Ketones, 3-hydroxy reaction with allenylboronic acid

Ikeda, N., Omori, K., Yamamoto, H. Complete 1,3-asymmetric induction in the reactions of allenylboronic acid with 3-hydroxy ketones. Tetrahedron Lett. 1986, 27, 1175-1178. 

Reaction of allenylboronic acid with 3-hydroxy ketones in anhydrous ether at room temperature in the presence of SA molecular sieves for 20 h, followed by treatment with basic hydrogen peroxide, yields 1,3-diols with high 1,3-asymmetric induction (>99%) (equation 9). ... 

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See also in sourсe #XX -- [ ]

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