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Oils, essentials, derived from aromatic

Physical processes (see chapter 2) for isolation of natural flavouring substances include distillation, solvent extraction (including supercritical carbon dioxide), and chromatography. Major sources are essential oils. These may be derived from various parts of aromatic plants such as fruits (e.g. citms, fennel), fmit parts (e.g. mace), flowers (e.g. safflower), flower parts (e.g. saffron), flower buds (e.g. clove), bulbs (e.g. onion), barks (e.g. cinnamon), leaves (e.g. basil), leaves and twigs (e.g. mandarin petitgrain), rhizomes (e.g. ginger), roots (e.g. angelica), and seeds (e.g. mustard). [Pg.141]

Essential oils are usually derived from the non-seed parts of the plants with chemical composition other than the triglyceride structure of natural fats and oils. They refer to the subtle, aromatic liquids extracted from the flowers, seeds, leaves, stems, bark and roots of herbs, bushes, shrubs and trees through distillation. Essential oils are concentrated liquids containing volatile aromatic compounds. They are used in perfumery, aromatherapy, cosmetics, incense, medicine, household cleaning products and for flavouring food and drink. Their use in aromatherapy and other health care areas is growing. [Pg.182]

Essential oils are volatile compounds responsible for the aromas commonly associated with many plants (see essay "Terpenes and Phenylpropanoids")- The chief constituent of the essential oil from cloves is aromatic and volatile with steam. In this experiment, you will isolate the main component derived from this spice by steam distillation. Steam distillation provides a means of isolating natural products, such as essential oils, without the risk of decomposing them thermally. Identification and characterization of this essential oil will be accomplished by infrared spectroscopy. [Pg.122]

The most important natural sources of flavors are the essential oils derived from spices, fruits, and flowers as well as extractives and exudates (resins) from certain plant sources and animal secretions, e.g., musk. Essential oils are aromatic substances which are widely used in several industries such as perfume, pharmaceutical, food, and nutrition. These are mixtures of more than 200 compounds [14,16]. It contains monoterpenes, sesquiterpene hydrocarbons, and their oxygenated derivatives, along with aliphatic and aromatic aldehydes, alcohols, esters, and nonvolatile residues. Generally, terpenes are unsaturated com-... [Pg.176]

Phenols, which in foods act as aromatic substances, are either primary food components of some essential oils or are produced as secondary substances in food processing. The primary components are phenols structurally related to the corresponding alkyl aryl ethers (see Section 8.2.3.1.2). Secondarily formed phenols are produced mainly from phenolic acids and lignin during thermal processes and by the action of microorganisms. Particularly important compounds are derived from phenol, guaiacol (2-methoxyphenol) and syringol (2,6-dimethoxyphenol) (8-119). [Pg.582]

The primary aromatic substances in beer are derived from raw materials (barley or hops) that confer the beer s typical odour and taste. Bitter acids of hops have a bitter taste (see Section 8.3.5.1.3), but hop cones also contain 0.3-1% m/m of terpenoids (60-80% of hop essential oil), which have a considerable influence on the smell of beer. The main components of aromatic hop oils are sesquiterpenic hydrocarbons in which a-humulene, P-caryophyllene and famesene dominate. The major monoter-penic hydrocarbon is myrcene. For example, the essential oil content of fine aromatic varieties, such as Saaz, is 0.8% m/m, of which 23% is myrcene, 20.5% a-humulene, 14% famesene 6% and P-caryophyUene. Significant components of the hop aroma in beer are mainly isomeric terpenoid monoepoxides resulting from autoxidation and diepoxides of a-humulene and fS-caryophyUene, but also other terpenoids. Important components of hops odour are also various alcohols (such as geraniol and hnalool), esters (ethyl 2-methylpropanoate, methyl 2-methylbutanoate, propyl 2-methylbutanoate and esters of terpenic alcohols, such as geranyl isobutanoate), hydrocarbons, aldehydes and ketones formed by oxidation of fatty acids, such as (3E,5Z)-undeca-l,3,5-triene, (Z)-hex-3-enal, nonanal, (Z)-octa-l,5-dien-3-one, their epoxides, such as ( )-4,5-epoxydec-2-enal and sulfur compounds. Other important components of hops are so-called polyphenols (condensed tannins) that influence the beer s taste and have antioxidant effects. Less important compounds are waxes and other hpids. Hop products, such as powder, pellets and extracts (by extraction with carbon... [Pg.619]

Most natural flavorings, with the exception of common salt, are derived from plant substances—either from the aromatic, volatile vegetable oils known as essential oils, or from the nonvolatile plant oils called resins. But some are derived from synthetics which resemble the natural products. [Pg.361]

A syrupy liquid produced by special glands of flowers that is collected by bees and converted by them into honey. The unique flavors of the honeys derived from the different nectars are due mainly to the essential oils and other aromatic substances produced by the flowers. [Pg.763]

As discussed in this book (Chapter 2, for example) a main difference between fossil fuels and biomass as feedstocks is that in the former case the functionalization of base chemicals obtained from the oil (ethylene, propylene, aromatics, etc.) occurs essentially by introduction of heteroatoms, while in the case of biomass-derived based chemicals (glycerol, for example) it is necessary to eliminate heteroatoms (oxygen, in particular). Consequently, the catalysts required to develop a petrochemistry based on bio-derived raw materials need to be discovered and cannot simply be translated from existing ones, even if the knowledge accumulated over many years will make this discovery process much faster than that involved in developing the petrochemical catalytic routes. [Pg.395]

Jeff Quigg says the mixing of a perfume is "a trial and error process." An experienced perfumer must memorize a vast library of hundreds or even thousands of individual scents and combinations of scents. Perfume ingredients can be divided into natural essential oils (derived directly from plants) and aromatic chemicals (synthetically produced fragrance components). [Pg.17]

Crude Oil. Crude petroleum consists essentially of mixtures of paraffinic, naphthenic, and aromatic hydrocarbons containing from 1 to over 70 carbon atoms per molecule and may contain dissolved gases or solids. The naphthenic hydrocarbons are based on cyclopentane or cyclohexane or on fused C5 and Ce rings. There is no evidence of the existence of C3, C4, C7, or C7+ cycloparaffins in crude oil. Olefins, diolefins, and acetylenes are absent. The aromatics are mainly benzene derivatives naphthalene, tetralin, and their substituted derivatives have been isolated in a few cases. [Pg.329]

Numerous monoterpenes were identified in the essential oil of the rhizomes of Z. cassumunar [279]. From the hexane extract of the rhizomes of Z. cassumunar, thirteen aromatic compounds 309,310, 312, 317-324, 326 and 327 were isolated [280-282]. The structures of these compounds were determined on the basis of their spectroscopic data and by syntheses. The crystal structures of cyclohexene derivative 312 and quinone 324 were determined by X-ray diffraction analysis [280]. Evaluation of the biological activity of these compounds revealed that compound 317 possessed smooth muscle relaxant activity ( guinea-pig ileum and tracheal chain) [283].The mechanism of bronchodilator activity of 317 was found to be similar to those of aminophylline and papaverine [284]. Compound 317 also exhibited uterine relaxant effect and shared a similar mechanism of action with papaverine [285]. Anti-inflammatory activity of 309, 312, 317-319, 326 and 327 was evaluated using the carragenin-induced rat paw edema model and compound 317 was reported to possess the strongest inhibitory activity on the edema formation [286]. Compounds 322 and 323 exhibited insecticidal activity towards neonate larvae ofSpodoptera littoral is [266]. [Pg.844]

Typically consisting of highly complex mixtures of mono- (Cjo), sesquiterpenes (C15), 49 d phenols that confer the scent of the plant from which they are derived, plant essential oils are obtained through steam distillation of plant material from a relatively select group of plants [5]. As a result, most essential oils come from highly aromatic species such as those in the Apiaceae (carrot), Lamiaceae (mint). [Pg.201]


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