Biogeochemical cycles

The majority of published °Pb reports address the utility of °Pb as a geochronological tool rather than as an element that is involved in complex biogeochemical cycles. Nonetheless, some of these studies do provide insight into the geochemical behavior of °Pb and °Po. Nearly all of the lead in the world s surface oceans is believed to be of anthropogenic origin—derived from combustion... 

B. H. SvENSSON and R. Soderlund (eds.). Nitrogen, Phosphorus, and Sulfur-Global Biogeochemical Cycles, SCOPE Report, No. 7, Sweden 1976, 170 pp. also SCOPE Report No. 10, Wiley, New York, 1977, 220 pp, and SCOPE Newsletter 47, Jan. 1995, pp. 1-4. 

It is the determination of volatile organic compounds produced from natural products that requires separation techniques that allow isolation of stereoisomers. The most commonly determined groups are the terpene and sesquiterpene species present in essential oils, which are used as key indicators of biological factors such as the growth season, geographic location, climate, etc. These species are also released directly into the atmosphere by very many plants and trees, and make a substantial contribution to global biogeochemical cycles. 

Feedbacks may be affected directly by atmospheric CO2, as in the case of possible CO2 fertilization of terrestrial production, or indirectly through the effects of atmospheric CO2 on climate. Furthermore, feedbacks between the carbon cycle and other anthropogenically altered biogeochemical cycles (e.g., nitrogen, phosphorus, and sulfur) may affect atmospheric CO2. If the creation or alteration of feedbacks have strong effects on the magnitudes of carbon cycle fluxes, then projections, made without consideration of these feedbacks and their potential for changing carbon cycle processes, will produce incorrect estimates of future concentrations of atmospheric CO2. 

Cnitzen, P. J. In The Major Biogeochemical Cycles and Their Interactions, Bolin, B. Cook, R. B., Eds. SCOPE 21 John Wiley Sons New York, NY, 1983 pp 67-111. 

Biogeochemical cycling in forests includes elemental inputs, exports, and a complex set of physical, chemical and biotic processes which comprise internal nutrient cycles (Fig. 1). Any disturbance, whether anthropogenic (i.e. 

Biomass Redistribution Associated with Deforestation and Fire. The influence of deforestation on biogeochemical cycles is dependent upon a number of factors associated with the unique characteristics of the ecosystem (climate, soils, topography, etc), the quantity of the total nutrient pool stored in aboveground biomass (Table II), and the level of disturbance (i.e. the degree of canopy removal, soil disturbance, and the quantity of wood or other forest products exported from the site). The quantity of biomass consumed by one or more slash fires following deforestation can also dramatically increase nutrient losses, influence post fire plant succession, and hence, postfire biogeochemical cycles. 

Woodmansee, R.G. Wallach, L.S. Effects of fire regimes on biogeochemical cycles In Fire Regimes and Ecosystem Properties, Proceedings. USDA, U.S. Forest Service, GTR-WO-26, 1981,... 

The last chapter in this introductory part covers the basic physical chemistry that is required for using the rest of the book. The main ideas of this chapter relate to basic thermodynamics and kinetics. The thermodynamic conditions determine whether a reaction will occur spontaneously, and if so whether the reaction releases energy and how much of the products are produced compared to the amount of reactants once the system reaches thermodynamic equilibrium. Kinetics, on the other hand, determine how fast a reaction occurs if it is thermodynamically favorable. In the natural environment, we have systems for which reactions would be thermodynamically favorable, but the kinetics are so slow that the system remains in a state of perpetual disequilibrium. A good example of one such system is our atmosphere, as is also covered later in Chapter 7. As part of the presentation of thermodynamics, a section on oxidation-reduction (redox) is included in this chapter. This is meant primarily as preparation for Chapter 16, but it is important to keep this material in mind for the rest of the book as well, since redox reactions are responsible for many of the elemental transitions in biogeochemical cycles. 

Introduction Biogeochemical Cycles as Fundamental Constructs for Studying Earth System Science and Global Change... 

Some of the earliest work in the study of biogeochemical cycles and their role in the physical... 

The models used to study biogeochemical cycles are described by a set of terms whose definitions must be clearly understood at the outset. We define them here as they are used throughout the book. 

Biogeochemical cycle. As discussed early in the chapter, this term describes the global or regional cycles of the "life elements" C, N, S, and P with reservoirs including the whole or part of the atmosphere, the ocean, the sediments, and the living organisms. The term can be applied to the corresponding cycles of other elements or compounds. 

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