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Separator response analysis

Bode Plot a graph of the frequency response see Frequency Response Analysis) of an electrode whereby the magnitude and the phase angle are separately plotted as a function of the frequency. [Pg.1364]

The refractive index detector, in general, is a choice of last resort and is used for those applications where, for one reason or another, all other detectors are inappropriate or impractical. However, the detector has one particular area of application for which it is unique and that is in the separation and analysis of polymers. In general, for those polymers that contain more than six monomer units, the refractive index is directly proportional to the concentration of the polymer and is practically independent of the molecular weight. Thus, a quantitative analysis of a polymer mixture can be obtained by the simple normalization of the peak areas in the chromatogram, there being no need for the use of individual response factors. Some typical specifications for the refractive index detector are as follows ... [Pg.185]

Second, there are biometrical requirements. Various exposure response models may be used and compared. The models need to be clearly defined, and goodness of fit should be reported, both for the separate exposures as well as for the mixtures. Concentration addition, response addition, and mixed-model results may be compared as possible alternatives, especially when underpinning of mechanistic assumptions is weak. Results at one exposure level (e.g., EC50) do not necessarily predict results at other exposure levels due to different slopes and positions of the curves for separate compounds and the mixtures. Statistical tests should be executed properly to compare predicted and observed responses. If any statements about the significance of results are made, the methods of dose-response analysis need to be reported. [Pg.143]

Two such circuits having different relaxation time constants and connected in series lead to two semicircles as shown in Fig. 2.55(b). As in the case of any other spectroscopic analysis the separate responses may overlap and the experimental curve must then be resolved into its separate constituent semicircles. Impedance spectroscopy makes use of other electrical parameters, including the admittance (Y = Z 1), to assist in quantifying the circuit parameters. [Pg.87]

Applications of NMR in process control, although not as popular as FT-IR and NIR, provide an alternative when the latter techniques fail. The advantages of low-field (10-60 MHz) low-resolution NMR in process control applications are its noninvasive nature and the lack of need for calibration procedures with feed or product, as it is tolerant to changes in process environment and feed quality. Process/quality control NMR applications are based on separation of the FID into separate responses from components with different T2S (Fig. 6). Longer in-stream analysis times, high... [Pg.1911]

The response seen in linear-scan or cyclic voltammetry for multielectron transfers is more complex. If the E° values (see 12.3.1.2.1) are sufficiently separated, the analysis is simple. Figure 1 demonstrates how to analyze the currents for two one-electron waves. The peak current for the second wave (3 in the figure) must be calculated from the extrapolation of the first wave (dotted line 1 in the figure). This is because, as... [Pg.184]

The residual stress effect is considered by the separate analysis model and unified analysis model, and the results are shown in figures 3(a) and (b). Figure 3(a) corresponds to the elastic analysis and it is seen that the separate analysis model and unified analysis model give the same resultant stress Figure 3(b) corresponds to the eltistic-plastic analysis tmd it is seen that the resultant stresses found from the two models are different. This is because in the elastic analysis the two responses in phase I and phase II are both linear and the resultant response can be obtained from a direct superposition of the two separate ones. In the elastic-plastic analysis, however, the two separate responses are both nonlinear and the separate analysis model based on the direct superposition of the two separate responses is no longer suitable. [Pg.89]

Separate response curves are obtained at each node for each soil case calculated. A single spectrum is developed at each node for several damping values which envelop Che range of soil cases considered. This is done to simplify the analysis and qualification of systems and components which must fulfill, with a high degree of confidence, their lOCFRlOO-related radionuclide control functions under design basis conditions. Where this procedure is found to be too conseirvative, however, Che response spectra for individual soils may be used. [Pg.165]

In the permissible stress approach, the loads are specified exactly, the response analysis is carried out on the basis of elastic theory, and the structure is assessed safe, if the calculated stresses are less than the specified permissible stress. There is no separate consideration of system and parameter uncertainty or the nature of the structure, nor the consequences of failure. The loads are specified usually by other codes of practice which recommend, for example in Britain, a mixture of fair average estimates for dead loads in B. S. 648, extreme maximal estimates for imposed loads in C.P. 3 Chapter V Part 1, and statistical estimates for wind load in C.P.3 Chapter V Part 2. The uncertainty is catered for informally by the safe conservative assumptions of the designer s theoretical model and formally by an appropriate choice of loads and permissible stress values. [Pg.62]

Frequency response analysis (FRA 6.3.2) lOOpHz-lOMHz A sinusoidal voltage signal is applied and the analyzer measures the frequency dependence of the complex impedance between the electrical ports of a system under test, at a given temperature Extremely precise results for any form of polymeric materials (hquid, sohd, thin flhn, etc.) The turnkey BDS concept 10,20, or 40 systems, available from Novocontrol the first two are economical versions of BDS 40, but the sample cell has to be ordered separately... [Pg.594]

An approximate method for the response variability calculation of dynamical systems with uncertain stiffness and damping ratio can be found in Papadimitriou et al. (1995). This approach is based on complex mode analysis where the variability of each mode is analyzed separately and can efficiently treat a variety of probability distributions assumed for the system parameters. A probability density evolution method (PDEM) has also been developed for the dynamic response analysis of linear stochastic structures (Li and Chen 2004). In this method, a probability density evolution equation (PDEE) is derived according to the principle of preservation of probability. With the state equation expression, the PDEE is further reduced to a one-dimensional partial differential equation from which the instantaneous probability density function (PDF) of the response and its evolution are obtained. Finally, variability response functions have been recently proposed as an alternative to direct MCS for the accurate and efficient computation of the dynamic response of linear structural systems with rmcertain Young modulus (Papadopoulos and Kokkinos 2012). [Pg.2241]

Decoupled Analysis Most seismic analyses of landfill systems conducted in practice today employ a decoupled approach in which the response of the landfill to the seismic loading is considered separately from integrity assessments for the waste mass and containment system components. The seismic response analysis is conducted assuming that the containment system components and waste mass maintain their integrity, that there is no relative displacement at geosynthetic interfaces, and that no instabdities develop. The most common type... [Pg.2831]

At very close tip-substrate separation, an unpredicted peak was observed in the current response. Analysis of the force curve and random walk simulations of the chain conformation enabled this peak to be attributed to compression-induced conformational change of the end-grafted chains overcompressed chains elongate to escape confinement. These results illustrate the power of SECM-AFM in being able to characterize, in situ, the dynamics of end-grafted polymer chains. Moreover, as SECM-AFM allows the force and current responses associated with chain compression to be simultaneously measured, the interplay between chain conformation and dynamics and their modulation upon confinement can be explored. Additionally, as SECM-AFM is a local probe... [Pg.584]

Frequency-response analysis [1] is the most widely used technique for impedance testing. Similar to the lock-in technique, it can extract a small signal from a very high background of noise, automatically rejecting DC and harmonic responses. The difference is that a frequency-response analyzer (FRA) correlates the input signal with the reference sine waves. To achieve faster measurements, FRAs are usually equipped with separate analyzers for each input chaimel. [Pg.167]

When an analyte is too concentrated, it is easy to overload the column, thereby seriously degrading the separation. In addition, the analyte may be present at a concentration level that exceeds the detector s linear response. Dissolving the sample in a volatile solvent, such as methylene chloride, makes its analysis feasible. [Pg.568]

Oxytocin and Vasopressin Receptors. The actions of oxytocin and vasopressin are mediated through their interactions with receptors. Different receptor types as well as different second messenger responses help explain their diverse activities in spite of the hormones stmctural similarities. Thus oxytocin has at least one separate receptor and vasopressin has been shown to have two principal receptor types, and V2. Subclasses of these receptors have been demonstrated, and species differences further compHcate experimental analysis. It is apparent that both oxytocin and receptors function through the GP/1 phosphoHpase C complex (75), while the V2 receptors activate cycHc AMP (76). [Pg.191]


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See also in sourсe #XX -- [ Pg.218 ]




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