Polyester plastic aromatic

Plasticized PVC with an aliphatic polyester-b-aromatic polyester Miscible blend PVC/PC and a bishydroxyphenyl-hexafluoropropane (6F-PC)... 

AROMATIC o-XYLENE C6H4(CH3>2 PHTHALIC ANHYDRIDE C6H4(C203> POLYESTERS, PLASTICIZERS, FINE CHEMICALS 1.7... 

A process akin to the allylic oxidation in activation is aromatic side chain oxidation to produce acids or anhydrides. Phthalic anhydride, an important intermediate in production of polyesters, plasticizers, and fine chemicals synthesis, can be produced via selective oxidation of -xylenes using vanadium oxide catalysts (Eqn. 3). This process today accounts for over 85% of the phthalic anhydride produced worldwide, and has largely displaced the partially wasteful and more expensive naphthalene-based route (Eqn. 4), by which nearly all PA was produced in 1960 (Figure 4). Nearly all of the phthalic anhydride produced today is used for manufacturing vinyl plasticizers, with a much smaller application in the fine chemicals industry. 

Xydar Amoco Performance Products Inc. s tradename for its family of liquid-crystal polymers, xylene A colorless aromatic hydrocarbon liquid. It is used as a solvent, in the manufacture of polyester plastics, and as a chemical intermediate. 

With the attempt to combine good material properties of aromatic polyesters and biodegradability of aliphatic polyesters, aliphatic aromatic copolyesters have been developed during the last years to be used as technical biodegradable plastics The BASF AG / Germany is now producing a biodegradable material based on a copolyester of 1,4-butanediol, adipic acid and terephthalic acid (BTA-copolyester) tmder the trade name Ecoflex in a several thousand tons per year scale. 

Low cost Light-colored or nonstaining stocks (including black stock) Low temperature service Heat resistance Petroleum oils, naphthenic and aromatic Ester plasticizers, chlorinated paraflins, or selected petroleum oils Ester plasticizers or cis-polybutadiene Poljrmeric plasticizers, chlorinated paraflins, polyester plasticizers, and low volatility petroleum oils Chlorinated paraflins and organic phosphate esters A polyether-[di(butoxy-ethoxy ethyl) formal] Ester, chlorinated paraflins, or poljmieric plasticizers... 

If monomers which form amide bonds or imide rings are involved in synthesis of aromatic polyesters, thermotropic copolyamide esters or copolyimide est are obtained. p-Aminobenzoic acid increases the strength and modulus of elasticity of a polyester plastic based on p-hydroxybenzoic acid [71]. 

Benzene, toluene, and xylene are made mosdy from catalytic reforming of naphthas with units similar to those already discussed. As a gross mixture, these aromatics are the backbone of gasoline blending for high octane numbers. However, there are many chemicals derived from these same aromatics thus many aromatic petrochemicals have their beginning by selective extraction from naphtha or gas—oil reformate. Benzene and cyclohexane are responsible for products such as nylon and polyester fibers, polystyrene, epoxy resins (qv), phenolic resins (qv), and polyurethanes (see Fibers Styrene plastics Urethane POLYiffiRs). 

Xylenes. The main appHcation of xylene isomers, primarily p- and 0-xylenes, is in the manufacture of plasticizers and polyester fibers and resins. Demands for xylene isomers and other aromatics such as benzene have steadily been increasing over the last two decades. The major source of xylenes is the catalytic reforming of naphtha and the pyrolysis of naphtha and gas oils. A significant amount of toluene and Cg aromatics, which have lower petrochemical value, is also produced by these processes. More valuable p- or 0-xylene isomers can be manufactured from these low value aromatics in a process complex consisting of transalkylation, eg, the Tatoray process and Mobil s toluene disproportionation (M lDP) and selective toluene disproportionation (MSTDP) processes isomerization, eg, the UOP Isomar process (88) and Mobil s high temperature isomerization (MHTI), low pressure isomerization (MLPI), and vapor-phase isomerization (MVPI) processes (89) and xylene isomer separation, eg, the UOP Parex process (90). 

Styrene [100-42-5] (phenylethene, viaylben2ene, phenylethylene, styrol, cinnamene), CgH5CH=CH2, is the simplest and by far the most important member of a series of aromatic monomers. Also known commercially as styrene monomer (SM), styrene is produced in large quantities for polymerization. It is a versatile monomer extensively used for the manufacture of plastics, including crystalline polystyrene, mbber-modifted impact polystyrene, expandable polystyrene, acrylonitrile—butadiene—styrene copolymer (ABS), styrene—acrylonitrile resins (SAN), styrene—butadiene latex, styrene—butadiene mbber (qv) (SBR), and unsaturated polyester resins (see Acrylonithile polya rs Styrene plastics). 

Aroma.tic-AUpha.tic Polyester Resins. Unlike most other classes of engineering plastics, which are made by only a few manufacturers, aromatic-aHphatic polyester resins are produced and compounded by several dozen firms (66). The aHphatic polyester resin marketplace is characterized by wide product differentiation and competition. Some firms make only a few hundred tons per year and presumably retain profitabiHty because of the avadabiHty of low cost monomer and the simplicity of the processes employed. Low investment and low manufacturing costs are possible even for smaH-volume operations. 

As the author pointed out in the first edition of this book, the likelihood of discovering new important general purpose materials was remote but special purpose materials could be expected to continue to be introduced. To date this prediction has proved correct and the 1960s saw the introduction of the polysulphones, the PPO-type materials, aromatic polyesters and polyamides, the ionomers and so on. In the 1970s the new plastics were even more specialised in their uses. On the other hand in the related fields of rubbers and fibres important new materials appeared, such as the aramid fibres and the various thermoplastic rubbers. Indeed the division between rubbers and plastics became more difficult to draw, with rubbery materials being handled on standard thermoplastics-processing equipment. 

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