Range, adhesive

Upon approach, organisms will be attracted or repelled by the biomaterial surface, depending on the resultant of the various interaction forces. Thus, the physico-chemical surface properties of the biomaterial, with or without conditioning film, and those of the microorganisms play a decisive role in this process. Because the size of microorganisms is in the im range, adhesion can be described in terms of colloid science. Indeed, for several strains and species physico-chemical models like the Deijaguin-... 

Figure Bl.20.6. Short-range adhesion of a mica-mica contact as a function of the relative crystallographic orientation of the mica surfaces, measured in a dry nitrogen atmosphere. With permission from [94].

Generally, silicone sealants possess the best combination of physical strength, cure rate, performance over a wide temperature range, adhesion, sealability and weatherability of any available material. 

Of course, it had been known for several centuries that short-range adhesion forces between molecules should act when elastic bodies make intimate contact. Newton had written in his book Opticks pnbUshed in 1704 that Tarticles attract one another by some... 

In conclusion, the polysulfide sealants have unique properties that can be put to very demanding uses. These are excellent resistance to various physical and chemical agents, excellent flexibility over a wide temperature range, adhesion, and long-term performance. 

There are polymeric adhesives that perform well at temperatures between -60 and 350°F. But only a few adhesives can withstand operating temperatures outside that range. Adhesives can also be degraded by chemical environments and outdoor weathering. The rate of strength degradation may be accelerated by continuous stress or elevated temperatures. 

A number of friction studies have been carried out on organic polymers in recent years. Coefficients of friction are for the most part in the normal range, with values about as expected from Eq. XII-5. The detailed results show some serious complications, however. First, n is very dependent on load, as illustrated in Fig. XlI-5, for a copolymer of hexafluoroethylene and hexafluoropropylene [31], and evidently the area of contact is determined more by elastic than by plastic deformation. The difference between static and kinetic coefficients of friction was attributed to transfer of an oriented film of polymer to the steel rider during sliding and to low adhesion between this film and the polymer surface. Tetrafluoroethylene (Telfon) has a low coefficient of friction, around 0.1, and in a detailed study, this lower coefficient and other differences were attributed to the rather smooth molecular profile of the Teflon molecule [32]. 

More recently, alternative chemistries have been employed to coat oxide surfaces with SAMs. These have included carboxylic 1129, 1301, hydroxamic 11311, phosphonic 1124, 1321 and phosphoric acids 11331. Potential applications of SAMs on oxide surfaces range from protective coatings and adhesive layers to biosensors. 

Both melamine—formaldehyde (MF) and resorcinol—formaldehyde (RF) foUowed the eadier developments of phenol—, and urea—formaldehyde. Melamine has a more complex stmcture than urea and is also more expensive. Melamine-base resins requite heat to cure, produce colorless gluelines, and are much more water-resistant than urea resins but stiU are not quite waterproof. Because of melamine s similarity to urea, it is often used in fairly small amounts with urea to produce melamine—urea—formaldehyde (MUF) resins. Thus, the improved characteristics of melamine can be combined with the economy of urea to provide an improved adhesive at a moderate increase in cost. The improvement is roughly proportional to the amount of melamine used the range of addition may be from 5 to 35%, with 5—10% most common. 

The manufacture of MDF, with a few exceptions, dupHcates the manufacture methods for dry-process hardboard, described at length hereia. One exception to it is that most MDF is made ia the medium-density range, 640—800 kg/m although small amounts are made at lower or higher densities. Second, the vast majority of MDF is made with UF resia adhesives with resia requhemeats ia the 7—11% range, and wax is usually added at the 0.50—0.75% level. A small amount of exterior-grade MDF is made with isocyanate resia. 

Because of the high costs of raw materials and the relatively complex synthesis, the 2-cyanoacryhc esters are moderately expensive materials when considered in bulk quantities. Depending on the quantity and the specific ester or formulation involved, the prices for cyanoacryhc ester adhesives can range from approximately 30/kg to over 1000/kg. For these reasons, as weU as several technical factors related to handling and performance, cyanoacryhc ester adhesives are best suited to small bonding apphcations, very often where single drops or small beads are adequate for bonding. In such cases the cost of the adhesive becomes inconsequential compared to the value of the service it performs, and these adhesives become very economical to use. 

Table 1 provides the approximate load bearing capabiUties of various adhesive types. Because the load-bearing capabiUties of an adhesive are dependent upon the adherend material, the loading rate, temperature, and design of the adhesive joint, wide ranges of performance are Hsted. 

Epoxy stmctural adhesives are used in an extraordinarily wide range of appHcations. They are available in essentially all of the forms discussed above, except for primer—Hquid combinations or as room temperature curing Hquids. The highest technology appHcation for epoxies is in aerospace stmctural... 

Phenohc resins are the oldest form of synthetic stmctural adhesives. Usage ranges from bonding automobile and other types of brake linings to aerospace apphcations. These adhesives have a reputation for providing the most durable stmctural bonds to aluminum. Because of volatiles, however, and the need for high pressures, the phenohc resins are used less as adhesives than the epoxy resins. 

Formulations. Hot-melt adhesive formulation involves providing the best physical properties over as large a temperature range as possible. 

This type of adhesive is generally useful in the temperature range where the material is either leathery or mbbery, ie, between the glass-transition temperature and the melt temperature. Hot-melt adhesives are based on thermoplastic polymers that may be compounded or uncompounded ethylene—vinyl acetate copolymers, paraffin waxes, polypropylene, phenoxy resins, styrene—butadiene copolymers, ethylene—ethyl acrylate copolymers, and low, and low density polypropylene are used in the compounded state polyesters, polyamides, and polyurethanes are used in the mosdy uncompounded state. 

In the area of moleculady designed hot-melt adhesives, the most widely used resins are the polyamides (qv), formed upon reaction of a diamine and a dimer acid. Dimer acids (qv) are obtained from the Diels-Alder reaction of unsaturated fatty acids. Linoleic acid is an example. Judicious selection of diamine and diacid leads to a wide range of adhesive properties. Typical shear characteristics are in the range of thousands of kilopascals and are dependent upon temperature. Although hot-melt adhesives normally become quite brittle below the glass-transition temperature, these materials can often attain physical properties that approach those of a stmctural adhesive. These properties severely degrade as the material becomes Hquid above the melt temperature. 

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