Pacific Solution

Australia s Pacific Solution Awash with Inhumanity... 

If the final product desired is teUurium metal, excess free caustic soda is required in the sodium teUurite solution. The solution is electrolyzed in a ceU using stainless steel anodes to produce teUurium metal (20). This technology is used at the CCR Division of Noranda MetaUurgy Inc., Canada, and at Pacific Rate Metals Industties Inc., the Philippines. Typical electrolysis conditions ate given in Table 2. 

Nickel. Worldwide, nickel used in electroplating has averaged about 63,500 t annually from 1980—1990 (9). The United States uses about 18,000 t/yr, and Europe about the same quantity Japan consumes about 9,000 t, and another 9,000 t is used by the other Pacific rim countries. Canada and South America are reported to use about 4500 t aimuaHy. Electroforming apphcations consume another 4500 t of nickel worldwide. About half of this electroforming is done in the United States and Canada. Nickel deposited from autocatalytic solutions was estimated to account for 1600 t of nickel on a worldwide basis (10) in 1990. Nickel averaged 3.65/kg ia early 1993 (see Nickel and nickel alloys). 

Hydrothermal vents have been sampled at 21 along the East Pacific Rise. The pure end member hydrothermal solutions have a temperature of 350°C and the following major ion composition (von Damm et al. (1985). Geochim. Cosmochim. Acta 49, 2197-2220). All concentrations are in mM and the pH is 3.4. Discuss the... 

Positive Eu anomaly is observed for hydrothermal solution issuing from the hydrothermal vent on the seawater at East Pacific Rise (Bence, 1983 Michard et al., 1983 Michard and AlbarMe, 1986). Guichard et al. (1979) have shown that the continental hydrothermal barites have a positive Eu anomaly, indicating a relatively reduced environment. Graf (1977) has shown that massive sulfide deposits and associated rocks from the Bathurst-Newcastle district. New Brunswick have positive Eu anomalies. These data are compatible with positive Eu anomaly of altered basaltic rocks, ferruginous chert and Kuroko ores in Kuroko mine area having positive Eu anomaly and strongly support that Eu is present as divalent state in hydrothermal solution responsible for the hydrothermal alteration and Kuroko mineralization. 

Figure 1.159. Eu/Eu values of (A) modern sediment, hydrothermal solution and seawater and (B) mid-Miocene to early Pliocene Japan Sea see in text). Modern data are from the Pacific ocean,...

Michard, A. and Albarede, F., Michard, G., Minsten, J.F. and Charlou, J.L. (1983) Rare-earth elements and uranium in high-temperature solutions from East Pacific Rise hydrothermal vent field (I3°N). Nature (London), 303, 795-797. 

Sano and Williams (1996) calculated present-day volcanic carbon flux from subduction zones to be 3.1 x 10 mol/year based on He and C isotopes and C02/ He ratios of volcanic gases and fumaroles in circum-Pacific volcanic regions. Williams et al. (1992) and Brantley and Koepenich (1995) reported that the global CO2 flux by subaerial volcanoes is (0.5-2.0) x lO mol/m.y. and (2-3) x 10 mol/m.y. (maximum value), respectively. Le Guern (1982) has compiled several measurements from terrestrial individual volcanoes to derive a CO2 flux of ca. 2 x 10 mol/m.y. Le Cloarec and Marty (1991) and Marty and Jambon (1987) estimated a volcanic gas carbon flux of 3.3 X 10 mol/m.y. based on C/S ratio of volcanic gas and sulfur flux. Gerlach (1991) estimated about 1.8 x 10 mol/m.y. based on an extrapolation of measured flux. Thus, from previous estimates it is considered that the volcanic gas carbon flux from subduction zones is similar to or lower than that of hydrothermal solution from back-arc basins. 

Von Damm, K.L., Edmond, J.M. Measure, C.I., Walden, B. and Weiss, R.F. (1985a) Chemistry of submarine hydrothermal solutions at 21°N, East Pacific Rise. Geochim. Cosmochim. Acta, 49, 2197-2220. 

During the middle Miocene, Kuroko deposits, polymetallic vein-type deposits, gold-quartz vein-type deposits and Sb and Hg vein-type deposits were formed (see sections 1.3 and 1.6). Many vein-type deposits were formed not only in and nearby the Japanese Islands, but also at middle Miocene in northwest USA (Basin and Range Lipman, 1982), and elsewhere in the circum-Pacific regions (e.g., Peru). It is probable that large amounts of CO2 effused into the atmosphere from hydrothermal solution associated with this widespread mineralization and volcanic gas from subduction zones, causing an increase in temperature. 

Kharkar DP, Thomson J, Turekian KK, Forster WO (1976) Uranium and thorium series nuclides in plankton from the Caribbean. Limnol Oceanogr 21 294-299 Krishnaswami S, Lai D, Somayajulu BLK, Weiss R, Craig H (1976) Large-volume in situ filtration of deep Pacific waters mineralogical and radioisotope studies. Earth Planet Sci Lett 32 420-429 Livingston HD, Cochran JK (1987) Determination of transuranic and thorium isotopes in ocean water in solution and in filterable particles. J Radioanal Nucl Chem 115 299-308 Masque P, Sanchez-Cabeza JA, Braach JM, Palacios E, Canals M (2002) Balance and residence times of °Pb and 4 o in surface waters of the northwestern Mediterranean Sea. Cont Shelf Res 22 2127-2146 Matsumoto E (1975) Th-234-U-238 radioactive disequilibrium in the surface layer of the oceans. Geochim Cosmochim Acta 39 205-212... 

Sadeghi, K. M. Sadeghi, M.-A. Kuo, J. F. Jang, L. K. Yen, T. F. Self-Propogated Surfactants Formed During Separation of Bitumen From Tar Sands Using an Alkaline Solution and Sonication, Presented at ACS, 1987 Pacific Conference on Chemistry and Spectroscopy, October 28-30, 1987. 

Soo [96] determined picogram amounts of bismuth in seawater by flameless atomic absorption spectrometry with hydride generation. The bismuth is reduced in solution by sodium borohydride to bismuthine, stripped with helium gas, and collected in situ in a modified carbon rod atomiser. The collected bismuth is subsequently atomised by increasing the atomiser temperature and detected by an atomic absorption spectrophotometer. The absolute detection limit is 3pg of bismuth. The precision of the method is 2.2% for 150 pg and 6.7% for 25 pg of bismuth. Concentrations of bismuth found in the Pacific Ocean ranged from < 0.003-0.085 (dissolved) and 0.13-0.2 ng/1 (total). 

Von Damm, K. L., J. M. Edmond, B. Grant and C. I. Measures, 1985, Chemistry of submarine hydrothermal solutions at 21 °N, East Pacific Rise. Geochimica et Cosmochimica Acta 49, 2197-2220. 

Cuprasol Also called EIC. A process for removing hydrogen sulfide and ammonia from geothermal steam by scrubbing with an aqueous solution of copper sulfate. The resulting copper sulfide slurry is oxidized with air, and the copper sulfate re-used. The sulfur is recovered as ammonium sulfate. Developed by the EIC Corporation, MA, and demonstrated by the Pacific Gas Electric Company at Geysers, CA, in 1979. 

RESS [Rapid Expansion of Supercritical Solutions] A process for depositing a film of solid material on a surface. The substance is dissolved in supercritical carbon dioxide. When the pressure is suddenly reduced, the fluid reverts to the gaseous state and the solute is deposited on the walls of the vessel. Used for size-reduction, coating, and microencapsulation. First described in 1879. Developed in 1983 by R. D. Smith at the Battelle Pacific Northwest Laboratory. 

The main contributions to this development stem from by B.C. Research (BCR) [129,130] for Pacific Northern Gas Ltd. and W.R.-Grace/Hydro-Quebec [129-131] in the period 1980 till 1992. The economic viability of this process depends largely on the performance of the electrochemical reactors for the generation of Ce4+, which should produce concentrated solutions of Ce4 + ( > 0.3 M) at high current density ( > 1 kA/m2), high current efficiency ( > 70%) and long life ( > 2 years). 

Given the disparity in success between raw and purified NaNT solutions described in the previous section, it was hypothesized that an impurity in the raw NaNT solution was contributing towards varying DBX-1 reaction results including the inability to produce DBX-1 at all. NaNT synthesis has never been optimized for scale-up nor have adequate analytical methods been developed to analyze NaNT. The investigating teams from Nalas Engineering and Pacific Scientific utilized various analytical methods to identify impurities in the NaNT solutions that impeded the reaction to DBX-1. 

Andrew Dickson (Chair) is an Associate Professor-in-Residence at the Scripps Institution of Oceanography. His research focuses on the analytical chemistry of carbon dioxide in sea water, biogeochemical cycles in the upper ocean, marine inorganic chemistry, and the thermodynamics of electrolyte solutions at high temperatures and pressures. His expertise lies in the quality control of oceanic carbon dioxide measurements and in the development of underway instrumentation for the study of upper ocean biogeochemistry. Dr. Dickson served on the NRC Committee on Oceanic Carbon. He is presently a member of the IOC C02 Advisory Panel and of the PICES Working Group 13 on C02 in the North Pacific. 

When studying the Pacific yew s close relative, the European yew, chemists made an exciting discovery that led to the second solution. 

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