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Processing aids, analysis

Eault tree analysis (ETA) is a widely used computer-aided tool for plant and process safety analysis (69). One of the primary strengths of the method is the systematic, logical development of the many contributing factors that might result ia an accident. This type of analysis requires that the analyst have a complete understanding of the system and plant operations and the various equipment failure modes. [Pg.83]

Apart from routine quality control actions, additive analysis is often called upon in relation to testing additive effectiveness as well as in connection with food packaging and medical plastics, where the identities and levels of potentially toxic substances must be accurately known and controlled. Food contact plastics are regulated by maximum concentrations allowable in the plastic, which applies to residual monomers and processing aids as well as additives [64-66]. Analytical measurements provide not only a method of quality control but also a means of establishing the loss of stabilisers as a function of material processing and product ageing. [Pg.14]

A PET oligomer isolation method has utilised chloroform extraction in a Parr bomb lined with a Teflon-TFE fluoro-carbon resin [40]. The analytics of fluoropolymer processing aids (combustion analysis, XRF, EUR, 19F NMR, OM) have recently been described [29]. Combustion analysis (Parr Oxygen Bomb Calorimeter) can be used for quantitative analysis... [Pg.597]

Table 8.47 shows the available options for the analysis of polymer processing aids, namely combustion and instrumental methods. The best method is dependent on PPA type, the level to be measured, and the available equipment (see also Section 8.2.1.2). Fluoropolymer processing aid concentrations can be determined by WDXRF configured to measure either fluorine or a tracer, and by EDXRF to analyse a tracer [29]. Calibration curves are required. At present, EDXRF or benchtop XRF units cannot directly measure fluorine. For resin or masterbatch producers who prefer to make on-line XRF measurements of processing aid concentrations (to letdown levels of 50-100 ppm), processing aids that contain a tracer (usually BaS04) are available. The analysis time is less than two minutes. [Pg.636]

PA-FTIR, IR, TLC, NMR, potentiometry and chemiluminescence [486], Analysis of fluoropolymer-based processing aids with a specific ion (F-) analyser can be carried out within 15 min per sample [29]. [Pg.669]

D. Hummel and F. Scholl, Atlas of Polymer and Plastics Analysis, Vol. 3, Additives and Processing Aids, Carl Hanser Verlag, Munich, Germany, 1981. [Pg.605]

Forming additives/processing aids, ceramics processing, 5 646-648 Forming-die alloys, zinc, 26 594 Forming limit analysis, copper wrought alloys, 7 736-737 Formonitrile, 3 171 Formulation aid, 12 32 Formylation, 12 177-178... [Pg.378]

Process aids, for filled networks, 22 571 Process analysis, Raman scattering in, 22 328... [Pg.761]

Infrared Analysis of Polymer, Resins and Additives an Atlas, Volume 1, Eds., D.O. Hummel and F.K. Scholl, Plastics, Elastomers, Fibers and Resins, Part 1 Text, Part 2 Spectra Tables, Index, Wiley Interscience, New York, 1969. Volume 2, Additives and Processing Aids 1973. [Pg.158]

The Food Standards Code [10] is the main regulatory instrument which controls the quality of food, contaminant levels, approved additives, processing aids, sanitisers and disinfectants and these standards are performance based. If a chemical or a group of chemicals is covered by a food standard then they must only be used in food in accordance with the standard. However, if a chemical is not mentioned in a standard, then this does not preclude its use in food. For a new chemical not previously used in food production, it would be necessary for the supplier to undertake a detailed risk analysis of the product to demonstrate its safety and suitability. The assessment would need to consider both the toxicological profile of the chemical and the levels of human exposure that are likely to arise from residues in food. [Pg.276]

Measurable residual amounts or conversion products from the many different raw materials and processing aids used in the various plastic synthesis processes can remain in the finished material. Knowledge of these materials is indispensable for the toxicological evaluation of the plastics and their analysis. The same applies for the many chemically different additives which are incorporated into the plastic matrix to allow better processing, increase stability and to give the material specific properties. [Pg.11]

Batch, G. L., and Macosko, C. W., Computer Aided Analysis of Pultrusion Processing. AIChE Conference on Materials in Emerging Technologies, Minneapolis, August 1987. [Pg.345]

Cadman, T. W., CAAPS User s Guide (Computer Aided Analysis for Process Systems), Enscii,... [Pg.204]

Aid in selling process safety management to senior managers. OSHA process safety standard arid gathering process safety information for process hazard analysis. [Pg.183]

Up-to-date compendiums on applications of infrared spectroscopy in applied polymer science are as follows. "An Infrared Spectroscopy Atlas for the Coatings Industry" (95) describes techniques, has liberal references to specific methods, and contains high-quality grating reference spectra on paint components and blended compositions. "Atlas of Polymer and Plastics Analysis," 2nd ed., by Hummel and Scholl (96), has issued two volumes Vol. 1, Polymers Vol. 3, on Additives and Processing Aids Vol. 2, on Plastics, Fibers, Rubbers, Resins, is in press. "Infrared Spectra of Plasticizers and Other Additives," 2nd ed., published by The Coblentz Society, Inc., is a high-quality IR reference spectrum collection (97). [Pg.712]

Hummel, D. 0. Scholl, F. "Atlas of Polymer Plastics Analysis," 2nd ed. Carl Hanswer Verlag Munich, Verlag Chemie International New York, Vol. 1, "Polymers," 1978 Vol. 2, "Plastics, Fibers, Rubbers, Resins," 1984 Vol. 3, "Additives and Processing Aids," 1981,... [Pg.735]

One of the important trends in chemical analytical instrumentation during the past decade has been the use of digital computers as data processing aids. Raw experimental data from an instrument is manipulated, displayed, and printed by use of a microcomputer or minicomputer. This trend has become very apparent in thermal analysis instrumentation. A small dedicated microcomputer is used to set the instrument s operating parameters as well as to process and display the experimental data. Unfortunately, the T A instruments such as thermobalances, DTA, DSC, and TMA units are of designs that are at least 20 years or more old. New instrument designs have not been developed but, rather, the emphasis has been on computerization. [Pg.765]


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