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Ketones reactions with hydroxyalkyl azides

Rearrangements. Cyclic ketones undergo ring expansion on reaction with hydroxyalkyl azides." Regioselectivity is dependent on steric and electronic factors. Beckmann rearrangement of ketoxime carbonates has been observed at room temperature. [Pg.67]

Variation 4 Asymmetric Schmidt Reaction of Ketones with Hydroxyalkyl Azides (Aube )... [Pg.358]

Schmidt Rearrangement Reactions with Alkyl Azides 201 Table 7.3 Reactions of hydroxyalkyl azides with ketones... [Pg.201]

Rudy H, Cramer KE (1939) Uber den oxydativen Abbau des alloxan-2-dimethylatino anils zu 1-methyl benzimidazol. Chem Ber A 72(4) 728-744 Sahasrabudhe K, Gracias V, Furness K, Smith BT, Katz CE, Reddy DS, Aube J (2003) Asymmetric Schmidt reaction of hydroxyalkyl azides with ketones. J Am Chem Soc 125 (26) 7914-7922. doi 10.1021/ja0348896... [Pg.268]

See other pages where Ketones reactions with hydroxyalkyl azides is mentioned: [Pg.358]    [Pg.386]    [Pg.670]    [Pg.138]    [Pg.200]    [Pg.232]    [Pg.1084]    [Pg.1084]   
See also in sourсe #XX -- [ Pg.201 ]



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Azidation reaction

Azides reactions with ketones

Azides, reactions

Hydroxyalkyl

Hydroxyalkyl azides

Hydroxyalkyl azides with ketones

Hydroxyalkylation

Hydroxyalkylations

Ketones azidation

Reaction with azide

Reaction with ketone

Reactions hydroxyalkylation

Schmidt reactions hydroxyalkyl azides with ketones

With Azides

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