrational modes near 1580 cm . SWNT refers to singlewall carbon nanotubes [195].

Fig. 25. Room temperature Raman spectra for purified single-wall carbon nanotubes excited at five different laser wavelengths, showing evidence for the resonant enhancement effect. As a consequence of the ID density of states, specific nanotubes (n, m) are resonant at each laser frequency [195].

Figure 9-31. Raman speclra in m-LPPP waveguides obtained at dillerenl laser wavelengths as depicted in the figure. The bottom spectrum shows the result of a conventional cw Raman experiment -from Ref. 1147 (.

This estimated FPY was based on the reported molar absorptivity of PuF6 at the pump laser wavelength, the pressure of PuF6 in... 

Equations (33) and (34) demonstrate that the motion quantities 5 (displacement) and v (velocity) are encoded in phase and frequency modulation of the detector output signal, purely referenced to the laser wavelength A. Tobeableto recover the time histories s(t) and v t) from the modulated detector signal, adequate phase and frequency demodulation techniques, or both, are utilized in the signal decoder blocks of a laser vibrometer. 

Figure 5 shows the dependence of the total emission intensity on the excitation intensity and its spectral width obtained from DCM-encapsulated dendrimers. A nitrogen laser (wavelength of 337 run, pulse duration of 4 ns, and repetition rate of 10 Hz) was used as the excitation source. A cylindrical lens focused the excitation beam onto a stripe 200 pm wide on a quartz cuvette... 

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