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The Reactions of Aldehydes and Ketones with a Peroxyacid

If the two alkyl substituents attached to the carbonyl group of the ketone are different, then on what side of the carbonyl carbon is the oxygen inserted For example, does the oxidation of cyclohexyl methyl ketone form methyl cyclohexanecarboxylate or cyclohexyl acetate  [Pg.826]

To answer this question, we need to look at the mechanism of the reaction. [Pg.826]

Studies of the migration tendencies of different groups have established the following order relative migration tendencies [Pg.826]


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A of aldehydes and ketones

A reaction of, with

A reaction with aldehydes

Aldehydes and ketones, reactions

Aldehydes reaction with ketones

Aldehydes with ketones

Aldehydes with peroxyacids

Ketones with peroxyacids

Ketones, reaction with peroxyacids

Of aldehydes and ketones

Peroxyacid

Peroxyacids

Peroxyacids aldehyde reactions with

Reaction of aldehydes

Reaction of aldehydes with

Reaction with ketone

Reaction with ketones and aldehydes

Reaction with peroxyacids

Reactions of ketones

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