Environment reducing

Sihcon irons are very resistant to oxidizing and reducing environments, and resistance depends on the formation of a passive film. These irons are widely used in siilfuric acid service, since they are unaffec ted by siilfuric at all strengths, even up to the boihng point. 

F). Alkalies have little effect on this alloy, but it will not stand up against very highly oxidizing or reducing environments. 

Alloy 400 is also adequate for equipment processing of dry halogen gases and chlorinated hydrocarbons and can be used in reducing environments. 

The high temperatures of coal char oxidation lead to a partial vaporization of the mineral or ash inclusions. Compounds of the alkali metals, the alkaline earth metals, silicon, and iron are volatilized during char combustion. The volatilization of silicon, magnesium, calcium, and iron can be greatly enhanced by reduction of their refractory oxides to more volatile forms (e.g., metal suboxides or elemental metals) in the locally reducing environment of the coal particle. The volatilized suboxides and elemental metals are then reoxidized in the boundary layer around the burning particle, where they subsequently nucleate to form a submicron aerosol. 

Reduction of monocyclic aromatic nitro compounds has been demonstrated (a) with reduced sulfur compounds mediated by a naphthoquinone or an iron porphyrin (Schwarzenbach et al. 1990), and (b) by Fe(II) and magnetite produced by the action of the anaerobic bacterium Geobacter metallireducens (Heijman et al. 1993). Quinone-mediated reduction of monocyclic aromatic nitro compounds by the supernatant monocyclic aromatic nitro compounds has been noted (Glaus et al. 1992), and these reactions may be signihcant in determining the fate of aromatic nitro compounds in reducing environments (Dunnivant et al. 1992). 

Zoro JA, JM Hunter, G Eglinton, CC Ware (1974) Degradation of p,p -DDT in reducing environments. Nature 247 235-237. 

Positive Eu anomaly is observed for hydrothermal solution issuing from the hydrothermal vent on the seawater at East Pacific Rise (Bence, 1983 Michard et al., 1983 Michard and AlbarMe, 1986). Guichard et al. (1979) have shown that the continental hydrothermal barites have a positive Eu anomaly, indicating a relatively reduced environment. Graf (1977) has shown that massive sulfide deposits and associated rocks from the Bathurst-Newcastle district. New Brunswick have positive Eu anomalies. These data are compatible with positive Eu anomaly of altered basaltic rocks, ferruginous chert and Kuroko ores in Kuroko mine area having positive Eu anomaly and strongly support that Eu is present as divalent state in hydrothermal solution responsible for the hydrothermal alteration and Kuroko mineralization. 

There are two possibilities here to explain this correlation. One is that isotopically heavy sulfide sulfur derived from seawater sulfate was fixed in shale because reducing agency of shale with carbonaceous matters is thought to be stronger than that of sandstone. The ore fluids extracted this sulfur. Gold of low NAg precipitated in shale like the Kuryu deposit under more reducing environment than in sandstone like the Saigane deposit. 

From a geochemical viewpoint, U is an incompatible lithophile and refractory element. U exists in three distinct oxidation states in nature (Galas 1979) but the most common are ([Rn] 5f ) and ([Rn]). The most reduced form (metal) is never found in natural environments. At the surface of the earth, U is dominantly in the form. However, in a reducing environment, it will be in the state where it is insoluble and therefore generally far less mobile than U(VI). In the mantle, U is thought to occur in the... 

In the case of LNT, different proposals have been advanced to explain the mechanisms governing the NO, release. Recent papers suggested that the NO release is provoked by the heat generated upon the reducing switch (thermal release) [40], by the decrease of the gas-phase oxygen concentration that destabilizes the stored nitrates [41], by spillover and reduction of N02 onto reduced Pt sites or by the establishment of a net reducing environment, which decreases the equilibrium stability of nitrates [12,42,43],... 

Hence, TPD and TPSR data obtained over the binary catalyst showed that the presence of a net reducing environment did not play any significant role in the decomposi-tion/reduction of nitrates stored over Ba. Indeed a partial reduction of stored NO could... 

An enantioselective nitrilase from Pseudomonas putida isolated from soil cultured with 2 mM phenylacetonitrile was purified and characterized. This enzyme is comprised of 9-10 identical subunits each of 43 kDa. It exhibits a pH optimum at 7.0 and a temperature optimum at 40 °C (Ty2 = 160 min) and requires a reducing environment for activity. This nitrilase was shown to have an unusually high tolerance for acetone as co-solvent, with >50% activity retained in the presence of 30% acetone. The kinetic profile of this nitrilase reveals KM= 13.4mM, cat/ M = 0-9s 1mM 1 for mandelonitrile, ZfM = 3.6mM, kclJKM 5.2 s him-1 for phenylacetonitrile, and KM = 5.3 mM, kC lt/KM = 2.5 s 1 him 1 for indole 3-acetonitrile. Preliminary analysis of this enzyme with 5 mM mandelonitrile revealed formation of (/t)-mandelic acid with 99.9% ee [59]. 

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