Petroleum adsorbers

The more important groups of petroleum adsorbents are (1) fuller s earth, (2) bentonite, (3) various natural and treated clays, (4) bog iron ore, (5) bauxite and alumina, and (6) activated carbon. These are often... 

Another procedure, which is sometimes adopted, consists in adding a susi)eiisioii of the adsorbent in petroleum ether (b.p. ca. 60-80°) in small... 

The developer is generally a solvent in which the components of the mixture are not too soluble and is usually a solvent of low molecular weight. The adsorbent is selected so that the solvent is adsorbed somewhat but not too strongly if the solvent is adsorbed to some extent, it helps to ensure that the components of the mixture to be adsorbed will not be too firmly bound. Usually an adsorbate adheres to any one adsorbent more firmly in a less polar solvent, consequently when, as frequently occurs, a single dense adsorption zone is obtained with light petroleum and develops only slowly when washed with this solvent, the development may be accelerated by passing to a more polar solvent. Numerous adsorbat are broken up by methyl alcohol, ethyl alcohol or acetone. It is not generally necessary to employ the pure alcohol the addition from 0 5 to 2 per cent, to the solvent actually used suffices in most cases. 

The value of a graded series of eluents is that if one member of the series succeeds in desorbing a portion of an adsorbate, then another more power ful eluent should remove a further portion of the adsorbate. By mixing the eluents in various proportions, a finer gradation may be obtained, e.g., petroleum ether benzene and petroleum ether benzene and ether ether and acetone, etc. 

Pour-Point Depressants. The pour point of alow viscosity paraffinic oil may be lowered by as much as 30—40°C by adding 1.0% or less of polymethacrylates, polymers formed by Eriedel-Crafts condensation of wax with alkylnaphthalene or phenols, or styrene esters (22). As wax crystallizes out of solution from the Hquid oil as it cools below its normal pour point, the additive molecules appear to adsorb on crystal faces so as to prevent growth of an interlocking wax network which would otherwise immobilize the oil. Pour-point depressants become less effective with nonparaffinic and higher viscosity petroleum oils where high viscosity plays a dominant role in immobilizing the oil in a pour-point test. 

ZeoHte-based materials are extremely versatile uses include detergent manufacture, ion-exchange resins (ie, water softeners), catalytic appHcations in the petroleum industry, separation processes (ie, molecular sieves), and as an adsorbent for water, carbon dioxide, mercaptans, and hydrogen sulfide. 

Aromatic hydrocarbons can be purified as their picrates using the procedures described for amines. Instead of picric acid, 1,3,5-trinitrobenzene or 2,4,7-trinitrofluorenone can also be used. In all these cases, following recrystallisation, the hydrocarbon can be isolated either as described for amines or by passing a solution of the adduct through an activated alumina column and eluting with toluene or petroleum ether. The picric acid and nitro compounds are more strongly adsorbed on the column. 

Remick, R.J., Tiller, A.J., Advanced Methods for Low Pressure Storage of CNG, Non-petroleum Vehicular Fuels Conference, Washington, April 1985 Otto, K., Alternative Energy Sources IV, Vol 6 p241, Ann Arbor Science, MI Barton, S.S., Holland, J.A. Quinn, D.F., "The Development of Adsorbent Carbon for Storage of Compressed Natural Gas, Report AF-85-01, Ontario Ministry of Transportation, 1985 1201 Wilson Ave, Downsview, Ontario, Canada M3M 1J8... 

Petroleum Locate and eliminate seepage. Activated carbon will adsorb oil and gasoline (most hydrocarbons) on a short term basis. Airstrip with (40 1 air/water ratio) followed by 2 ft carbon units in series... 

A solution of 0.3 g of the foregoing crude acid dissolved in 7 ml of t-butanol and 0.4 ml of concentrated hydrochloric acid is refluxed for 20 min. The cooled reaction mixture is diluted with benzene, washed with saturated sodium bicarbonate solution, and with water, dried and evaporated under reduced pressure. The neutral residue (0.21 g) dissolved in benzene is adsorbed on a column of 2.5 g of neutral alumina. Elution with ether-petroleum ether gives 0.18 g of 19-norprogesterone mp 141-142°, after two crystallizations. 

The submitters mixed active anhydrous silica gel with water (12% v>/w) and stored it in a sealed container for at least 24 hours prior to use. A ratio of 60-80 g. of silica gel per gram of crude product was used for column chromatographic separations, and a column was chosen that would give a 10 1 height diameter ratio of adsorbent. Columns were wet-packed with distilled petroleum ether (b.p. 60-68c), and after the crude product had been applied a step-gradient was run rapidly through 2% vjv ether in petroleum ether, 5% ether, and 10% ether. The column was then eluted with 20% vjv ether in petroleum ether until the bromohydrin acetate was obtained. 

There exist a number of other methods for the separation of diamondoids from petroleum fluids or natural gas streams (1) a gradient thermal diffusion process [54] is proposed for separation of diamondoids (2) a number of extraction and absorption methods [53,83] have been recommended for removing diamondoid compounds from natural gas streams and (3) separation of certain diamondoids from petroleum fluids has been achieved using zeolites [56, 84] and a number of other solid adsorbents. 

The most common methods for trapping pesticide vapors from air use adsorbents. Common air sampling adsorbents include charcoal (derived from petroleum or coconut) and synthetic polymeric materials, such as cross-linked polystyrene and open-cell polyurethane foam. Charcoal has been used for the cumulative sampling of volatile... 

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