Epoxy resin Aliphatic

Aliphatic Glycidyl Ethers. Aliphatic epoxy resins have been synthesized by glycidylation of difunctional or polyfunctional polyols such as a 1,4-butanediol, 2,2-dimethyl-l,3-propanediol (neopentyl glycol), polypropylene glycols, glycerol, trimethylolpropane, and pentaerythritol. 

Multidentate V-heterocyclic ligands, thorium and, 24 767 Multidimensional gas chromatography, 4 617-618 6 433-434 Multidrug resistant bacteria, 18 252 Multi-effect distillation (ME), 26 65—67 Multi-effect vapor-compression submerged-tube desalination plant, 26 70 Multielevation piperacks, 19 515 Multifeed fractionation, 10 616 Multifilamentary superconductor, 23 846 Multifilament sutures, 24 218 threads for, 24 207 Multifilament yarns, 11 177-178 Multifile patent searches, 18 244 Multifunctional aliphatic epoxies, 10 376 Multifunctional coatings, 1 714-716 Multifunctional epoxy resins, 10 367-373, 418, 454... 

Several other epoxy resins have been made. Many contain glycidyl ether group while others are cyclic aliphatic epoxies and acrylic aliphatic epoxies. 

Dian resin, modified by aliphatic epoxy resin 100 140-150 binder Binder for reinforced plastics... 

Conclusions on p Transition Motions in Pure Aryl-aliphatic Epoxy Resins... 

Dynamic mechanical analysis and the 13C NMR experiments performed on pure aryl-aliphatic epoxy networks, as well as on antiplasticised systems, have led to a deeper insight into the molecular motions involved in the glassy state of these epoxy resins. 

It appears that the nature of the cooperativity that develops in aryl-aliphatic epoxy resin is similar to that encountered in bisphenol A polycarbonate a cooperativity directly involving the local interchain packing, which... 

Aliphatic and Cycloaliphatic Resins. Aliphatic and cycloaliphatic epoxy resins have been produced from the epoxidation of olefinic compounds. The epoxidation process involves the use of an olefinic or polyolefinic compound and a peracid (e.g., peracetic acid) or other... 

Two types of epoxy resins are formed by this process (1) cycloaliphatic resins and (2) aliphatic resins. Of the many structures that can be synthesized by this process, the cycloaliphatic diepoxies offer the most interesting combination of properties. However, the aliphatic epoxy resins have the greatest utilization in epoxy adhesive formulation. 

The aliphatic epoxy resins formed from reaction with hydrogen peroxide or peracetic acid include epoxidized polybutadiene, epoxidized soya or linseed oil, and epoxidized polyglycols. The resulting products have too low a functionality for use as base polymers. They are almost always used in combination with other epoxy resins to improve properties such as cure rate, flexibility, and heat deflection temperature. Therefore, these resins are often considered to be reactive diluents and flexibilizers. 

Glycidyl ethers of aliphatic polyols based on polyglycol, glycerin, and other polyols are flexible epoxy resins. They are used as reactive diluents and flexibihzers for solvent-free epoxy resin formulations. Epoxy-polyglycol resins that are produced from the reaction of epichlorohydrin and polyester polyols based on ethylene or propylene oxide are the most common of these types of flexible epoxy resins. Examples of typical commercial aliphatic epoxy resins are shown in App. C. 

In adhesive formulations, aliphatic amines are most commonly used to cure the DGEBA type of epoxy resin. Aliphatic amines are not widely used with the non-glycidyl ether resins, since the amine-epoxy reaction is slow at low temperatures. The reaction usually requires heat and accelerators for an acceptable rate of cure. Aliphatic amines are primarily used with lower-viscosity DGEBA resins because of the difficulty in mixing such low-viscosity curing agents with the more viscous epoxy resins. 

A research team led by O. Figovsky synthesized aliphatic multifunctional cyclic carbonates from corresponding epoxies and carbon dioxide and NIPUs based on them [17,18], The authors tested some compositions polyfunctional carbonates synthesized in the laboratory, namely trimethylolpropane tricyclocarbonate (TMPTCC) and chlorine-contained aliphatic tricyclocarbonates (on the base of chlorine-contained aliphatic epoxy resins Oxilin ) and various diamines 2-methylpentam-ethylene diamine (MPMD), Dytek A, Invista Co. meta-xylenediamine (MXDA), Mitsubishi Gas Chem. Co. polyetheramineJeffamineEDR-148, Huntsman Co. and diethylenetriamine (DETA), D.E.H. 20, Dow Chemical Co. The properties of these materials are shown in Table 4.1. 

The polyether-epoxy flexibilizers which contain epoxy groups along the chain (Scheme 57) impair better mechanical properties of the crosslinked composition in comparison with mixtures of aliphatic epoxy resins and polyether polyols. The improved properties are also obtained using 3,4-epoxycyclohexane-1-carboxylates of polyoxypropylene polyether polyols [38] (Scheme 58). 

Two types of nonglycidyl ether epoxy resins are commercially available cyclic aliphatic epoxies and acyclic aliphatic epoxies. 

Cyclic aliphatic epoxy resins were first introduced in the United States. Some typical examples of commercial materials are 3,4-epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclohexane carboxylate (Unox epoxide 201, liquid) (IX), vinylcyclobexene dioxide (Unox epoxide 206, liquid) (X), and dicyclopentadiene dioxide (Unox epoxide 207, solid) (XI). 

Acyclic aliphatic resins differ from cyclic aliphatic resins in that the basic structure of the molecules in the former is a long chain, whereas the latter, as shown, contains ring structures. Two types of acyclic aliphatic epoxies are commercially available, namely, epoxidized diene polymers and epoxidized oils. 

Aliphatic epoxy resins generally have higher color stability and reactivity than aromatic epoxy resins, but their resistance to aqueous acid solutions is much lower. 

Reactive diluents and low molecular mass aliphatic epoxy resins are of low viscosity, show a noticeable vapor pressure and have to be handled with care. These substances produce medium to strong irritation of skin and mucous membranes they are also sensitizers and can cause skin disorders. 

Second is the cyclo-aliphatic epoxy resin, in which the epoxide ring is incorporated onto one of the sides of a cyc/( -hexane ring, e.g. 

There are mainly two families of epoxies the glycidyl epoxies and non-glycidyl epoxies (also called aliphatic or cycloaliphatic epoxy resins). The absence of aromatic rings in aliphatic epoxies makes them UV resistant and suitable for outdoor applications and also reduces viscosity. The most common epoxy monomers of each family are diglycidylether of bisphenol A (known as DGEBA) and 3,4-Epoxycyclohexyl-3 4 -epoxycyclohexane carboxylate (ECC) respectively and their structures are given in Figure 2 (a, b). Cycloaliphatic resins are usually found in the form of pure chemicals with a definite... 

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