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Reactions, with ketones

C HgNjOjS. Colourless needles, with iH20. Prepared by reducing diazotized sulphanilic acid with an excess of sodium sulphite. It is a typical hydrazine in its reactions with ketones, and with acetoacetic ester. The latter reaction gives rise to the tartrazine dyestuffs, and is much used commercially. [Pg.305]

Esters of nonenolizable monocarboxylic acids such as ethyl benzoate give p diketones on reaction with ketone enolates... [Pg.892]

MeOH, LaCl3, (MeO)3CH, 25°, 10 min, 80-100% yield/ Dimethyl acetals can be prepared efficlenlly under neutral conditions by catalysis with lanthanoid halides, but the results of the reaction with ketones are unpredictable. [Pg.179]

In all cases so far investigated, including a useful direct reaction with ketones, the methoxydienyl salt is substituted at the 5-position and not at the alternative 1-position. The Fe(CO)a group can conveniently be removed from many of these adducts by the action of ferric chloride in ethanol. ... [Pg.17]

Fluoroalkyl ketone enolates and enol etliers have also been use in condensation reactions with ketones [22] Interestingly, these materials fail to undergo Dar/ens-type side reactions (equation 18)... [Pg.626]

In the case of t-butyl substituted a,/3-unsaturated ketones, however, no reaction with ketones occurred in the presence of triphenylmethyl fluoroborate instead, a 1,2-methyl shift in the unsaturated ketone accompanied by cyclization afforded a crystalline dihydro-furylium salt. ... [Pg.299]

Grignard reagents undergo a general and very useful reaction with ketones. Melhylmagnesium bromide, for example, reacts with cyclohexanone to yield a product with the formula C7HuO. What is the structure of this product if it has an IR absorption at 3400 cm-1 ... [Pg.439]

Sodium borohydride, reaction with ketones and aldehydes,... [Pg.1315]

Vilstneier reagent, reaction with ketones to form 0-chloro-a,/3- unsaturated aldehydes, 46,19... [Pg.140]

When the reactant is of the form ZCH2Z, aldehydes react much better than ketones and few successful reactions with ketones have been reported. However, it is possible to get good yields of alkene from the condensation of diethyl malonate, CH2(COOEt)2, with ketones, as well as with aldehydes, if the reaction is run with TiCU and pyridine in THF. In reactions with ZCH2Z, the catalyst is most often a secondary amine (piperidine is the most common), though many other catalysts have been used. When the catalyst is pyridine (to which piperidine may or may not be added) the reaction is known as the Doebner modification of the Knoevenagel reaction. Alkoxides are also common catalysts. [Pg.1226]


See other pages where Reactions, with ketones is mentioned: [Pg.596]    [Pg.617]    [Pg.596]    [Pg.292]    [Pg.1283]    [Pg.1286]    [Pg.1289]    [Pg.1300]    [Pg.1301]    [Pg.1303]    [Pg.1304]    [Pg.1312]    [Pg.1318]    [Pg.19]    [Pg.577]   
See also in sourсe #XX -- [ Pg.432 ]




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1.3- Dithianes reaction with ketones

2-Aminoaryl ketones, reaction with

2-Methylcyclohexanone reaction with methyl vinyl ketone

3- coumarin, reaction with ketones

74 nitrosyl chloride, reaction with ketones

Acetylenic ketones, reaction with secondary

Additions Reactions with Aldehydes and Ketones

Aldehydes reaction with ketones

Aldol Reactions with Ketone Acceptors

Aldol condensation ketone reaction with enolates

Alkenyl halides reactions with ketones

Ammonium acetate, reaction with ketones

Aromatic halides reactions with ketones

Azides reactions with ketones

Azides, alkyl reactions with ketones

Benzil aldol reaction with aliphatic ketones

Benzyl ethers reaction with ketones

Bis -1,2-ethanedithiol reaction with ketones

Bis ethylene glycol reaction with ketones

Boranes alkynyl, reactions with aldehydes and ketones

Boranes reactions with aldehydes and ketones

Boronic acid, allylesters reactions with ketones

Bromine reaction with ketones

Bromo ketones, reaction with boranes

Carboxylate salts, reaction with acyl chloride ketones

Carboxylic acids a-diazo, reaction with ketones

Carboxylic reaction with ketones

Chromyl chloride reaction with ketones

Claisen condensation ketone enolate reaction with esters

Crotyl organometallic compounds reactions with achiral ketones

Cyano-esters, reaction with ketones

Cyclopropane, 2- methylenecycloaddition reactions with unsaturated ketones

Cyclopropane, diphenylidenecycloaddition reactions with unsaturated ketones

Diazo compounds reactions with ketones

Dichlorocarbene reaction with ketones

Diels-Alder reaction, of acrolein with methyl vinyl ketone

Diels-Alder reaction, with conjugated ketones

Diels-Alder reaction, with ketones

Diels-Alder reactions with methyl vinyl ketone

Diels-Alder reactions with vinyl ketones

Diesters, reaction with ketones

Dimethyloxosulfonium methylide reaction with ketones

Electrophilic reactions with ketones

Enamines, reaction with halo ketones

Enolate anions, malonate, reaction with ketones

Enolates ketone enolate reaction with esters

Enone. conjugate addition reaction with from ketones

Esters chloro, reaction with ketones

Esters reaction with ketone enolate anions

Ethoxide, sodium, reaction with ketones

Ethyl diazoacetate reactions with ketones

Ethynyl ketones, reaction with

Experiment 16 Grignard Reaction with a Ketone Triphenylmethanol

Fluorinated ketones, reaction with enamines

Formaldehyde reaction with ketones

Gilman cuprates reactions with ketones

Glycols reaction with ketones

Grignard reagents reaction with a-alkoxy acyclic ketones

Grignard reagents reaction with ketones

Grignard reagents, reaction with enol-ketones

Halides, alkyl reaction with ketone enolate anions

Halides, alkyl reaction with ketones

Halo ketones, amination reaction, with alcohols

Halo-sulfones with ketones reaction

Hemiacetals from reaction of alcohols with aldehydes and ketones

Hexamethyldisilazide lithium reaction with ketones

Hydrazides reaction with ketones

Hydrogen reaction with ketones

Hydroxyalkyl azides reactions with ketones

Imines reactions with ketones

Iminium salts reactions with unsymmetrical methyl ketones

In reactions of ketones with

Indole reaction with methyl vinyl ketone

Indoles reaction with ketones

Indoles reaction with methyl vinyl ketone

Isatin, reactions with ketones

Isocyanates reactions with ytterbium ketone dianions

Isonitriles reaction with ketones

Ketone directed aldol reactions with aldehydes

Ketone enolates, reactions with aryne

Ketone enolates, reactions with electrophiles

Ketone reaction with LDA

Ketone reaction with LiAlH

Ketone reaction with NaBH

Ketone reaction with lithium

Ketone reactions with organometallic reagents

Ketone, /-butyl ethyl reaction with benzaldehyde

Ketones addition reaction with Grignard reagents

Ketones addition reactions with

Ketones and aldehydes, distinguishing from reaction with alcohols to form acetal

Ketones and aldehydes, distinguishing from reaction with alcohols to form hemiacetal

Ketones and aldehydes, distinguishing from reaction with amines to form imine

Ketones and aldehydes, distinguishing from reaction with secondary amines to form

Ketones bicyclic, reaction with

Ketones cyclic imines, reactions with

Ketones diazo, reaction with rhodium

Ketones direct Mannich reaction with

Ketones direct aldol reaction with

Ketones hindered, reaction with

Ketones reaction with acetylides

Ketones reaction with active methylene compounds

Ketones reaction with acyl halides

Ketones reaction with alcohols

Ketones reaction with alkenes

Ketones reaction with allenes

Ketones reaction with allylboronates

Ketones reaction with amines

Ketones reaction with ammonia

Ketones reaction with bisulfite

Ketones reaction with chloroacetonitrile

Ketones reaction with cuprates

Ketones reaction with cyanide

Ketones reaction with diazoalkanes

Ketones reaction with diazomethane

Ketones reaction with enol esters

Ketones reaction with ester enolates

Ketones reaction with esters

Ketones reaction with halogens

Ketones reaction with hydrazines

Ketones reaction with hydrazoic acid

Ketones reaction with hydrogen sulfide

Ketones reaction with hydroxylamine

Ketones reaction with metallates

Ketones reaction with organocuprates

Ketones reaction with organolithium compounds

Ketones reaction with peracids

Ketones reaction with phosphorous

Ketones reaction with sulfur tetrafluoride

Ketones reactions with THIQs

Ketones reactions with arynes

Ketones reactions with benzyl

Ketones reactions with boron-stabilized carbanions

Ketones reactions with chloromethyleneiminium salts

Ketones reactions with dienes

Ketones reactions with dithioacetals

Ketones reactions with hypochlorite

Ketones reactions with lithiated

Ketones reactions with organoaluminum reagents

Ketones reactions with organoboranes

Ketones reactions with organocadmium compounds

Ketones reactions with organocerium compounds

Ketones reactions with organocerium reagents

Ketones reactions with organocopper compounds

Ketones reactions with organometallic compounds

Ketones reactions with organometallics

Ketones reactions with organosamarium reagents

Ketones reactions with phosphazenes

Ketones reactions with samarium diiodide

Ketones reactions with silenes

Ketones reactions with trialkylaluminum

Ketones reactions with type 1 crotyl organometallics

Ketones reactions with type I crotyl organometallics

Ketones reactions with type I crotylboron compounds

Ketones reactions with type III crotyl organometallics

Ketones, 0-hydroxy reaction with allenylboronic acid

Ketones, 2- -1 -alkenyl reaction with amines

Ketones, Henry reaction aldehydes with

Ketones, Henry reaction with alcohols

Ketones, Henry reaction with amines

Ketones, P-hydroxy reaction with allenylboronic acid

Ketones, a- vinyl reaction with enolates

Ketones, a-alkoxy reactions with organocuprates

Ketones, chiral reaction with organolithium

Ketones, conjugated reaction with borane

Ketones, conjugated reaction with boranes

Ketones, conjugated reaction with hydroperoxide

Ketones, conjugated reaction with organometallics

Ketones, diisobutyl reaction with 2-pentenylzinc bromide

Ketones, enol, reaction with

Ketones, oxidative reactions with

Ketones, preparation by alkylation reaction with dimethylformamide and

Ketones, reaction with Alpine borane

Ketones, reaction with DIBAL

Ketones, reaction with NaOEt

Ketones, reaction with Oxone

Ketones, reaction with Selectride

Ketones, reaction with TosMic

Ketones, reaction with acid dianions

Ketones, reaction with alkyne anions

Ketones, reaction with allylboranes

Ketones, reaction with allylic Grignard reagents

Ketones, reaction with allyltin compounds

Ketones, reaction with aluminum alkoxides

Ketones, reaction with aluminum borohydride

Ketones, reaction with boranes

Ketones, reaction with boron enolates

Ketones, reaction with cyanoborohydride

Ketones, reaction with diazoesters

Ketones, reaction with dithiane anions

Ketones, reaction with enolate anions

Ketones, reaction with enzymes

Ketones, reaction with hexamethyldisilazide

Ketones, reaction with hydrazone carbanions

Ketones, reaction with hydroxylamines

Ketones, reaction with imine carbanions

Ketones, reaction with indole Grignard

Ketones, reaction with indole Grignard reagents

Ketones, reaction with malonate enolates

Ketones, reaction with nitro enolates

Ketones, reaction with organolithium reagents

Ketones, reaction with peroxyacids

Ketones, reaction with phosphonate ester ylids

Ketones, reaction with phosphonate ylids

Ketones, reaction with phthalimide

Ketones, reaction with silane carbanions

Ketones, reaction with silyl enol ethers

Ketones, reaction with silyl vinyl ethers

Ketones, reaction with singlet oxygens

Ketones, reaction with sodium

Ketones, reaction with succinic enolates

Ketones, reaction with sulfur ylids

Ketones, reaction with water

Ketones, reaction with ytterbium

Ketones, reaction with zinc borohydride

Ketones, reactions with alditols

Ketones, reactions with allylsilanes

Ketones, unsaturated reaction with

Lead tetraacetate reaction with ketones

LiAlH4, reaction with conjugated ketones

LiAlH4, reaction with ketones

Ligand displacement reactions with ketones

Lithium aluminium hydride reaction with unsaturated ketones

Lithium dibutylcuprate reactions with ketones

Lithium diisopropylamide reaction with ketones

Lithium diisopropylamide, formation reaction with ketones

Lithium dimethylcuprate reactions with ketones

Magnesium amalgam reaction with ketones

Magnesium, reaction with ketones

Methyl isopropyl ketone, reaction with

Methyl vinyl ketone reaction with diethyl malonate

Methyl vinyl ketone reaction with enamines

Methyl vinyl ketone, reaction with 1morpholino-l-cyclohexene

Methylamine, reaction with ketones

MoOPh reaction with ketones

Multi-component Reactions with Aldehydes and Ketones

Nitriles reactions with diaryl ketone dianions

Organolithium reagents, reaction with chiral ketones

Organolithium reagents, reaction with hindered ketones

Organometallic compounds reactions with cyclic ketones

Phenethylamine, reaction with ketones

Phenylhydrazine, reaction with ketones

Phosphorus Bromide reaction with ketones

Phosphorus pentachloride reaction with ketones

Phthalimides, reaction with ketones

Pinacol coupling reactions with ketones

Reaction of Methanol with Nitriles, Ketones, and Esters

Reaction of Organometallic Reagents with Aldehydes and Ketones

Reaction of Simple Aldehydes or Ketones with Alkynes

Reaction with aldehydes or ketones

Reaction with conjugated ketones

Reaction with diazo ketones

Reaction with fluonnated ketones

Reaction with fluoroalkyl ketones

Reaction with halo ketones

Reaction with ketones and aldehydes

Reaction with metal ketones

Reaction with methyl ketones

Reaction with methyl vinyl ketone

Reaction with tnfluoromethyl ketones

Reactions of Aldehydes and Ketones with Nitrogen Nucleophiles

Reactions of Amines with Ketones and Aldehydes (Review)

Reactions of Organozinc Reagents with a,p-Unsaturated Ketones

Reactions of enolates with aldehydes and ketones the aldol reaction

Reactions of monosaccharides with beta-ketonic

Reactions with Ketone Reagents

Reactions with a,p-Unsaturated Ketones

Reactions with a-bromo ketones

Reactions with carbonyl compounds ketones

Schmidt reaction with unsymmetrical ketones

Schmidt reactions hydroxyalkyl azides with ketones

Selenoxides reaction with ketones

Semicarbazide, reaction with aldehydes ketones

Silane carbanions, reaction with aldehydes ketones

Silane, propargylacylation reaction with ketones

Silane, vinylepoxidation reaction with ketones

Silanones reactions with ketones

Silyl enol ether reaction with unsaturated ketone

Sodium azide, reaction with azido-ketones

Sodium azide, reaction with ketones

Sodium borohydride, reaction with ketones

Sodium borohydride, reaction with ketones and aldehydes

Stannanes reactions with ketones

Styrene, a-methyl cycloaddition reactions with tetramethyldibromo ketones

Subject reactions with ketones

Sulfone, methoxymethyl phenyl reaction with cyclic ketones

Sulphurous Acid, Reaction Ketones with

Tetramethylpiperidide lithium, reaction with ketones

Tetraphenylcyclopentadienone, from dibenzyl ketone and benzil reaction with benzyne to form 1,2,3,4tetraphenylnaphthalene

Tetraphenylcyclopentadienone, from dibenzyl ketone and benzil reaction with diphenylacetylene

The Reaction of Trialkylboranes with Methyl Vinyl Ketone and Acrolein

The Reactions of Aldehydes and Ketones with Alcohols

The Reactions of Aldehydes and Ketones with Amines

The Reactions of Aldehydes and Ketones with Cyanide Ion

The Reactions of Aldehydes and Ketones with Water

The Reactions of Aldehydes and Ketones with a Peroxyacid

Thiol acids reaction with halo ketones

Thiols reaction with ketones

Tin, sulfidobis reaction with a-mercurated ketones

Tin, sulfidobis reaction with a-mercurated ketones preparation of enol stannyl ethers

Titanium, tris methylproperties reaction with alkoxy ketones

Trifluoroethyl vinyl ketone reaction with

Trimethylaluminum reaction with ketones

Typical Reaction with Acid Chlorides to Form Ketones

Vilsmeier reagent, reaction with ketones

Vilsmeier reagent, reaction with ketones aldehydes

Vinyl ketones reactions with enamines

Yamamoto’s reagent reactions with ketones

Ylide reactions, nonstabilized with ketones

Zinc, bis hydride donor reaction with phenyl isopropyl ketone

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