Poly phosphated alcohols

Poly(vinyl nitrate) has been prepared and studied for use in explosives and rocket fuel (104,105). Poly(vinyl alcohol) and sulfur trioxide react to produce poly(vinyl sulfate) (106—111). Poly(vinyl alkane sulfonate)s have been prepared from poly(vinyl alcohol) and alkanesulfonyl chlorides (112—114). In the presence of urea, poly(vinyl alcohol) and phosphoms pentoxide (115) or phosphoric acid (116,117) yield poly(vinyl phosphate)s. 

Polymeric Calcium Phosphate Cements. Aqueous solutions of polymers such as poly(acryHc acid), poly(vinyl alcohol), gelatin, etc, and/or autopolymerizable monomer systems, eg, 2-hydroxyethyl methacrylate, glycerol dimethacrylate, calcium dimethacrylate, etc, have been used as Hquid vehicles (41,42,76) for the self-setting calcium phosphate cement derived from tetracalcium phosphate and dicalcium phosphate [7757-93-9J. 

Cheng et al. [116] reported that the structure of primaquine phosphate irradiated with 0.7—10 Mrad remained unchanged. The energy transfer action of the quinolyl group was considerable due to its resonance stabilization. Radiation-induced degradation of polyl(vinyl alcohol) decreased in the presence of primaquine phosphate but the degradation mechanism was unaffected. The content of primaquine phosphate showed linear relationship with degradation parameters of poly(vinyl alcohol). 

Common suspending agents are poly(vinyl alcohols) of various molecular weights and degrees of hydrolysis, starches, gelatin, calcium phosphate (especially freshly precipitated calcium phosphate dispersed in water to be used in the preparation), salts of poly(acrylic acid), gum arabic, gum tragacanth, etc. 

Titanates have been instrumental in the bonding of fluorinated resins to packaging films, poly(hydantoin)—polyester to polyester wire enamel, polysulfide sealant to polyurethane (a phosphated titanate is recommended), polyethylene to cellophane using a titanated polyethylenimine, and silicone mbber sealant to metal or plastic support using polysilane (Si—H) plus polysiloxane (Si—OR) and titanate as the adhesive ingredients (450—454). Polyester film coated first with a titanium alkoxide, then with a poly(vinyl alcohol)—polyethylenimine blend, becomes impermeable to gases (455). 

FIG. 2 Bovine serum albumin adsorption to different polymer surfaces at 37°C in phosphate-buffered solution. The initial albumin concentration is 3 mg/ml. PVA poly(vinyl alcohol), PMMA poly(methyl methacrylate), PET polyethylene therephthalate), PP polypropylene, HDPE high-density polyethylene, PTFE polytetrafluoroethylene. (From Ref. 1.)... 

Poly(vinyl alcohol). Deposition is achieved by flushing the capillary with a 10% aqueous solution of 50 kDa PVA (99% or more hydrolyzed), pushing the coating solution out of the column with a stream of nitrogen, and then heating the capillary at 140°C under a stream of nitrogen. This produces capillaries with an efficiency of greater than a million plates, essentially no EOF, stability up to pH 10, and the ability to separate basic or acidic proteins (see Fig. 321). A 50 m M sodium phosphate buffer at pH 3.0 is used, and CE is carried out at 30 kV at 20°C. 

Poly(vinyl alcohols) bonded with nucleic acid bases through phosphate linkages were prepared. Contents of uracil, thymine and hypoxanthine in the polymers were about 50 to 60 mol-%, and that of adenine was about 10%. Interactions of these polymers with DNA in aqueous solution were studied. The apparent hypochromidty was 6.5% for adenine substituted poly(vinyl alcohol) - DNA and 3% for the corresponding uracil substituted derivative83. ... 

Typical suspension stabilizers for the production of EPS are water-soluble, surface-active macromolecules, such as poly (vinyl alcohol) (PVA), hydroxyethyl-cellulose (HEC) and polyvinylpyrrolidone (PVP), or natural products, such as gelatin [36-40], and insoluble inorganic powders, such as tricalcium phosphate (TCP), also called picketing stabilizer , mostly in combination with surfactants called extenders [33-35,44], or a combination of these [129]. The differences and specialties of these stabilizing mechanism are described briefly below ... 

Starch phosphate was combined with rosin and alum to increase the dry strength and ink retention characteristics of paper.1677 Starch phosphates have also been used as soil conditioners to increase water retention.1678 Starch phosphates improved the dispersion and dye reception of synthetic fibers,1667 and are used to stabilize water,1543 finger paints,1679 and white coating colors.1680 Phosphonoamidated starches are useful in paper sizing.1681 Biodegradable films were produced by combining starch phosphate with poly (vinyl alcohol).1682 Phosphonoacetyl starch added to polyacrylonitrile improved it affinity for dyes.1683... 

Displacement by plasma of radiolabeled thrombin and radio-labeled thrombin-antithrombin III inactive complex from a heparinized surface was measured and found to be significant for example, removing 63% of the thrombin and 90% of the complex that could not be removed by phosphate-buffered saline alone. Heparin-poly(vinyl alcohol) (PVA) gel beads with a very low heparin release rate, prepared by acetal coupling of the heparin to the PVA, adsorbed thrombin and potentiated the inactivation of thrombin by antithrombin 111, as measured by both thrombin time and chromogenic substrate assays. 

Poly(vinyl alcohol) can be wholly or partially converted to poly(vinyl phosphate) by the action of POCI3 followed by hydrolysis (12.82). Heating of the polyacid product leads to a cross-linked polymer which resists hydrolysis by dilute acids and bases. The monoammonium salt is obtained by the action of phosphoric acid and urea on polyvinyl alcohol (12.83). 

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