Oxide peroxide fluoride

Magnesium Air, beryllium fluoride, ethylene oxide, halogens, halocarbons, HI, metal cyanides, metal oxides, metal oxosalts, methanol, oxidants, peroxides, sulfur, tellurium... 

Thermal decomposition of peroxide fluoride species provides a convenient route to titanium oxide fluorides [246]. Decomposition of(NH4)3Ti(02)F5 and K3Ti(02)F5 at 640 and 450°C yields TiOF2 and K3TiOF5, respectively, which were identified by elemental analysis and vibrational spectroscopy. 

Thermal decomposition of the previously known peroxide fluorides, K2V0(02)2F and K2V203(02)2F2, at 275°C and 325°C yields the oxide fluorides, K2V03F and K2V205F2, respectively, which were identified by infrared spectroscopy and elemental analysis [246]. Both K2V03F and K2V205F2 were shown by powder X-ray diffraction to crystallize in the hexagonal system [260]. 

Explodes on contact with bromine trifluoride chlorine trifluoride fluorine hydrogen peroxide + catalysts acetylene + ethylene. Explodes when heated with calcium carbonate + magnesium 3,4-dichloronitrobenzene + catalysts vegetable oils + catalysts ethylene + nickel catalysts difluorodiazene (above 90°C) 2-nitroanisole (above 250°C/34 bar + 12% catalyst) copper(II) oxide nitryl fluoride (above 200°C) polycarbon mono fluoride (above 500°C). 

BENSULFOID (7704-34-9) Combustible solid (flash point 405°F/207°C). Finely divided dry materia forms explosive mixture with air. The vapor reacts violently with lithium carbide. Reacts violently with many substances, including strong oxidizers, aluminum powders, boron, bromine pentafluoride, bromine trifluoride, calcium hypochlorite, carbides, cesium, chlorates, chlorine dioxide, chlorine trifluoride, chromic acid, chromyl chloride, dichlorine oxide, diethylzinc, fluorine, halogen compounds, hexalithium disilicide, lampblack, lead chlorite, lead dioxide, lithium, powdered nickel, nickel catalysis, red phosphorus, phosphorus trioxide, potassium, potassium chlorite, potassium iodate, potassium peroxoferrate, rubidium acetylide, ruthenium tetraoxide, sodium, sodium chlorite, sodium peroxide, tin, uranium, zinc, zinc(II) nitrate, hexahydrate. Forms heat-, friction-, impact-, and shock-sensitive explosive or pyrophoric mixtures with ammonia, ammonium nitrate, barium bromate, bromates, calcium carbide, charcoal, hydrocarbons, iodates, iodine pentafluoride, iodine penloxide, iron, lead chromate, mercurous oxide, mercury nitrate, mercury oxide, nitryl fluoride, nitrogen dioxide, inorganic perchlorates, potassium bromate, potassium nitride, potassium perchlorate, silver nitrate, sodium hydride, sulfur dichloride. Incompatible with barium carbide, calcium, calcium carbide, calcium phosphide, chromates, chromic acid, chromic... 

ESTANO (Spanish) (7440-31-5) Finely divided material is combustible and forms explosive mixture with air. Contact with moisture in air forms tin dioxide. Violent reaction with strong acids, strong oxidizers, ammonium perchlorate, ammonium nitrate, bis-o-azido benzoyl peroxide, bromates, bromine, bromine pentafluoride, bromine trifluoride, bromine azide, cadmium, carbon tetrachloride, chlorine, chlorine monofluoride, chlorine nitrate, chlorine pentafluoride, chlorites, copper(II) nitrate, fluorine, hydriodic acid, dimethylarsinic acid, ni-trosyl fluoride, oxygen difluoride, perchlorates, perchloroethylene, potassium dioxide, phosphorus pentoxide, sulfur, sulfur dichloride. Reacts with alkalis, forming flammable hydrogen gas. Incompatible with arsenic compounds, azochloramide, benzene diazonium-4-sulfonate, benzyl chloride, chloric acid, cobalt chloride, copper oxide, 3,3 -dichloro-4,4 -diamin-odiphenylmethane, hexafluorobenzene, hydrazinium nitrate, glicidol, iodine heptafluoride, iodine monochloride, iodine pentafluoride, lead monoxide, mercuric oxide, nitryl fluoride, peroxyformic acid, phosphorus, phosphorus trichloride, tellurium, turpentine, sodium acetylide, sodium peroxide, titanium dioxide. Contact with acetaldehyde may cause polymerization. May form explosive compounds with hexachloroethane, pentachloroethane, picric acid, potassium iodate, potassium peroxide, 2,4,6-trinitrobenzene-1,3,5-triol. 

HAZARD RISK Dangerous fire hazard explodes on contact with diborane, BrFs, permanganic acid forms sensitive explosive mixtures with IF4, AGCIO4, nitric acid, liquid O2, ignites on contact with sodium peroxide and water incompatible or reacts strongly with strong oxidizers, many fluorides and perchlorates NFPA Code H 2 F 3 R 0. 

Binary salts have varying hazards, one of which is toxicity. Some of the binary salts are highly toxic, such as sodium fluoride, calcium phosphide, and mercuric chloride. Cyanide salts are also highly toxic, such as sodium cyanide and potassium cyanide. The remaining salts, binary oxides, peroxide, hydroxides, and oxysalts are generally not considered toxic. 

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